Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol, and 3-methyl-2-buten-1-ol as a function of temperature

Journal of Atmospheric Chemistry

Volumn 59, Issue 3, 2008, Pages 187-197

  Rodriguez, Diana ^a   Rodriguez, Ana ^a   Soto, Amparo ^a   Aranda, Alfonso ^a   Diaz De Mera, Yolanda ^a   Notario, Alberto ^a  

^a UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

Author keywords

Alcohols; Atmospheric chemistry; Chlorine atoms; Gas phase reaction; Relative method; Temperature

Indexed keywords

2 BUTEN 1 OL; 2 METHYL 2 PROPEN 1 OL; 3 METHYL 2 BUTEN 1 OL; ALCOHOL DERIVATIVE; CHLORIDE; NITROGEN; POLITEF;

AIR TEMPERATURE; ATMOSPHERIC CHEMISTRY; ATMOSPHERIC PRESSURE; CHLORINE; IONIZATION; KINETICS; TEMPERATURE EFFECT;

ARTICLE; ATMOSPHERIC PRESSURE; GAS; GAS CHROMATOGRAPHY; KINETICS; TEMPERATURE;

EID: 48449094259     PISSN: 01677764     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10874-008-9101-6     Document Type: Article

References (36)

1. R. Atkinson 1997 Atmospheric reactions of alkoxy and β-hydroxyalkoxy radicals Int. J. Chem. Kinet. 29 99 111
2. R. Atkinson 2000 Atmospheric chemistry of VOCs and NOx Atmos. Environ. 34 2063 2101
3. Brasseur, G.P., Orlando, J.J., Tyndall, G.S.: Atmospheric chemistry and global change. Oxford University Press, New York (1999)
4. W.J. Bloss M.J. Evans J.D. Lee R. Sommariva D.E. Heard M.J. Pilling 2005 The oxidative capacity of the troposphere: coupling of field measurements of OH and a global chemistry transport model Farad. Disc. 130 425 436
5. 3 fluorinated alcohols and their wet deposition in the atmosphere Atmos. Environ. 37 4817 4822
6. 3 flourinated alcohols and their wet deposition in the atmosphere. Atmos. Environ. 37, 4817-4822 (2003)
7. S. Coquet P.A. Ariya 2000 Kinetics of the gas-phase reactions of Cl atom with selected C2-C5 unsaturated hydrocarbons at 283 < T < 323 K Int. J. Chem. Kinet. 32 478 488
8. M.J. Ezell W. Wang A.A. Ezell G. Soskin B.J. Fiynlayson-Pitts 2002 Kinetics of reactions of chlorine atoms with a series of alkenes at 1 atm and 298 K: Structure and reactivity Phys. Chem. Chem. Phys 1 5813 5820
9. 3 radicals, and Cl atoms Int. J. Chem. Kinet. 30 589 594
10. B.J. Finlayson-Pitts 1993 Chlorine atoms as a potential tropospheric oxidant in the marine boundary layer Res. Chem. Inter. 19 235 249
11. Finlayson-Pitts, B.J., Pitts, J.N.: Chemistry of the upper and lower. Atmosphere: theory, experiments and applications. Wiley, New York (2000)
12. E. Galan I. Gonzalez B. Fabbri 2002 Estimation of fluorine and chlorine emissions from Spanish structural ceramic industries. The case study of the Bailen area, Southern Spain Atmos. Environ. 36 5289 5298
13. E. Grosjean E. Grosjean 1994 Rate constants for the gas-phase reactions of ozone with unsaturated aliphatic alcohols Int. J. Chem. Kinet. 26 1185 1191
14. E. Grosjean D. Grosjean 1999 The reaction of unsaturated aliphatic oxygenates with ozone J. Atmos. Chem. 32 205 232
15. A.B. Guenther C.N. Hewitt D. Erickson R. Fall C. Geron R. Graedel P. Harley L. Klinger M. Lerdau W.A. Mckay T. Pierce B. Scholes R. Steinbrecher R. Tallamraju J. Taylor P. Zimmerman 1995 A global model of natural volatile organic compound emissions J. Geoph. Res. 100 8873 8892
16. T. Imamura Y. Iida K. Obi I. Nagatani K. Nakagawa I. Patroescu-klotz S. Hatakeyama 2004 Rate coefficients for the gas-phase reactions of OH radicals with methylbutenols at 298 K Int. J. Chem. Kinet. 36 379 385
17. 3 J. Phys. Chem. A. 100 4111 4119
18. E.W. Kaiser T.J. Wallington 1996 Kinetics of reactions of chlorine atoms with a series of alkenes at 1 at and 298K: structure and reactivity J. Phys. Chem. 100 9788
19. G. König M. Brunda H. Puxbaum C.N. Hewitt S.C. Duckham J. Rudolph 1995 Relative contribution of oxygenated hydrocarbons to the total biogenic VOC emissions of selected mid-European agricultural and natural plant species Atmos. Environ. 29 861 874
20. F.S.C. Lee F.S. Rowland 1977 Thermal chlorine-38 reactions with propene J. Phys. Chem. 81 1222
21. Z. Li A. Pirasteh 2006 Kinetic study of the reactions of atomic chlorine with several volatile organic compounds at 240-340 K Int. J. Chem. Kinet. 38 386 398
22. E. Martinez A. Aranda Y. Diaz-de-Mera A. Rodríguez D. Rodríguez A. Notario 2004 Mechanistic and kinetic study of the gas-phase reaction of atomic chlorine with cyclohexanone using an absolute and a relative technique; influence of temperature J. Atmos. Chem. 48 283 299
23. Noda, J., Hallquist, M., Langer, S., Ljungstrom, E.: Products from the gas-phase reaction of some unsaturated alcohols with nitrate radicals. Phys. Chem. Chem. Phys. 2555-2564 (2000)
24. Noda, J., Nyman, G., Langer, S.: Kinetics of the gas phase reactions of some unsaturated alcohols with nitrate radical. J. Phys. Chem. A. 106, 945-951 (2002)
25. J.J. Orlando G.S. Tyndall E.C. Apel D.D. Riemer S.E. Paulson 2003 Rate coefficients and mechanisms of the reaction of Cl-atoms with a series of unsaturated hydrocarbons under atmospheric conditions Int. J. Chem. Kinet. 35 334 353
26. C. Papagni J. Arey R. Atkinson 2001 Rate constants for the gas-phase reactions of OH radicals with a series of unsaturated alcohols Int. J. Chem. Kinet. 33 142 147
27. A.A.P. Pszenny W.C. Keene D.J. Jacob S. Fan J.R. Maben M.P. Zetwo M. Springer-Young J.N. Galloway 1993 Evidence of inorganic chlorine gas other than hydrogen-chloride in marine surface air Geoph. Res. Lett. 20 699 702
28. M.L. Ragains B.J. Finlayson-Pitts 1997 Kinetics and mechanism of the reaction of Cl atoms with 2-methyl-1,3-butadiene (isoprene) at 298 K J Phys. Chem. A. 101 1509 1517
29. A. Rodriguez D. Rodriguez A. Soto A. Notario A. Aranda Y. Diaz-de-Mera I. Bravo 2007 Relative rate measurements of reactions of unsaturated alcohols with atomic chlorine as a function of temperature Atmos. Environ. 41 4693 4702
30. H.B. Singh J.F. Kasting 1988 Chlorine-hydrocarbon photochemistry in the marine troposphere and lower stratosphere J. Atmos. Chem. 7 261 285
31. H.B. Singh A.N. Thakur Y.E. Chen 1996 Tetrachloroethylene as an indicator of low Cl atom concentrations in the troposphere Geoph. Res. Lett. 23 1529 1532
32. J. Stutz M.J. Ezell A.A. Ezell B.J. Finlayson-Pitts 1998 Rate constants and kinetic isotope effects in the reactions of atomic chlorine with n-butane and simple alkenes at room temperature J. Phys. Chem. A. 102 8510 8519
33. P.L. Tanaka S. Oldfield J.D. Neece C.B. Mullins D.T. Allen 1993 Anthropogenic sources of chlorine and ozone formation in urban atmospheres Environ. Sci. and Tech. 34 4470 4473
34. Wayne, R.P., Barnes, I., Biggs, P., Burrows, P.J., Canosa-Mas, C.E., Hjorth, J., Le Bras, G., Moortgat, G.K., Perner, D., Poulet, G., Restelli, G., Sidebottom, H.: In the nitrate radical: physics, chemistry, and the atmosphere. Air Pollution Research Report 31. C.E.C. Brussels (1990)
35. O.W. Wingenter M.K. Kubo N.J. Blake T.W. Smith D.R. Blake F.S. Rowland 1996 Hydrocarbon and halocarbon measurements as photochemical and dynamical indicators of atmospheric hydroxyl, atomic chlorine, and vertical mixing obtained during Lagrangian flights J. Geoph. Res. 101 4331 4340
36. J. Ziajka W. Pasiuk-Bronikowska 2003 Autoxidation of sulphur dioxide in the presence of alcohols under conditions related to the tropospheric aqueous phase Atmos. Environ. 37 3913 3922