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A like computation for the n-propylidene complex gave essentially the same structure about carbon as found for the ethylidene complex, so the second methyl group has no significant effect. Furthermore, isobutylidene and neopentylidene complex counterparts also have the same computed agostic parameters so extra methyl groups on the ß carbon have no effect on the agostic distortion
-
A like computation for the n-propylidene complex gave essentially the same structure about carbon as found for the ethylidene complex, so the second methyl group has no significant effect. Furthermore, isobutylidene and neopentylidene complex counterparts also have the same computed agostic parameters so extra methyl groups on the ß carbon have no effect on the agostic distortion.
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