Photocatalytic oxidation of gaseous 1,2-dichlorobenzene using photonic titania (inverse opal) on optical fibers in a monolith configuration

Separation and Purification Technology

Volumn 62, Issue 3, 2008, Pages 523-528

  Ren, M ^a   Valsaraj, K T ^a  

^a LOUISIANA STATE UNIVERSITY   (United States)

Author keywords

Dichlorobenzene degradation; Gas phase; Optical fibers; Photocatalytic monolith reactor; Photonic band gap titania

Indexed keywords

COLLOIDS; FABRICATION; FIBER OPTICS; FIBERS; FLOW RATE; FOG; GELATION; INVERSE PROBLEMS; LIGHT; OPTICAL DESIGN; OPTICAL FIBER FABRICATION; OPTICAL FIBERS; OPTICAL MATERIALS; PHOTOCATALYSIS; PHOTODEGRADATION; PHOTONIC BAND GAP; REACTION RATES; TITANIUM DIOXIDE; TITANIUM OXIDES; ULTRAVIOLET RADIATION;

ASYMPTOTIC VALUES; DICHLOROBENZENE; EXPERIMENTAL PARAMETERS; FEED FLOW RATES; FIBER DISTRIBUTION; INTRINSIC RATE CONSTANT; INVERSE OPALS; MACROPOROUS; MONOLITH REACTORS; OPTICAL (PET) (OPET); PHOTO-CATALYTIC OXIDATION (PCO); PHOTONIC; PHOTONIC-BAND-GAP (PBG); POLYSTYRENE (PS) TEMPLATES; REACTION RATE CONSTANTS; SEMI-BATCH; SOL-GEL CHEMISTRY; TITANIA; UV INTENSITY; UV LIGHT INTENSITY; UV-ABSORBANCE (UVA); X RAY DIFFRACTION (XRD);

RATE CONSTANTS;

EID: 48349132321     PISSN: 13835866     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.seppur.2008.02.029     Document Type: Article

References (34)

1. Yu J.C., Chan L.Y.L., and Krause P. Photocatalytic degradation of a gaseous organic pollutant. J. Chem. Edn. 75 (1998) 750-751
2. Voelker G., Kleinschmidt O., and Hesse D. Photocatalytic oxidation of gaseous pollutants with oxygen on semiconductor surfaces. Hungarian J. Ind. Chem. 26 (1998) 315-319
3. G. Lewandowski, M. Davis; D.F. Ollis, Photocatalytic oxidation of gas-phase aromatic contaminants, Mol. Supramol. Photochem. (2003) 249-282.
4. 2 electrodes: electrochemical production of OH radicals and oxidation of aqueous organic pollutants. Absracts of the 210th ACS National Meeting. Chicago, IL, August 20-24 (1995)
5. Gogate P.R., and Pandit A.B. A review of imperative technologies for wastewater treatment. 1. Oxidation technologies at ambient conditions. Adv. Environ. Res. 8 (2004) 505-551
6. 2 foam. Nano Lett. 3 (2003) 249-251
7. Hamaguchi T., Uno M., Kurosaki K., and Yamanaka S. Study on the formation process of titania nanohole arrays. J. Alloys Compd. 386 (2005) 265-269
8. 2 doped with Sn by auto-assembly method and photo-catalytic property. Sci. China Ser. B: Chem. 48 (2005) 436-441
9. Marinangelli R.E., and Ollis D.F. Photoassisted heterogeneous catalysis with optical fibers I. Isolated single fiber. AIChE J. 23 (1977) 415-426
10. 2-coated fiber-optic cable reactor: photocatalytic degradation of 4-chlorophenol. Environ. Sci. Technol. 29 (1995) 2974-2981
11. 2-coated fiber optic cable reactor. Environ. Sci. Technol. 30 (1996) 2806-2812
12. Joannopoulos J.D., Meade R.D., and Winn J.N. Photonic Crystals: Molding the Flow of Light (1995), Princeton University Press, Princeton, New Jersey
13. Wijnhoven J.E.G.J., and Vos W.L. Preparation of photonic crystals made of air spheres in Titania. Science 281 (1998) 802-804
14. Srinivasan M., and White T. Degradation of methylene blue by three-dimensionally ordered macroporous titania. Environ. Sci. Technol. 41 (2007) 4405-4409
15. Mihi A., Miguez H., Rodriguez I., Rubio S., and Meseguer F. Surface resonant modes in colloidal photonic crystals. Phys. Rev. B 71 12 (2005) 125131/1-125131/7
16. Tan Y., Qian W., Ding S., and Wang Y. Gold-nanoparticle-infiltrated polystyrene inverse opals: a three-dimensional platform for generating combined optical properties. Chem. Mater. 18 (2006) 3385-3389
17. 2 supplied as vapors and in aqueous solution under similar conditions. Environ. Sci. Technol. 30 (1996) 2014-2020
18. 2 nanofilm. Desalination 211 (2007) 1-9
19. Zhang H., Quan X., Chen S., Zhao H., and Zhao Y. Fabrication of photocatalytic membrane and evaluation its efficiency in removal of organic pollutants from water. Sep. Purif. Technol. 50 (2006) 147-155
20. Sharma R.K., and Celin M.S. Photodegradation of organic pollutants. Trends Wat. Poll. Res. (2005) 221-236
21. 2 photocatalysis. Appl. Catal. B: Environ. 39 (2002) 247-256
22. Ren M., Ravikrishna R., and Valsaraj K.T. Photocatalytic degradation of gaseous organic species on photonic band-gap titania. Environ. Sci. Technol. 40 (2006) 7029-7033
23. Jiang P., Gordana N., Narat R., Mittleman D.M., and Colvin V.L. The fabrication and bandgap engineering of photonic multilayers. Adv. Mater. 13 (2001) 389-393
24. Colvin V.L. Photonic band gap materials from opals. Glass Sci. Technol. 75 (2002) 51-53
25. Rodriguez I., Alienzen P., Manzano F.R., Mesegner F., Corma A., and Garcia H. Photonic crystals for applications in photoelectrochemical processes. Photoelectrochemical solar cells with inverse opal topology. Photonics Nanostuc. Fundam. Appl. 3 (2005) 148-154
26. Lin H.F., and Valsaraj K.T. Development of an optical fiber monolith reactor for photocatalytic wastewater treatment. J. Appl. Electrochem. 35 (2005) 699-708
27. Ollis D.F., Pelizzetti W., and Serpone N. Photocatalyzed destruction of water contaminants. Environ. Sci. Technol. 25 (1991) 1522-1529
28. 2 supported on glass bead. Appl. Catal. B 17 (1998) 313
29. Jacoby W.A., Blake D.M., Noble R.D., and Koval C.A. Kinetics of the oxidation of trichloroethylene in air via heterogeneous photocatalysis. J. Catal. 157 (1995) 87
30. Stein A., and Schroeden R.C. Colloidal crystal templating of 3-d ordered macroporous solids: materials for photonics and beyond. Curr. Opin. Solid State Mater. Sci. 5 (2001) 553-554
31. Manoharan V.N., Imhof A., Thorne J.D., and Pine D.J. Photonic crystals from emulsion templates. Adv. Mater. 13 (2001) 447-450
32. Chen J.I.L., Freyman G.V., Choi S.Y., Kitaev V., and Ozin G.A. Amplified photochemistry with solow photons. Adv. Mater. 18 (2006) 1915-1919
33. Chen J.I.L., Freyman G.V., Kitaev V., and Ozin G.A. Effect of disorder on the amplified photocatalytic activity of titania inverse opal. J. Am. Chem. Soc. 129 (2007) 1196-1202
34. Lin H.F., and Valsaraj K.T. Optical fiber monolith reactor for photocatalytic wastewater treatment: mathematical model and experimental validation. AIChE J. 52 (2006) 2271-2280