Buckminsterfullerene's (C60) octanol-water partition coefficient (Kow) and aqueous solubility

Environmental Science and Technology

Volumn 42, Issue 16, 2008, Pages 5945-5950

  Jafvert, Chad T ^a   Kulkarni, Pradnya P ^a  

^a PURDUE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON CLUSTERS; RISK ASSESSMENT; RISK MANAGEMENT;

BUCKMINSTER FULLERENE; FULLERENE C;

FULLERENES;

ALCOHOL; FULLERENE; OCTANOL; ORGANIC COMPOUND; TETRAHYDROFURAN; TOLUENE; WATER; FULLERENE DERIVATIVE;

ALCOHOL; AQUEOUS SOLUTION; BIOACCUMULATION; CARBON ISOTOPE; COMPARATIVE STUDY; FULLERENE; PARTITION COEFFICIENT; RISK ASSESSMENT; SOLUBILITY; TOLUENE; WATER;

AQUEOUS SOLUTION; ARTICLE; CONCENTRATION (PARAMETERS); HYDROPHOBICITY; MATHEMATICAL MODEL; PARTITION COEFFICIENT; SOLUBILITY; WOHL EQUATION; CHEMISTRY;

FULLERENES; OCTANOLS; SOLUBILITY; WATER;

EID: 49749120213     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es702809a     Document Type: Article

References (20)

1. 70, in water. Preparation and characterization. Langmuir 2001, 17, 6013-6017.
2. 60 in water: Nanocrystal formation and microbial response. Environ. Sci. Technol. 2005, 39, 4307-4316.
3. 60 fullerene with help of FTIR reflectance and UV-VIS spectroscopy. Chem. Phys. Lett. 2002, 364, 8-17.
4. Brant, J.; Lebille, J.; Bottero, J.; Wiesner, M. Characterizing the impact of preparation method on fullerene cluster structure and chemistry. Langmuir 2006, 22, 3878-3885.
5. Brant, J.; Lecoanet, H.; Wiesner, M. Aggregation and deposition characteristics of fullerene nanoparticles in aqueous systems. J. Nano Res. 2005, 7, 545-553.
6. Nakamura, E.; Isobe, H. Functionalized fullerenes in water. The first 10 years of their chemistry, biology and nanoscience. Acc. Chem. Res. 2003, 36, 807-815.
7. Andersson, T.; Westman, G.; Wennerstrom, O.; Sundahl, M. NMR and UV-VIS investigation of water-soluble fullerene-60-γ-cyclodextrin complex. J. Chem. Soc., Perkin Trans. 2 1994, 5, 1097-1101.
8. 60 in model biological systems. A visible-UV absorption study of solvent-dependent parameters and solute aggregation. J. Phys. Chem. 1994, 98, 3492-3500.
9. Schwarzenbach, R.; Gschwend, P.; Imboden, D. Environmental Organic Chemistry; Wiley-Interscience: New York, 2002.
10. Dohanyosova, P.; Dohnal, V.; Fenclova, D. Temperature dependence of aqueous solubility of anthracene: accurate determination by a new generator column apparatus. Fluid Phase Equilib. 2003, 214, 151-167.
11. 70 in seven normal alcohols and their deduced solubility in water. Fullerene Sci. Technol. 1996, 4, 509-515.
12. 60 in a variety of solvents. J. Phys. Chem. 1993, 97, 3379-3383.
13. Kimata, K.; Hirose, T.; Moriuchi, K.; Hosoya, K.; Araki, T.; Tanaka, N. High-capacity stationary phases containing heavy atoms for HPLC separation of fullerenes. Anal. Chem. 1995, 67, 2556-2561.
14. Leo, A.; Hansch, C.; Elkins, D. Partition coefficients and their uses. Chem. Rev. 1971, 71, 525-616.
15. Chiou, C.; Schmedding, D. Partitioning of organic compounds in octanol-water systems. Environ. Sci. Technol. 1982, 16, 4-10.
16. 60 in solvent mixtures. Environ. Sci. Technol. 2008, 42, 845-851.
17. Prausnitz, J.; Lichtenthaler, R.; de Azevedo, E. Molecular Thermodynamics of Fluid-Phase Equilibria; Prentice-Hall: Englewood Cliffs, NJ, 1986.
18. Butler, J.; Thomson, D.; Maclennan, W. The free energy of the normal aliphatic alcohols in aqueous solution. Part I. The partial vapor pressures of aqueous solutions of methyl, n-propyl, and n-butyl alcohols. Part II. The solubilities of some normal aliphatic alcohols in water. Part III. The theory of binary solutions, and its application to aqueous-alcoholic solutions. J. Chem. Soc. 1933, 16, 674-686.
19. Matous, J.; Noval, J.; Sobr, J.; Pick, J. Phase equilibria in the system tetrahydrofuran (1)-water (2). Collect. Czech. Chem. Commun. 1972, 37, 2653-2663.
20. 60 in n-hexane. Chem. Phys. Lett. 1999, 299, 177-179.