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Volumn 10, Issue 4, 1977, Pages 329-332

Michaelis-arbuzov preparation of halo-F-methylphosphonates

Author keywords

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Indexed keywords


EID: 49449125517     PISSN: 00221139     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-1139(00)83108-5     Document Type: Article
Times cited : (85)

References (19)
  • 2
    • 84913670907 scopus 로고    scopus 로고
    • For recent references to fluoromethylene yields, cf:
  • 5
    • 49649137125 scopus 로고
    • Fluoro olefins. Part V. The synthesis and cyclization of polyfluorinated diketones. The reaction of polyfluorinated α,β-unsaturated cyclic ketones with methylenetriphenylphosphoranes
    • and co-workers;
    • (1972) Journal of Fluorine Chemistry , vol.1 , pp. 381
    • Burton1
  • 17
    • 84913646903 scopus 로고    scopus 로고
    • Although the products of these reactions are the expected Michaelis-Arbuzov type of products, the mechanism of this process is probably not the expected SN2 reaction. Additional work is in progress to delineate some of the mechanistic features of this reaction sequence.
  • 18
    • 84913674479 scopus 로고    scopus 로고
    • The yield of phosphonate is an isolated yield based on phosphite.
  • 19
    • 84913684528 scopus 로고    scopus 로고
    • 13C nmr) of the phosphonates were consistent with the assigned structures.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.