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42
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49349100912
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The torsion angle (τ) is the angle between two virtual planes that bisects the cobaloxime plane. Each plane is formed by considering the middle point of the C-C bond of two oxime units that passes through cobalt and pyridine nitrogen
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The torsion angle (τ) is the angle between two virtual planes that bisects the cobaloxime plane. Each plane is formed by considering the middle point of the C-C bond of two oxime units that passes through cobalt and pyridine nitrogen.
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43
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49349099608
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The dihedral angle (butterfly bending angle, α) is the angle between two dioxime planes of each cobaloxime unit
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The dihedral angle (butterfly bending angle, α) is the angle between two dioxime planes of each cobaloxime unit.
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44
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2842577382
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(a) Elliott, C. M.; Hershenhart, E.; Finke, R. G.; Smith, B. L. J. Am. Chem. Soc. 1981, 103, 5558.
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48
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2B, where R is an organic group σ-bonded to cobalt, B is an axial base trans to the organic group, and L is a monoanionic dioxime ligand (e.g., glyoxime (gH), dimethylglyoxime (dmgH), 1,2-cyclohexanedione dioxime (chgH), diphenylglyoxime (dpgH), and dimesitylglyoxime (dmestgH)).
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2B, where R is an organic group σ-bonded to cobalt, B is an axial base trans to the organic group, and L is a monoanionic dioxime ligand (e.g., glyoxime (gH), dimethylglyoxime (dmgH), 1,2-cyclohexanedione dioxime (chgH), diphenylglyoxime (dpgH), and dimesitylglyoxime (dmestgH)).
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49
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49349100086
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The dioxy products show a characteristic band around 250-260 nm for Co-→dioxime in the UV-vis spectra.
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The dioxy products show a characteristic band around 250-260 nm for Co-→dioxime in the UV-vis spectra.
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50
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49349113259
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C(C=N) = δ(C=N complex) - δ(C=N free dioxime).
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C(C=N) = δ(C=N complex) - δ(C=N free dioxime).
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