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Both (R)- and (S)-1 ligands can be obtained in enantiomerically pure form: D. J. Cram, R. C. Helgeson, S. C. Peacock, L. J. Klapan, P. Domeir, L. A. Moreau, K. Koga, J. M. Mayer, Y. Chao, M. G. Siegel, D. H. Hoffman, G. D. Y. Sogah, J. Org. Chem. 1978, 43, 1930-1946.
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0031971605
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The NMR spectra of complexes 2-5 from racemic 1 or from enantiomerically pure (S)-1/(R)-1 are identical; this means that only sterospecific homochiral Λ-RRR or Δ-SSS complexes are formed. [5a] M. A. Masood, E. J. Enemark, T. D. P. Stack, Angew. Chem. Int. Ed. 1998, 37, 928-932. [5b] A. Lützen, M. Hapke, J. Griep-Raming, D. Haase, W. Saak, Angew. Chem. Int. Ed. 2002, 41, 2086-2089. [5c] P. Baret, V. Beaujolais, D. Gaude, Ch. Coulombeau, J.-L. Pierre, Chem. Eur. J. 1997, 3, 969-973. [5d] Y. Cui, H. L. Ngo, W. Lin, Chem. Commun. 2003, 1388-1389.
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0037124694
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The NMR spectra of complexes 2-5 from racemic 1 or from enantiomerically pure (S)-1/(R)-1 are identical; this means that only sterospecific homochiral Λ-RRR or Δ-SSS complexes are formed. [5a] M. A. Masood, E. J. Enemark, T. D. P. Stack, Angew. Chem. Int. Ed. 1998, 37, 928-932. [5b] A. Lützen, M. Hapke, J. Griep-Raming, D. Haase, W. Saak, Angew. Chem. Int. Ed. 2002, 41, 2086-2089. [5c] P. Baret, V. Beaujolais, D. Gaude, Ch. Coulombeau, J.-L. Pierre, Chem. Eur. J. 1997, 3, 969-973. [5d] Y. Cui, H. L. Ngo, W. Lin, Chem. Commun. 2003, 1388-1389.
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14
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0030920144
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The NMR spectra of complexes 2-5 from racemic 1 or from enantiomerically pure (S)-1/(R)-1 are identical; this means that only sterospecific homochiral Λ-RRR or Δ-SSS complexes are formed. [5a] M. A. Masood, E. J. Enemark, T. D. P. Stack, Angew. Chem. Int. Ed. 1998, 37, 928-932. [5b] A. Lützen, M. Hapke, J. Griep-Raming, D. Haase, W. Saak, Angew. Chem. Int. Ed. 2002, 41, 2086-2089. [5c] P. Baret, V. Beaujolais, D. Gaude, Ch. Coulombeau, J.-L. Pierre, Chem. Eur. J. 1997, 3, 969-973. [5d] Y. Cui, H. L. Ngo, W. Lin, Chem. Commun. 2003, 1388-1389.
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15
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0038717233
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The NMR spectra of complexes 2-5 from racemic 1 or from enantiomerically pure (S)-1/(R)-1 are identical; this means that only sterospecific homochiral Λ-RRR or Δ-SSS complexes are formed. [5a] M. A. Masood, E. J. Enemark, T. D. P. Stack, Angew. Chem. Int. Ed. 1998, 37, 928-932. [5b] A. Lützen, M. Hapke, J. Griep-Raming, D. Haase, W. Saak, Angew. Chem. Int. Ed. 2002, 41, 2086-2089. [5c] P. Baret, V. Beaujolais, D. Gaude, Ch. Coulombeau, J.-L. Pierre, Chem. Eur. J. 1997, 3, 969-973. [5d] Y. Cui, H. L. Ngo, W. Lin, Chem. Commun. 2003, 1388-1389.
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85153000012
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note
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int = 0.0843. The final wR2 was 0.1545 (all data).
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20
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0037122112
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