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Volumn 27, Issue 14, 2008, Pages 3338-3345

Molecular oxygen insertion in benzylcobaloximes with mixed dioximes

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE COMPOUNDS; NONMETALS; OXYGEN;

EID: 49349114903     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om700938w     Document Type: Article
Times cited : (12)

References (50)
  • 35
    • 49349098150 scopus 로고    scopus 로고
    • SAINT, version 6.02; Bruker AXS, Madison, WI, 1999
    • SAINT+, version 6.02; Bruker AXS, Madison, WI, 1999.
  • 36
    • 49349083271 scopus 로고    scopus 로고
    • Sheldrick, G. M. , SADABS, Empirical Absorption Correction Program; University of Göttingen, Göttingen, Germany, 1997.
    • Sheldrick, G. M. , SADABS, Empirical Absorption Correction Program; University of Göttingen, Göttingen, Germany, 1997.
  • 37
    • 49349083128 scopus 로고    scopus 로고
    • XPREP, version 5.1; Siemens Industrial Automation Inc, Madison, WI, 1995
    • XPREP, version 5.1; Siemens Industrial Automation Inc., Madison, WI, 1995.
  • 39
    • 49349083127 scopus 로고    scopus 로고
    • Sheldrick, G. M. SHELXL-97, Program for Crystal Structure Refinement; University of Göttingen, Göttingen, Germany, 1997.
    • Sheldrick, G. M. SHELXL-97, Program for Crystal Structure Refinement; University of Göttingen, Göttingen, Germany, 1997.
  • 42
    • 49349100912 scopus 로고    scopus 로고
    • The torsion angle (τ) is the angle between two virtual planes that bisects the cobaloxime plane. Each plane is formed by considering the middle point of the C-C bond of two oxime units that passes through cobalt and pyridine nitrogen
    • The torsion angle (τ) is the angle between two virtual planes that bisects the cobaloxime plane. Each plane is formed by considering the middle point of the C-C bond of two oxime units that passes through cobalt and pyridine nitrogen.
  • 43
    • 49349099608 scopus 로고    scopus 로고
    • The dihedral angle (butterfly bending angle, α) is the angle between two dioxime planes of each cobaloxime unit
    • The dihedral angle (butterfly bending angle, α) is the angle between two dioxime planes of each cobaloxime unit.
  • 48
    • 49349091694 scopus 로고    scopus 로고
    • 2B, where R is an organic group σ-bonded to cobalt, B is an axial base trans to the organic group, and L is a monoanionic dioxime ligand (e.g., glyoxime (gH), dimethylglyoxime (dmgH), 1,2-cyclohexanedione dioxime (chgH), diphenylglyoxime (dpgH), and dimesitylglyoxime (dmestgH)).
    • 2B, where R is an organic group σ-bonded to cobalt, B is an axial base trans to the organic group, and L is a monoanionic dioxime ligand (e.g., glyoxime (gH), dimethylglyoxime (dmgH), 1,2-cyclohexanedione dioxime (chgH), diphenylglyoxime (dpgH), and dimesitylglyoxime (dmestgH)).
  • 49
    • 49349100086 scopus 로고    scopus 로고
    • The dioxy products show a characteristic band around 250-260 nm for Co-→dioxime in the UV-vis spectra.
    • The dioxy products show a characteristic band around 250-260 nm for Co-→dioxime in the UV-vis spectra.
  • 50
    • 49349113259 scopus 로고    scopus 로고
    • C(C=N) = δ(C=N complex) - δ(C=N free dioxime).
    • C(C=N) = δ(C=N complex) - δ(C=N free dioxime).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.