Spatially limited diffusion coupled with ohmic potential drop and/or slow interfacial exchange: A new method to determine the diffusion time constant and external resistance from potential step (PITT) experiments

Journal of Electroanalytical Chemistry

Volumn 572, Issue 2, 2004, Pages 299-307

  Vorotyntsev, Mikhail A ^a   Levi, Mikhael D ^b   Aurbach, Doron ^b  

^a UNIVERSITÉ DE BOURGOGNE   (France)

^b BAR ILAN UNIVERSITY   (Israel)

Author keywords

Chronoamperometry; Interfacial charge transfer resistance; Linear diffusion; Ohmic effects; PITT

Indexed keywords

CHARGE CARRIERS; CHARGE TRANSFER; DISPERSIONS; ELECTROLYTES; MATHEMATICAL MODELS; OHMIC CONTACTS; OPTIMIZATION; PERTURBATION TECHNIQUES; SOLUTIONS; TITRATION;

CHRONOAMPEROMETRY; INTERFACIAL CHARGE-TRANFER RESISTANCE; LINEAR DIFFUSION; OHMIC EFFECTS; PITT;

DIFFUSION;

EID: 4944250333     PISSN: 15726657     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jelechem.2003.12.014     Document Type: Article

References (31)

1. Wen C.J., Boukamp B.A., Huggins R.A., Weppner W. J. Electrochem. Soc. 126:1979;2258.
2. Weppner W., Huggins R.A. Ann. Rev. Mater. Sci. 8:1978;269.
3. Weppner W. Bruce P.G. Solid-State Electrochemistry. 1995;199 Cambridge University Press. Chapter 8.
4. Carslaw H.S., Jaeger J.C. Conduction of Heat in Solids. 1967;Clarendon Press, Oxford.
5. Crank J. The Mathematics of Diffusion. 1967;Oxford University Press, London.
6. Andrieux C.P., Savéant J.M. J. Electroanal. Chem. 171:1984;65.
7. Andrieux C.P., Savéant J.M. J. Electroanal. Chem. 142:1982;1.
8. Nahir T.M., Buck R.P. J. Electroanal. Chem. 341:1992;1.
9. Ikeda T., Schmehl R., Denisevich P., Willman K., Murray R.W. J. Am. Chem. Soc. 104:1982;2683.
10. Inzelt G., Fekete E., Szabo L. Acta Chim. Hung. 125:1988;435.
11. Lange R., Doblhofer K. Ber. Bunsen-Gesellschaft. 92:1988;578.
12. Murray R.W. Molecular Design of Electrode Surfaces. 1992;Wiley, New York.
13. Bard J., Faulkner L.R. Electrochemical Methods: Fundamentals and Applications. second ed. 2000;Wiley, New York.
14. Montella C. J. Electroanal. Chem. 518:2002;61.
15. Churikov A.V., Volgin M.A., Pridatko K.I. Electrochim. Acta. 47:2002;2857.
16. Churikov A.V., Ivanischev A.V. Electrochim. Acta. 48:2003;3677.
17. Deiss E. Electrochim. Acta. 47:2002;402.
18. Diard J.-P., Le Gorrec B., Montella C. J. Electroanal. Chem. 499:2001;67.
19. Levi M.D., Wang C., Aurbach D. J. Electroanal. Chem. 561:2004;1.
20. Preis W., Sitte W. J. Electrochem. Soc. 145:1998;2179.
21. Kondratiev V.V., Tikhomirova A.V., Malev V.V. Electrochim. Acta. 45:1999;751.
22. M.D. Levi, M.A. Vorotyntsev, D. Aurbach (in preparation).
23. Levi M.D., Aurbach D. Electrochim. Acta. 45:1999;167.
24. Levi M.D., Aurbach D., Vorotyntsev M.A. Condens. Mat. Phys. 30:2002;329.
25. Vorotyntsev M.A., Kornyshev A.A. Rep. Acad. Sci. USSR. 230:1976;631.
26. Kornyshev A.A., Vorotyntsev M.A. Electrochim. Acta. 23:1978;267.
27. Kornyshev A.A., Vorotyntsev M.A. Electrochim. Acta. 26:1981;303.
28. Andrieux C.P., Savéant J.M. J. Electroanal. Chem. 134:1982;163.
29. Vorotyntsev M.A., Daikhin L.I., Levi M.D. J. Electroanal. Chem. 364:1994;37.
30. Vorotyntsev M.A., Badiali J.P., Vieil E. Electrochim. Acta. 41:1996;1375.
31. Levi M.D., Aurbach D. J. Phys. Chem. B. 101:1997;4641.