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At present, we believe that HOMO/LUMO levels of different doped PEDOTs show very similar values. It is widely accepted that Voc of the devices is determined by the difference between the quasi-Fermi level of TiO2 and the HOMO level of PEDOT. However, the interface properties would result in different Vocʼs of the devices because the conditions of interfaces change the electron density, that is, the quasi-Fermi level of TiO2. As discussed in the paper, the doped anion with the longest alkyl chain (N(C4F9SO2) 2, or C8F9SO3 , would change the growth speed of PEDOT and integrated charges during in situ photoelectrochemical polymerization processes, which would greatly change the conditions of the interface between PEDOT and dye molecules
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-) would change the growth speed of PEDOT and integrated charges during in situ photoelectrochemical polymerization processes, which would greatly change the conditions of the interface between PEDOT and dye molecules.
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