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Crystal data of 1, C6H14ClO12Eu, M r, 465.58, monoclinic, C2, a, 8.6786(6, b, 8.3965(6, c= 10.2153(7) Å, β=92.040(1)°, V= 743.92(9) Å3, Z=2, ρcalcd=2.079 Mg m-3, R1, 0.0508. wR2=0.1239, μ=4.448 mm-1, S, 1.043; Flack =0.04(5, Crystal data 2: C6H10D4ClO12Eu, Mr, 469.61, monoclinic, C2, a =8.689(2, b, 8.410(2, c, 10.224(3) Å. β, 92.057(4)°. V= 746.7(3) Å3, Z=2, ρcalcd, 2.089 Mg m-3, R1 =0.0465, wR2, 0.1150, μ, 4.432 mm-1, S, 1.058; Flack, 0.02(5, The structures were solved with direct methods by using the program SHELXTL Sheldrick. 1997, 10] All non-hydrogen atoms were located from the trial structure and refined anisotropically with SHELXTL by using fu
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[10] All non-hydrogen atoms were located from the trial structure and refined anisotropically with SHELXTL by using full-matrix least-squares procedures. The hydrogen and deuterium atom positions were fixed geometrically at calculated distances and allowed to ride on the parent carbon atoms. The final difference Fourier map was found to be featureless. CCDC 651944 (1) and 651945 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
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