A hyper-cross-linked polystyrene with nano-pore structure

European Polymer Journal

Volumn 44, Issue 8, 2008, Pages 2516-2522

  Liu, Qing Quan ^a,b   Wang, Li ^a   Xiao, An Guo ^a   Yu, Hao Jie ^a   Tan, Qiao Hua ^a  

^a ZHEJIANG UNIVERSITY   (China)

^b HUNAN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Chloromethylated polystyrene (CMPS); Hyper cross linked polystyrene (HCLPS); Nano pore; Porogen; Swelling

Indexed keywords

CHEMICAL REACTIONS; COAL TAR; CONCENTRATION (PROCESS); MONOMERS; NANOPORES; NANOTECHNOLOGY; POLYMERS; PORE STRUCTURE; SPECIFIC SURFACE AREA; STYRENE; TOLUENE;

AVERAGE PORE SIZE; CHLOROMETHYL GROUPS; CHLOROMETHYLATED POLYSTYRENE (CMPS); CHLOROMETHYLATED POLYSTYRENES; CROSS-LINKED POLYSTYRENE; CROSS-LINKING DEGREE; CROSS-LINKING REACTIONS; CYCLOHEXANOL; DICHLOROETHANE; DIVINYL BENZENE; FEED VOLUME; FINAL PRODUCTS; FRIEDEL-CRAFTS CATALYST; HYPER-CROSS-LINKED POLYSTYRENE (HCLPS); NANO-PORE; POROGEN; SPECIFIC SURFACE AREAS; SUSPENSION POLYMERIZATIONS; SWELLING; SWELLING CAPACITIES; TOTAL PORE VOLUME; VINYL-BENZYL CHLORIDE;

POLYSTYRENES;

EID: 49149103078     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2008.05.033     Document Type: Article

References (26)

1. Davankov V.A., and Tsyurupa M.P. Structure and properties of hypercrosslinked polystyrene - the first representative of a new class of polymer networks. React Polym 13 (1990) 27-42
2. Tsyurupa M.P., and Davankov V.A. Porous structure of hypercrosslinked polystyrene: state-of-the-art mini-review. React Funct Polym 66 (2006) 768-779
3. Podlesnyuk V.V., Hradil J., and Králová E. Sorption of organic vapors by macroporous and hypercrosslinked polymeric adsorbents. React Funct Polym 42 (1999) 181-191
4. Veverka P., and Jerabek K. Influence of hypercrosslinking on adsorption and absorption on or in styrenic polymers. React Funct Polym 59 (2004) 71-79
5. Veverka P., and Jerabek K. Mechanism of hypercrosslinking of chloromethylated styrene-divinylbenzene copolymers. React Funct Polym 41 (1999) 21-25
6. Azanova V.V., and Hradil J. Sorption properties of macroporous and hypercrosslinked copolymers. React Funct Polym 41 (1999) 163-175
7. Penner N.A., and Nesterenko P.N. Application of neutral hydrophobic hypercrosslinked polystyrene to the separation of inorganic anions by ion chromatography. J Chromatogr A 884 (2000) 41-51
8. Kiseleva M.G., Radchenko L.V., and Nesterenko P.N. Ion-exchange properties of hypercrosslinked polystyrene impregnated with methyl orange. J Chromatogr A 920 (2001) 79-85
9. Pastukhov A.V., Tsyurupa M.P., and Davankov V.A. Hypercrosslinked polystyrene: a polymer in a non-classical physical state. J Polym Sci Part B: Polym Phys 37 (1999) 2324-2333
10. Lee J.Y., Wood C.D., Bradshaw D., Rosseinsky M.J., and Cooper A.I. Hydrogen adsorption in microporous hypercrosslinked polymers. Chem Commun (2006) 2670-2672
11. Germain J., Hradil J., Fréchet J.M.J., and Svec F. High surface area nanoporous polymers for reversible hydrogen storage. Chem Mater 18 (2006) 4430-4435
12. Tsyurupa M.P., and Davankov V.A. Hypercrosslinked polymers: basic principle of preparing the new class of polymeric materials. React Funct Polym 53 (2002) 193-203
13. Cjurupa M.P., Lalaev V.V., and Davankov V.A. Synthesis and some physico-chemical properties of macronet isoporous styrene polymers with cross-bridges of biphenylmethane type. Acta Polym 35 (1984) 451-455
14. Tsyurupa M.P., Lalaev V.V., and Davankov V.A. On reasons determining unusual properties of hypercrosslinked styrene polymers. Dikl AN SSSR 279 (1984) 156-162
15. Davankov V.A., Pastukhov A.V., and Tsyurupa M.P. Unusual mobility of hypercrosslinked polystyrene networks: swelling and dilatometric studies. J Polym Sci Part B: Polym Phys 38 (2000) 1553-1563
16. Davankov V.A., Tsyurupa M.P., and Rogozhin S.V. On factors determining the swelling ability of cross-linked polymers(II). Angew Makromol Chem 53 (1976) 19-27
17. Macintyre F.S., Sherrington D.C., and Tetley L.S. Synthesis of ultrahigh surface area monodisperse porous polymer nanospheres. Macromolecules 39 (2006) 5381-5384
18. Ahn J.H., Jang J.E., Oh C.G., Ihm S.K., Cortez J., and Sherrington D.C. Rapid generation and control of microporosity, bimodal pore size distribution, and surface area in Davankov-type hyper-cross-linked resins. Macromolecules 39 (2006) 627-632
19. Kangwansupamonkon W., Damronglerd S., and Kiatkamjornwong S. Effects of the crosslinking agent and diluents on bead properties of styrene-divinylbenzene copolymers. J Appl Polym Sci 85 (2002) 654-669
20. Okay O. Styrene-divinylbenzene copolymers VII. Stability of the porous structures formed in toluene-cyclohexanol mixtures. Angew Makromol Chem 157 (1988) 15-21
21. Okay O. Styrene-divinylbenzene copolymers VI. Porosity formation in the presence of toluene-cyclohexanol mixture as inert diluents. Angew Makromol Chem 157 (1988) 1-13
22. Pekcan O., Kaya D., and Okay O. Observation of critical opalescence in free radical crosslinking copolymerization of styrene and divinylbenzene by fluorescence method. Eur Polym J 35 (1999) 2025-2029
23. Macintyre F.S., and Sherrington D.C. Control of porous morphology in suspension polymerized poly(divinylbenzene) resins using oligomeric porogens. Macromolecules 37 (2004) 7628-7636
24. Okay O. Macroporous copolymer networks. Prog Polym Sci 25 (2000) 711-779
25. Erbay E., and Okay O. Pore memory of macroporous styrene-divinylbenzene copolymers. J Appl Polym Sci 71 (1999) 1022-1055
26. Fontanals N., Cortes J., Galia M., Marce R.M., Cormack P.A.G., Borrull F., et al. Synthesis of Davankov-type hypercrosslinked resins using different isomer compositions of vinylbenzyl chloride monomer, and application in the solid-phase extraction of polar compounds. J Polym Sci Part: A Polym Chem 43 (2005) 1718-1728