Unusual reactivity at a platinum center determined by the ligands and the solvent environment

Angewandte Chemie - International Edition

Volumn 43, Issue 38, 2004, Pages 5081-5084

  Tamasi, Gabriella ^b   Cini, Renzo ^b   Intini, Francesco P ^a   Sivo, Maria F ^a   Natile, Giovanni ^a  

^a UNIVERSITY OF BARI   (Italy)

^b UNIVERSITY OF SIENA   (Italy)

Author keywords

Demethylation; O ligands; Oxidation; Platinum; Solvent effects

Indexed keywords

OXIDATION; SOLVENTS;

CHLOROFORM; DEMETHYLATION; LIGANDS;

PLATINUM;

CHLORINE; LIGAND; PLATINUM; SOLVENT; WATER;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTAL STRUCTURE; DEMETHYLATION; OXIDATION; REACTION ANALYSIS; SOLUBILITY; STRUCTURE ANALYSIS;

CRYSTALLOGRAPHY, X-RAY; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PLATINUM; SOLVENTS;

EID: 4944242484     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200454111     Document Type: Article

References (38)

1. a) L. M. Rendina, R. J. Puddephatt, Chem. Rev. 1997, 97, 1735-1754;
2. b) R. A. Gossage, A. D. Ryabov, A. L. Spek, D. J. Stufkens, J. A. M. van Beek, R. van Eldik, G. van Koten, J. Am. Chem. Soc. 1999, 121, 2488-2497, and references therein.
3. Y. N. Kukushkin, Russ. J. Inorg. Chem. 1963, 8, 417-420.
4. K. A. Morgan, M. M. Jones, J. Inorg. Nucl. Chem. 1972, 34, 259-274; K. A. Morgan, M. M. Jones, J. Inorg. Nucl. Chem. 1972, 34, 275-296.
5. K. A. Morgan, M. M. Jones, J. Inorg. Nucl. Chem. 1972, 34, 259-274; K. A. Morgan, M. M. Jones, J. Inorg. Nucl. Chem. 1972, 34, 275-296.
6. M. Crespo, R. Puddephat, Organometallics 1987, 6, 2548-2550.
7. 4)4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; fax: (+44) 1223-336-033; or deposit@ ccdc.cam.ac.uk).
8. G. M. Sheldrick, SHELXS 97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
9. G. M. Sheldrick, SHELXL 97, Program for the Refinement of Crystal Structures, University of Göttingen, Germany, 1997.
10. a) H. Junicke, K. Schenzel, F. W. Heinemann, K. Pelz, H. Bogel, D. Steinborn, Z. Anorg. Allg. Chem. 1997, 623, 603-607;
11. b) J. Muller, F. Glahe, E. Freisinger, B. Lippert, Inorg. Chem. 1999, 38, 3160-3166;
12. c) H. Schollhorn, R. Beyerle-Pfnur, U. Thewalt, B. Lippert, J. Am. Chem. Soc. 1986, 108, 3680-3688;
13. d) I. Dieter, B. Lippert, H. Schollhorn, U. Thewalt, Z. Naturforsch. B 1990, 45, 731-740;
14. e) F. P. Intini, M. Lanfranchi, G. Natile, C. Pacifico, A. Tiripicchio, Inorg. Chem. 1996, 35, 1715-1717.
15. R. Cini, P. A. Caputo, F. P. Intini, G. Natile, Inorg. Chem. 1995, 34, 1130-1134.
16. A. M. Gonzales, R. Cini, F. P. Intini, C. Pacifico, G. Natile, Inorg. Chem. 2002, 41, 470-478.
17. 2] was prepared according to the method reported by R. A. Michelin, R. Bertani, M. Mozzon, G. Bombieri, F. Benetollo, R. J. Angelici, Organometallics 1991, 10, 1751-1757. The oxidation reaction was performed as reported for compound 1.
18. a) B. Lippert in Cisplatin; Chemistry and Biochemistry of a Leading Anticancer Drug (Ed.: B. Lippert) Verlag Helvetica Chimica Acta, Zürich, 1999, pp. 379-403;
19. b) K. Matsumoto in Cisplatin; Chemistry and Biochemistry of a Leading Anticancer Drug (Ed.: B. Lippert) Verlag Helvetica Chimica Acta, Zürich, 1999, pp. 455-475;
20. c) J. K. Barton, H. N. Rabinowitz, D. J. Szalda, S. J. Lippard, J. Am. Chem. Soc. 1977, 99, 2827-2829;
21. d) T. V. Halloran, P. K. Mascharak, I. D. Williams, M. M. Roberts, S. J. Lippard, Inorg. Chem. 1987, 26, 1261-1270;
22. e) K. Sakai, Y. Tanaka, Y. Tsuchiya, K. Hirata, T. Tsubomura, S. Iijima, A. Bhattacharjee, J. Am. Chem. Soc. 1998, 120; 8366-8379;
23. f) K. Matsumoto, K. Fuwa, Inorg. Chem. 1983, 22, 4086-4090;
24. g) K. Matsumoto, H. Takahashi, K. Fuwa, J. Am. Chem. Soc. 1984, 106, 2049-2054;
25. h) K. Ito, R. Somazawa, J. Matsunami, K. Matsumoto, Inorg. Chim. Acta 2002, 339, 292-296.
26. D. W. Nebert, F. J. Gonzales, Annu. Rev. Biochem. 1987, 56, 945-993.
27. a) J. R. Hwu, S.-C. Tsay, Chem. Commun. 1998, 161-168;
28. b) A. Maercker, Angew. Chem. 1987, 99, 1002-1019; Angew. Chem. Int. Ed. Engl. 1987, 26, 972-989.
29. b) A. Maercker, Angew. Chem. 1987, 99, 1002-1019; Angew. Chem. Int. Ed. Engl. 1987, 26, 972-989.
30. T. B. Brill, S. J. Landon, Chem. Rev. 1984, 84, 577-585.
31. a) R. D. Simpson, Organometallics 1997, 16, 1797-1799;
32. b) C. W. Rogers, B. O. Patrick, J. Rettig, M. O. Wolf, J. Chem. Soc. Dalton Trans. 2001, 1278-1283;
33. c) T. Ren, V. De Silva, G. Zou, C. Lin, L. M. Daniels, C. F. Campana, J. C. Alvarez, Inorg. Chem. Commun. 1999, 2, 301-303.
34. a) T. Miyamoto, J. Organomet. Chem. 1977, 134, 335-362;
35. b) J. M. Solar, R. D. Rogers, W. R. Mason, Inorg. Chem. 1984, 23, 373-377.
36. K. Kohda, I. Terashima, N. Sawada, I. Nozaki, M. Yasuda, Y. Kawazoe, Chem. Res. Toxicol. 1992, 5, 8-91.
37. a) J. S. Sun, C. E. Uzelmeier, D. L. Ward, K. R. Dunbar, Polyhedron 1998, 17, 2049-2063;
38. b) C. E. Jones, B. L. Shaw, B. L. Turtle, J. Chem. Soc. Dalton Trans. 1974, 992-999.