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Tetrahedron Letters
Volumn 18, Issue 48, 1977, Pages 4175-4178
Non-aqueous conversion of ketals to ketones via treatment with trimethylsilyl iodide
Author keywords

[No Author keywords available]
Indexed keywords

EID: 49349134435     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(01)83458-4     Document Type: Article
Times cited : (127)
References (13)
  • 1
    • 0343535120 scopus 로고
    • Very few instances of non-aqueous “hydrolyses” of ketals have been reported. For an example in the steroid field see:
    • (1959) Tetrahedron , vol.7 , pp. 138
    • Bowers1    Ibanez2    Ringold3
  • 2
    • 84918285817 scopus 로고    scopus 로고
    • Trimethylsilyl iodide is easily prepared in two steps from the chloride via hexamethyldisiloxane, M. E. Jung and M. A. Lyster, Organic Syntheses, submitted for publication.
  • 4
    • 84918285816 scopus 로고    scopus 로고
    • M.E. Jung and M.A. Lyster, J. Org. Chem., in press.
  • 12
    • 84986489311 scopus 로고
    • Synthetic Methods and Reactions; 321. Mild and Effective Cleavage of Esters and Ethers with Phenyltrimethylsilane/Iodine Reagent
    • (1977) Synthesis , pp. 417
    • Ho1    Olah2
  • 13
    • 84918285814 scopus 로고    scopus 로고
    • Spectral data (NMR, IR) of the crude reaction mixture indicates that the carbonyl compounds are present before water is added. An aqueous workup is performed since direct distillation of the crude reaction mixture gives somewhat (10–20%) lower yields.

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.