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15
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84906375214
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Salts of these ions increase surface tension by a bulk osmotic effect analogous to freezing point depression (i.e, an increase in [salt] increases the thermodynamic (entropic) cost of unmixing bulk water from a salt solution to form pure water at the air-water interface, analogous to unmixing bulk water to form pure ice in the case of freezing point depression
-
Salts of these ions increase surface tension by a bulk osmotic effect analogous to freezing point depression (i.e., an increase in [salt] increases the thermodynamic (entropic) cost of unmixing bulk water from a salt solution to form pure water at the air-water interface, analogous to unmixing bulk water to form pure ice in the case of freezing point depression).
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16
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29344437812
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Hong, J.; Capp, M. W.; Saecker, R. M.; Record, M. T. Biochemistry 2005, 44, 16896-16911.
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In Protein Structure, Stability, and Folding
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2nd ed, Shriver, J. W, Ed, Humana Press: Totawa, NJ, in press
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Record, M.T.3
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24
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84906360969
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-
Equation 1 for the SFEI is completely analogous to earlier analyses of thermodynamic effects of solutes on biopolymer processes.5,22,23 The SPM is a two-domain (local, bulk) interpretation of preferential interaction coefficients Γ, fundamental thermodynamic quantities (obtainable from experiment or from integration of the local excess or deficit of solute around a biopolymer relative to bulk) that describe the competition of solute and water for a surface. Equation 1 should be applied only for model compounds with low aqueous solubility, small salt effects i.e. free energy increments, or both. Rigorous application requires various corrections determined from isopiestic distillation data for two- and three-component solutions.25,26 Because this data is not available and the low-solubility requirement is met in most cases, the internally consistent analysis developed here should be applicable to salt effects on biopolymer processes
-
25,26 Because this data is not available and the low-solubility requirement is met in most cases, the internally consistent analysis developed here should be applicable to salt effects on biopolymer processes.
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25
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0037059028
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Anderson, C. F.: Felitsky, D. J.; Hong, J.; Record, M. T. Biophys. Chem. 2002, 101-102, 497-511.
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Anderson, C.F.1
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Record, M.T.4
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26
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34548270876
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Cannon, J. G.; Anderson, C. F.; Record, M. T. J. Phys. Chem. B 2007, 111, 9675-9685.
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Cannon, J.G.1
Anderson, C.F.2
Record, M.T.3
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27
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0037197254
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Tsodikov, O. V.; Record, M. T.; Sergeev, Y. V. J. Comput. Chem. 2002, 23, 600-609.
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Tsodikov, O.V.1
Record, M.T.2
Sergeev, Y.V.3
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28
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0025906146
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Livingstone, J. R.; Spolar, R. S.; Record, M. T. Biochemistry 1991, 30, 4237-4244.
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Livingstone, J.R.1
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Record, M.T.3
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29
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84906389438
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-
p,3 typically changes <2% in this concentration range.
-
p,3 typically changes <2% in this concentration range.
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-
-
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31
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-
0011337553
-
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Saylor, J. H.; Whitten, A. I.; Claiborne, I.; Gross, P. M. J. Am. Chem. Soc. 1952, 74, 1778-1781.
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Saylor, J.H.1
Whitten, A.I.2
Claiborne, I.3
Gross, P.M.4
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32
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0032911138
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33947485233
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Wetlaufer, D.B.1
Malik, S.K.2
Stoller, L.3
Coffin, R.L.4
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36
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84906360970
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-
Most solubility and distribution measurements were performed at 25°C; benzene solubility in a few salt solutions was measured at 30°C. This temperature difference is insignificant because the temperature dependence of solubility free energy increments for a particular solute, where measured, is found to be small.
-
Most solubility and distribution measurements were performed at 25°C; benzene solubility in a few salt solutions was measured at 30°C. This temperature difference is insignificant because the temperature dependence of solubility free energy increments for a particular solute, where measured, is found to be small.
-
-
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40
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8744225646
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Felitsky, D. J.; Cannon, J. G.; Capp, M. W.; Hong, J.; Van Wynsberghe, A. W.; Anderson, C. F.; Record, M. T. Biochemistry 2004, 43, 14732-14743.
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Felitsky, D.J.1
Cannon, J.G.2
Capp, M.W.3
Hong, J.4
Van Wynsberghe, A.W.5
Anderson, C.F.6
Record, M.T.7
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41
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-
84906375212
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-
1.
-
1.
-
-
-
-
45
-
-
84906389434
-
-
nE series.
-
nE series.
-
-
-
-
47
-
-
84906360967
-
-
-) and slightly smaller for excluded anions.
-
-) and slightly smaller for excluded anions.
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-
-
-
52
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-
0000276029
-
-
Podo, F.; Ray, A.; Nemethy, G. J. Am. Chem. Soc. 1973, 95, 6164-6171.
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Podo, F.1
Ray, A.2
Nemethy, G.3
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53
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0026684671
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Spolar, R. S.; Livingstone, J. R.; Record, M. T. Biochemistry 1992, 31, 3947-3955.
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Spolar, R.S.1
Livingstone, J.R.2
Record, M.T.3
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