Co-crystallization of Co(II) with calcite: Implications for the mobility of cobalt in aqueous environments

Chemical Geology

Volumn 254, Issue 1-2, 2008, Pages 87-100

  Katsikopoulos, Dionisis ^a   Fernández González, Ángeles ^a   Prieto, Angel Carmelo ^b   Prieto, Manuel ^a  

^a UNIVERSITY OF OVIEDO   (Spain)

^b UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

Aragonite; Calcite; Miscibility gap; Partitioning; Solid solution; Sphaerocobaltite

Indexed keywords

AQUEOUS SOLUTION; ARAGONITE; CALCITE; CHEMICAL COMPOSITION; COBALT; CRYSTALLINITY; CRYSTALLIZATION; EXPERIMENTAL STUDY; FTIR SPECTROSCOPY; MOBILITY; PARTITIONING; PRECIPITATION (CHEMISTRY); SCANNING ELECTRON MICROSCOPY; SOLID SOLUTION; SOLUBILITY; SUPERSATURATION; X-RAY DIFFRACTION; ZONING;

EID: 48449105668     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemgeo.2008.06.003     Document Type: Article

References (52)

1. Allison J.D., Brown D.S., and Novo-Gradac K.J. MINTEQA2, a geochemical assessment model for environmental systems. Report EPA/600/3-91/0-21 (1991), U. S. Environmental Protection Agency, Athens, Georgia 107 pp.
2. 4) solid solution. Cryst. Growth Des. 5 (2005) 1371-1378
3. Anthony J.W., Bideaux R.A., Bladh K.W., and Nichols M.C. Handbook of mineralogy, Volume V. Borates, carbonates, sulfates (2003), Mineral Data Publishing, Tucson 813 pp.
4. Appelo C.A.J., and Postma D. Geochemistry, groundwater and pollution. (2nd edition) (2005), A. A. Balkema Publishers, Leiden 649 pp.
5. 4 prepared by thermal decomposition of basic cobalt carbonate. Electrochim. Acta 40 (1995) 2683-2686
6. Braybrook A.L., Heywood B.R., Jackson R.A., and Pitt K. Parallel computational and experimental studies of the morphological modification of calcium carbonate by cobalt. J. Cryst. Growth 243 (2002) 336-344
7. 3 (s) solid solutions. Geochim. Cosmochim. Acta 60 (1996) 933-940
8. 2+ incorporated at the calcite surface: an X-ray standing wave SEXAFS study. Phys. Rev. B 61 (2000) 4877-4883
9. Dal Negro A., and Ungaretti L. Refinement of the crystal structure of aragonite. Am. Mineral. 56 (1971) 768-772
10. Donaldson J.D., Clark S.J., and Grimes S.M. Cobalt in medicine, agriculture, and the environment. The Monograph Series (1986), Cobalt Development Institute, Guilford 155 pp.
11. Effenberger H., Mereiter K., and Zemann J. Crystal structure refinements of magnesite, calcite, rhodochrosite, siderite, smithonite, and dolomite, with discussion of some aspects of the stereochemistry of calcite type carbonates. Zeits. Krist. 156 (1981) 233-243
12. Egorov V.M., Ikornikova N.Y.u., and Lobachev A.N. Preparation and study of the sphaerocobaltite monocrystal solubility under hydrothermal conditions. J. Cryst. Growth 36 (1976) 138-146
13. Fernández-Díaz L., Astilleros J.M., and Pina C.M. The morphology of calcite crystals grown in a porous medium doped with divalent cations. Chem. Geol. 225 (2006) 314-321
14. Freij S.J., Putnis A., and Astilleros J.M. Nanoscale observations of the effect of cobalt on calcite growth and dissolution. J. Cryst. Growth 267 (2004) 288-300
15. Gamsjäger H., and Reiterer F. Investigation of equilibriums involving carbon dioxide, carbonates and water. Environ. Int. 2 (1979) 419-424
16. Glynn P.D. MBSSAS: a code for the computation of Margules parameters and equilibrium relations in binary solid-solution aqueous solution systems. Comput. Geosci. 17 (1991) 907-966
17. Glynn P.D. Solid-solution solubilities and thermodynamics: sulfates, carbonates and halides. In: Alpers C.N., Jambor J.L., and Nordstrom D.K. (Eds). Sulfate Minerals: Crystallography, Geochemistry and Environmental Significance. Mineralogical Society of America and Geochemical Society. Rev. Mineral. Geochem. vol. 40 (2000) 481-511
18. Glynn P.D., Reardon E.J., Plummer L.N., and Busenberg E. Reaction paths and equilibrium end-points in solid solution aqueous solution systems. Geochim. Cosmochim. Acta 54 (1990) 267-282
19. 3. J. Geol. 73 (1965) 817-829
20. Guggenheim E.A. The theoretical basis of Raoult's law. Trans. Faraday Soc. 33 (1937) 151-159
21. Henisch H.K. Crystals in gels and Liesegang's rings (1988), Cambridge University Press, Cambridge 197 pp.
22. Henisch H.K., and Garcia-Ruiz J.M. Crystal growth in gels and Liesegang ring formation. I. Diffusion relationships. J. Cryst. Growth 75 (1986) 195-202
23. IARC. Chlorinated drinking water, chlorination by-products, some other halogenated compounds, cobalt and cobalt compounds. IARC monographs on the evaluation of carcinogenic risks to humans vol. 52 (1991), World Health Organization, Lyon 544 pp.
24. 2+ interaction with calcite and aragonite surfaces. Chem. Geol. 53 (1985) 229-236
25. Köhler S., Cubillas P., Rodríguez-Blanco J.D., Bauer C., and Prieto M. Removal of cadmium from wastewaters by aragonite shells and the influence of other divalent cations. Env. Sci. Technol. 41 (2007) 112-118
26. Lippmann F. Phase diagrams depicting the aqueous solubility of mineral systems. Neues Jahrb. Mineral. Abh. 139 (1980) 1-25
27. Lorens R.B. Sr, Cd, Mn, and Co distribution coefficients in calcite as a function of calcite precipitation rate. Geochim. Cosmochim. Acta 45 (1981) 553-561
28. Oelkers E.H. Physical and chemical properties of rocks and fluids for chemical mass transport calculations. In: Lichtner P.C., Steefel C.I., and Oelkers E.H. (Eds). Reactive Transport in Porous Media. Rev. Mineral. vol. 34 (1996) 131-191
29. Palache C., Berman H., and Frondel C. The System of Mineralogy vol. 2 (1951), Wiley & Sons, New York 1124 pp.
30. Parkhurst D.L., and Appelo C.A.J. User's guide to PHREEQC (Version 2) - a computer program for speciation, batch-reaction, one-dimensional transport and inverse geochemical calculations. U. S. Geological Survey: Water-Resources Investigations Report 99-4259 (1999) 312 pp, online version.
31. Pertlik F. Structures of hydrothermally synthesized cobalt (II) carbonate and nickel (II) carbonate. Acta Cryst. 42 (1986) 4-5
32. Pina C.M., and Putnis A. The kinetics of nucleation of solid solutions from aqueous solutions: a new model for calculating non-equilibrium distribution coefficients. Geochim. Cosmochim. Acta 66 (2002) 185-192
33. Prieto M., Putnis A., Fernández-Díaz L., and Lopez-Andres S. Metastability in diffusing-reacting systems. J. Cryst. Growth 142 (1994) 225-235
34. 3 solid solutions from aqueous solutions. Geochim. Cosmochim. Acta 61 (1997) 3383-3397
35. Prieto M., Fernandez-Gonzalez A., Becker U., and Putnis A. Computing Lippmann diagrams from direct calculation of mixing properties of solid solutions: application to the barite-celestite system. Aquat. Geochem. 6 (2000) 133-146
36. Prieto M., Fernández-Gonzalez A., and Martín-Díaz R. Sorption of chromate ions diffusing through barite-hydrogel composites: implications for the fate and transport of chromium in the environment. Geochim. Cosmochim. Acta 66 (2002) 783-795
37. Prieto M., Astilleros J.M., Pina C.M., Fernández-Díaz L., and Putnis A. Comment: supersaturation in binary solid solution-aqueous solution systems. Am. J. Sci. 307 (2007) 1034-1045
38. Putnis A., Prieto M., and Fernández-Díaz L. Fluid supersaturation and crystallization in porous media. Geol. Mag. 132 (1995) 1-13
39. Redlich O., and Kister A.T. Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40 (1948) 345-348
40. Rimstidt J., Balog A., and Webb J. Distribution of trace elements between carbonate minerals and aqueous solutions. Geochim. Cosmochim. Acta 62 (1998) 1851-1863
41. Robie R.A., and Hemingway B.S. Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar pressure and at higher temperatures. U. S. Geol. Surv. Bull. 2131, U.S (1995), Government Printing Office, Washington 461 pp.
42. Robinson R.A., and Stokes R.H. Electrolyte solutions: the measurement and interpretation of conductance, chemical potential, and diffusion in solutions of simple electrolytes. 2nd edition (1959), Butterworth, London 559 pp.
43. Smith R.M., and Martell A.E. Critical stability constants. Inorganic Complexes vol. 4 (1976), Plenum Press, New York 257 pp.
44. Smith I.C., and Carson B.L. Trace metals in the environment. Cobalt vol. 6 (1981), Ann Arbor Science Pub., Ann Arbor 1202 pp.
45. 2O system. Geochim. Cosmochim. Acta 57 (1993) 2699-2713
46. Urusov V.S. Energy criteria for solid solution miscibility gap calculations. Bull. Soc. Fr. Mineral. Cristallogr. 97 (1974) 217-222
47. Verweij, W., 2005. Chemical Equilibria in Aquatic Systems-CHEAQS-PC Calculating Program. http://home.tiscali.nl/cheaqs/index.html.
48. Wada N., Yamashita K., and Umegaki T. Effects of divalent cations upon nucleation, growth and transformation of calcium carbonate polymorphs under conditions of double diffusion. J. Cryst. Growth 148 (1995) 297-304
49. Wolery T.J. EQ3/6, a software package for geochemical modeling of aqueous systems. Lawrence Livermore Nat. Lab. Report UCRL-MA-110662 Pt I-III, Livermore (1992) 246 pp.
50. X'Pert Plus v. 1.0, 1999. Program for Crystallography and Rietveld Analysis. Philips Analytical B. V., Almelo.
51. Xu N., Hochella M.F., Brown G.E., and Parks G.A. Co(II) sorption at the calcite water interface: I. X-ray photoelectron spectroscopic study. Geochim. Cosmochim. Acta 60 (1996) 2801-2815
52. Zachara J.M., Cowan C.E., and Resch C.T. Sorption of divalent metals on calcite. Geochim. Cosmochim. Acta 55 (1991) 1549-1562