Structures and magnetic properties of Mn(hfac)2 complexes derived from Bis-TEMPO-substituted diamines

Inorganica Chimica Acta

Volumn 361, Issue 14-15, 2008, Pages 4159-4163

  Kinoshita, Hidetoshi ^a   Akutsu, Hiroki ^a   Yamada, Jun ichi ^a   Nakatsuji, Shin'ichi ^a  

^a UNIVERSITY OF HYOGO   (Japan)

Author keywords

Biradical; Ethylenediamine; Magnetic property; Mn(hfac)2 complex; Piperadine; TEMPO radical; X ray crystal structures

Indexed keywords

ANTIFERROMAGNETISM; MAGNETIC PROPERTIES; SPIN DYNAMICS;

BIRADICAL; ETHYLENE DIAMINE; PIPERADINE; TEMPO RADICAL; X RAY CRYSTAL STRUCTURES;

COORDINATION REACTIONS;

EID: 49549107289     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2008.03.005     Document Type: Article

References (9)

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9. -3J/T) where J is the exchange coupling between Mn and aminoxyl spin sites (postulated to be equal in complex 6), N is the Avogadro number, g is the average g-factor of spins (g = 2.00 is used here), β is the Bohr magneton constant, k is the Boltzmann constant. Cf.:. Rancurel C., Leznoff D.B., Sutter J.-P., Golhen S., Ouahab L., Kliava J., and Kahn O. Inorg. Chem. 38 (1999) 4753