An integrated approach to electrochemical impedance spectroscopy

Electrochimica Acta

Volumn 53, Issue 25, 2008, Pages 7360-7366

  Orazem, Mark E ^a   Tribollet, Bernard ^b  

^a University of Florida   (United States)

^b CNRS   (France)

Author keywords

Error analysis; Impedance spectroscopy; Modeling

Indexed keywords

DESIGN OF EXPERIMENTS; ELECTROCHEMICAL CORROSION; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; ERRORS; FOOD PROCESSING; MODAL ANALYSIS; MODELS; NUMERICAL ANALYSIS; PHILOSOPHICAL ASPECTS; PLANNING; STRATEGIC PLANNING;

ELECTROCHEMICAL IMPEDANCE (EIS); EXPERIMENTAL DESIGN (ED); EXPERIMENTAL OBSERVATIONS; EXPERIMENTAL VERIFICATION; IMPEDANCE SPECTRUM; INTEGRATED APPROACH; MODEL DEVELOPMENT; MODEL SELECTIONS; PHYSICAL PRINCIPLES; REGRESSION (R2); SEQUENTIAL MODEL;

ERROR ANALYSIS;

EID: 48449106858     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.electacta.2007.10.075     Document Type: Article

References (25)

1. In: Macdonald J.R. (Ed). Impedance Spectroscopy: Emphasizing Solid Materials and Systems (1987), John Wiley & Sons, New York
2. In: Barsoukov E., and Macdonald J.R. (Eds). Impedance Sprectroscopy Theory, Experiment, and Applications. 2nd ed. (2005), Wiley-Interscience, New York
3. Huang Q.-A., Hui R., Wang B., and Zhang J. A review of ac impedance modeling and validation in SOFC diagnosis. Electrochim. Acta (2007) 8144
4. Orazem M.E., Agarwal P., and García-Rubio L.H. Critical issues associated with interpretation of impedance spectra. J. Electroanal. Chem. Interfacial Electrochem. 378 (1994) 51
5. Agarwal P., Orazem M.E., and García-Rubio L.H. Measurement models for electrochemical impedance spectroscopy: I. Demonstration of applicability. J. Electrochem. Soc. 139 7 (1992) 1917
6. Agarwal P., Crisalle O.D., Orazem M.E., and García-Rubio L.H. Measurement models for electrochemical impedance spectroscopy: 2. Determination of the stochastic contribution to the error structure. J. Electrochem. Soc. (1995) 4149
7. Agarwal P., Orazem M.E., and García-Rubio L.H. Measurement models for electrochemical impedance spectroscopy: 3. Evaluation of consistency with the kramers-kronig relations. J. Electrochem. Soc. 142 (1995) 4159
8. Orazem M.E. A systematic approach toward error structure identification for impedance spectroscopy. J. Electroanal. Chem. 572 (2004) 317
9. Dygas J.R., and Breiter M.W. Measurements of large impedances in a wide temperature and frequency range. Electrochim. Acta 41 7/8 (1996) 993
10. Gabrielli C., and Tribollet B. A transfer-function approach for a generalized electrochemical impedance spectroscopy. J. Electrochem. Soc. 141 (1994) 1147
11. Orazem M.E., Agarwal P., Jansen A.N., Wojcik P.T., and García-Rubio L.H. Development of physico-chemical models for electrochemical impedance spectroscopy. Electrochim. Acta 38 (1993) 1903
12. Jansen A.N., Wojcik P.T., Agarwal P., and Orazem M.E. Thermally-stimulated deep-level impedance spectroscopy: application to an n-GaAs Schottky diode. J. Electrochem. Soc. 143 (1996) 4066
13. Martin G.M., and Makram-Ebeid S. The mid-gap donor level el2 in GaAs. In: Pantelides S.T. (Ed). Deep Centers in Semiconductors (1986), Gordon and Breach Science Publishers, New York 455
14. Macdonald J.R. Power-law exponents and hidden bulk relaxation in the impedance spectroscopy of solids. J. Electroanal. Chem. 378 (1994) 17
15. Makharia R., Mathias M.F., and Baker D.R. Measurement of catalyst layer electrolyte resistance in PEFCs using electrochemical impedance spectroscopy. J. Electrochem. Soc. 152 5 (2005) A970
16. Antoine O., Bultel Y., and Durand R. Oxygen reduction reaction kinetics and mechanism on platinum nanoparticles inside Nafion. J. Electroanal. Chem. 499 (2001) 85
17. Bultel Y., Genies L., Antoine O., Ozil P., and Durand R. Modeling impedance diagrams of active layers in gas diffusion electrodes: diffusion, ohmic drop effects and multistep reactions. J. Electroanal. Chem. 527 (2002) 143
18. Roy S.K., Orazem M.E., and Tribollet B. Interpretation of low-frequency inductive loops in PEM fuel cells. J. Electrochem. Soc. 154 (2007) B1378
19. Roy S.K., and Orazem M.E. Error analysis for the impedance response of PEM fuel cells. J. Electrochem. Soc. 154 8 (2007) B883
20. Epelboin I., Gabrielli C., Keddam M., and Takenouti H. A model of the anodic behavior of iron in sulphuric acid medium. Electrochim. Acta 20 (1975) 913
21. Darling R.M., and Meyers J.P. Kinetic model of platinum dissolution in PEMFCs. J. Electrochem. Soc. 150 (2003) A1523
22. Zinola C.F., Rodriguez J., and Obal G. Kinetic of molecular oxygen electroreduction on platinum modified by tin underpotential deposition. J. Appl. Electrochem. 31 (2001) 1293
23. Damjanovic A., and Brusic V. Electrode kinetic of oxygen reduction on oxide-free Pt electrode. Electochim. Acta 12 (1967) 615
24. 2 involved in the membrane degradation mechanism in pemfc. Electrochem. Solid State Lett. 9 6 (2006) A229
25. Orazem M.E., Pébère N., and Tribollet B. A new look at graphical representation of impedance data. J. Electrochem. Soc. 153 (2006) B129