Electron paramagnetic resonance and crystallographic resolution of an axially compressed octahedral complex [Cu(terpyR8)2](ClO4)2 containing the C8 alkyl-chain ligand terpyR8; 4′-octoxy-2,2′:6′,2″-terpyridine

Inorganica Chimica Acta

Volumn 361, Issue 12-13, 2008, Pages 3453-3461

  Nielsen, Pia ^a   Toftlund, Hans ^a   Boas, John F ^b   Pilbrow, John R ^b   Moubaraki, Boujemaa ^b   Murray, Keith S ^b   Neville, Suzanne M ^b  

^a UNIVERSITY OF SOUTHERN DENMARK   (Denmark)

^b MONASH UNIVERSITY   (Australia)

Author keywords

Copper(II); EPR; Fluxional disorder; Long chain terpy ligand; Magnetism

Indexed keywords

BOND LENGTH; ELECTRON SPIN RESONANCE SPECTROSCOPY; GROUND STATE; HYDROGEN BONDS; LIGANDS; MAGNETISM; NITROGEN COMPOUNDS; PARAMAGNETIC RESONANCE; X RAY CRYSTALLOGRAPHY;

FLUXIONAL DISORDER; HYDROGEN BONDING INTERACTIONS; LONG CHAINS; OCTAHEDRAL COMPLEX; OCTAHEDRAL GEOMETRY; POLYCRYSTALLINE POWDERS; SPECTRUM CHARACTERISTIC; STRUCTURAL DISORDERS;

COPPER COMPOUNDS;

EID: 48849083243     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2008.02.054     Document Type: Article

References (24)

1. Halcrow M.A. J. Chem. Soc., Dalton Trans. (2003) 4375
2. Bridgeman A.J., Halcrow M.A., Jones M., Krausz E., and Solanki N.K. Chem. Phys. Lett. 314 (1999) 176
3. Folgado J.-V., Henke W., Allmann R., Stratemeier H., Beltrãn-Porter D., Rojo T., and Reinen D. Inorg. Chem. 29 (1990) 2035
4. Allmann R., Henke W., and Reinen D. Inorg. Chem. 17 (1978) 378
5. Solanski N.K., Leech M.A., McInnes E.J.L., Zhao J.P., Mabbs F.E., Feeder N., Howard J.A.K., Davies J.E., Rawson J.M., and Halcrow M.A. J. Chem. Soc., Dalton Trans. (2001) 2083
6. Solanski N.K., Leech M.A., McInnes E.J.L., Mabbs F.E., Howard J.A.K., Kilner C.A., Rawson J.M., and Halcrow M.A. J. Chem. Soc., Dalton Trans. (2002) 1295
7. Beddard G.S., Halcrow M.A., Hitchman M.A., de Miranda M.P., Simmons C.J., and Stratemeier H. Dalton Trans. (2003) 1028
8. Akita M., Hayami S., Inoue K., Kato K., Kaajiri R., Maeda Y., Mitani T., Osaka K., Shigeyoshi Y., and Takata M. Angew. Chem., Int. Ed. 44 (2005) 4899
9. Zhang W., Zhao F., Liu T., Yuan M., Wang Z.-M., and Gao S. Inorg. Chem. 46 (2007) 2541
10. Andres P.R., Lunkwitz R., Pabst G.R., Böhn K., Wouters D., Schmatloch S., and Schubert U.S. Eur. J. Org. Chem. 19 (2003) 3769
11. apex2 Software Package v. 1.27, Bruker AXS Inc., Madison, WI, USA, 2005.
12. Sheldrick G.M. sadabs: Program for Scaling and Correction of Area Detector Data (1997), University of Göttingen, Germany
13. Sheldrick G.M. sadabs: Program for Scaling and Correction of Area Detector Data (1997), University of Göttingen, Germany
14. Barbour L.J. x-seed (1999), University of Stellenbosch, South Africa
15. Sheldrick G.M. shelxl97 and shelxs97 (1997), University of Göttingen, Germany
16. Wertz J.E., Orton J.W., and Auzins P. Disc. Faraday Soc. 31 (1961) 140
17. Hanson G.R., Gates K.E., Noble C.J., Griffin M., Mitchell A., and Benson S. J. Inorg. Biochem. 98 (2004) 903
18. Kahn O. Molecular Magnetism (1993), VCH, New York
19. Bebendorf J., Bürgi H.-B., Gamp E., Hitchman M.A., Murphy A., Reinen D., Riley M.J., and Stratemeier H. Inorg. Chem. 35 (1996) 7419
20. Halcrow M.A., Kilner C.A., Wolowska J., McInnes E.J.L., and Bridgeman A.J. New J. Chem. 28 (2004) 228
21. Henke W., and Reinen D. Z. Anorg. Allg. Chem. 438 (1977) 187
22. Abragam A., and Bleaney B. Electron Paramagnetic Resonance of Transition Ions (1970), Clarendon Press, Oxford pp. 465-466
23. Campbell R.F., and Freed J.H. J. Phys. Chem. 84 (1980) 2668
24. Bencini A., and Gatteschi D. Electron Paramagnetic Resonance of Exchange Coupled Systems (1990), Springer, Berlin