Synthesis of chiral water-soluble metalloporphyrins (Fe, Ru,): new catalysts for asymmetric carbene transfer in water

Tetrahedron Letters

Volumn 49, Issue 40, 2008, Pages 5793-5795

  Nicolas, Irène ^a   Maux, Paul Le ^a   Simonneaux, Gérard ^a  

^a UNIVERSITÉ DE RENNES 1   (France)

Author keywords

Asymmetric cyclopropanation; Chiral water soluble porphyrin; Iron porphyrin; Ruthenium porphyrin; Sulfonated Halterman porphyrin

Indexed keywords

CARBENE; CYCLOPROPANE DERIVATIVE; ESTER DERIVATIVE; IRON; METALLOPORPHYRIN; RUTHENIUM; SULFURIC ACID;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL STRUCTURE; CHIRALITY; COMPLEX FORMATION; HYDROPHILICITY; PROTON NUCLEAR MAGNETIC RESONANCE; SOLUBILITY; SULFONATION;

EID: 49549085489     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2008.07.133     Document Type: Article

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17. -1.
18. 4. Then the reaction was reloaded with compound 3. Catalytic reactions were controlled on a Varian CP-3380 Gas Chromatograph equipped with a CP-Chirasil-Dex Column for yield and ee and Perkin Elmer 341 polarimeter for optical rotation. The same procedure was used with ruthenium compound 4 but without cobaltocene.