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Tetrahedron Letters

Volumn 12, Issue 37, 1971, Pages 3455-3458

Effects of structure on intramolecular cyclizations of alkenyl grignard reagents

(3) Kossa Jr , Walter C a Rees, Thomas C a Richey Jr , Herman G a

a PENNSYLVANIA STATE UNIVERSITY (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 49649150095 PISSN: 00404039 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4039(01)97204-1 Document Type: Article

Times cited : (79)

References (25)

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- Attempted ring cleavage and closures of the norbornane skeleton by organometallic routes
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8
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- Richey¹ Rothman²

9
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- H. G. Richey, Jr. A.M. Rothman, unpublished work.

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11
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12
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13
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- Ring-cleavage reactions of 2-bicyclo-[2.1.1]hexyl Grignard reagents
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14
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- 3 By scrupulous purification of reagents and exclusion of air, yields of up to 90% of the hydrocarbon resulting from rearrangement of 7 have been obtained.

15
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- 2) Grignard reagent was not detected, permitting the assignment of the rate limit. A recent study [E.A. Hill and H.-R. Ni, submitted for publication] at even higher temperatures suggests that the rearrangement rate is close to the assigned limit.

16
- 84918735568
- 8,16

17
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- W. C. Kossa, Jr., and H. G. Richey, Jr., unpublished work.

18
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- Methyl groups destabilize aryl radical anions [R. G. Lawler and C. T. Tabit, J. Amer. Chem. Soc., 5671 (1969) and references cited therein].

19
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- Radikalumlagerungen, III. Über das Auftreten von Radikalen bei der Bildung von Grignard-Verbindungen
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20
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21
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22
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23
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24
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- J. Zabicky, Wiley-Interscience, London, Chapter 2.
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25
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- 5 for hydrolysis products obtained from a reaction of 2.

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.