Peculiarities in atom transfer radical copolymerization

ACS Symposium Series

Volumn 854, Issue , 2003, Pages 180-192

  Klumperman, Bert ^a   Chambard, Grégory ^b   Brinkhuis, Richard H G ^c  

^a EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

^b DOW Chemical   (Netherlands)

^c AKZO NOBEL CENTRAL RESEARCH   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 49249121938     PISSN: 00976156     EISSN: None     Source Type: Book Series    
DOI: 10.1021/bk-2003-0854.ch013     Document Type: Conference Paper

References (21)

1. Matyjaszewski, K.; Ziegler, M. J.; Arehart, S. V.; Greszta, D.; Pakula, T., J. Phys. Org. Chem. 2000, 13, 775
2. Ziegler, M. J.; Matyjaszewski, K., Macromolecules 2001, 34, 415
3. Haddleton, D. M.; Crossman, M. C.; Hunt, K. H.; Topping, C.; Waterson, C.; Suddaby, K. G., Macromolecules 1997, 30, 3992
4. Matyjaszewski, K., Macromolecules 2002, 55, 6773
5. Galbraith, M.N.; Moad, G.; Solomon, D.H.; Spurting, T.H., Macromolecules 1987, 20, 675
6. Arehart, S. V.; Matyjaszewski, K., Macromolecules 1999, 32, 2221;
7. Dubé, M.A.; Penlidis, A.; O'Driscoll, K.F., Can. J. Chem. Eng. 1990, 68, 974
8. Mayo, F.R.; Lewis, F.M., J. Am. Chem. Soc. 1944, 66,1594
9. Skeist, I., J. Am. Chem. Soc. 1946, 68, 1781
10. Fukuda, T.; Ma, Y.D.; Inagaki, H., Macromolecules 1985, 18, 17
11. Zytowski, T.; Knühl, B.; Fischer, H. Helv. Chim. Acta 2000, 83, 658
12. Buback, M.; Gilbert, R.G.; Hutchinson, R.A.; Klumperman, B.; Kuchta, R.-D.; Manders, B.G.; O'Driscoll, K.F.; Russell, G.T.; Schweer, J. Macromol. Chem. Phys. 1995, 196, 3267
13. Manders, B.G. Ph.D. thesis; Technische Universiteit Eindhoven: Eindhoven, 1997; Chapter 5
14. Chambard, G.; Klumperman, B.; German, A.L., Macromolecules 2000, 33, 4417
15. Chambard, G. Ph.D. thesis; Technische Universiteit Eindhoven: Eindhoven, 2000 (ISBN 90-386-2622-3); Chapter 4
16. Chambard, G. Ph.D. thesis; Technische Universiteit Eindhoven: Eindhoven, 2000 (ISBN 90-386-2622-3); Chapter 5
17. 1/2 ≈ 100 hrs).
18. Value based on work by de Kock, J.B.L. (Ph.D. thesis; Technische Universiteit Eindhoven: Eindhoven, 1999 (ISBN 90-386-2701-7)
19. Borman, C.D.; Jackson, A.T.; Bunn, A.; Cutter, A.L.; Irvine, D.J., Polymer 2000, 47, 6015
20. Brinkhuis, R.H.G.; Klumperman, B. - to be published
21. The Br end group from a methacrylate chain end is lost during the MALDI-experiment. The fact that we mainly see intact chains, with the Br end group still present is attributed to the large fraction of acrylate chain end dormant species. From the simulations we were able to estimate that around 93% of all dormant chains contain an acrylate as the terminal unit.