Synthesis and stereochemistry of (-)-rosiridol and (-)-rosiridin

Tetrahedron Letters

Volumn 49, Issue 39, 2008, Pages 5580-5582

  Schöttner, Elisabeth ^a   Simon, Kristina ^a   Friedel, Manuel ^a   Jones, Peter G ^a   Lindel, Thomas ^a  

^a TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

Author keywords

DIP Cl; Monoterpenoids; Mosher method; Natural products; Prenyl nucleophiles

Indexed keywords

ROSIRIDIN; ROSIRIDOL; TERPENOID DERIVATIVE;

ARTICLE; GLYCOSYLATION; KOENIGS KNORR REACTION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; SYNTHESIS; X RAY ANALYSIS;

EID: 49149113369     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2008.07.018     Document Type: Article

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33. 1 0.029 (all data) for 5390 independent data and 380 parameters. The ethanol molecule was disordered over two positions. The Flack parameter refined to 0.06 (10), thus determining the absolute configuration on the basis of the anomalous dispersion of oxygen. Crystallographic data (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-691291. Copies of the data can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: +44-(0)1223-336033 or e-mail: deposit@ccdc.camac.uk).