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Volumn 27, Issue 13, 2008, Pages 2915-2917

Electronic structure of stable radicals of the heavy group 14 elements: UV-photoelectron spectroscopy characterization

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONIC STRUCTURE; MOLECULAR ORBITALS; MOLECULAR SPECTROSCOPY;

EID: 47949095874     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om7012925     Document Type: Article
Times cited : (19)

References (37)
  • 6
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    • Reviews on the stable radicals of the heavy group 14 elements: a
    • Reviews on the stable radicals of the heavy group 14 elements: (a) Power, P. P. Chem. Rev. 2003, 103, 789.
    • (2003) Chem. Rev , vol.103 , pp. 789
    • Power, P.P.1
  • 8
    • 48249121415 scopus 로고    scopus 로고
    • Moss, R. A, Platz, M. S, Jones, M, Jr, Eds, Wiley-Interscience: Hoboken, Chapter 2
    • (c) Lee, V. Ya.; Sekiguchi, A. In Reviews of Reactive Intermediate Chemistry; Moss, R. A., Platz, M. S., Jones, M., Jr., Eds.; Wiley-Interscience: Hoboken, 2007; Chapter 2.
    • (2007) Reviews of Reactive Intermediate Chemistry
    • Lee, V.Y.1    Sekiguchi, A.2
  • 17
    • 47949089469 scopus 로고    scopus 로고
    • Such ambiphilic (reductant/oxidant) behavior of the stable heavy group 14 element-centered radicals makes them unique organometallic reagents for the preparation of both anionic and cationic derivatives
    • Such ambiphilic (reductant/oxidant) behavior of the stable heavy group 14 element-centered radicals makes them unique organometallic reagents for the preparation of both anionic and cationic derivatives.
  • 18
    • 47949119938 scopus 로고    scopus 로고
    • The UV-PES spectra were recorded on a home-built, three-part spectrometer equipped with a spherical analyzer (Omicron, main body device (Meca2000, and He-I radiation source (Focus, For additional details, see the Supporting Information. It should be mentioned that all three radicals 1, 2, and 3 are thermally stable at the gas-phase conditions, since their mass spectra were successfully measured see ref 3
    • The UV-PES spectra were recorded on a home-built, three-part spectrometer equipped with a spherical analyzer (Omicron), main body device (Meca2000), and He-I radiation source (Focus). For additional details, see the Supporting Information. It should be mentioned that all three radicals 1, 2, and 3 are thermally stable at the gas-phase conditions, since their mass spectra were successfully measured (see ref 3).
  • 19
    • 47949133124 scopus 로고    scopus 로고
    • All computational details are given in the Supporting Information
    • All computational details are given in the Supporting Information.
  • 20
    • 0000912127 scopus 로고    scopus 로고
    • 3C is well-established by EPR spectroscopy: (a) Morehouse, R. L.; Christiansen, J. J.; Gordy, W. J. Chem. Phys. 1966, 45, 1751.
    • 3C is well-established by EPR spectroscopy: (a) Morehouse, R. L.; Christiansen, J. J.; Gordy, W. J. Chem. Phys. 1966, 45, 1751.
  • 25
    • 0001036290 scopus 로고    scopus 로고
    • 3Si radical, UV spectrum: (a) Lightfoot, P. D.; Becerra, R.; Jemi-Alade, A. A.; Lesclaux, R. Chem. Phys. Lett. 1991, 180, 441. EPR spectrum:
    • 3Si radical, UV spectrum: (a) Lightfoot, P. D.; Becerra, R.; Jemi-Alade, A. A.; Lesclaux, R. Chem. Phys. Lett. 1991, 180, 441. EPR spectrum:
  • 26
    • 47949129612 scopus 로고    scopus 로고
    • See ref 9
    • (b) See ref 9.
  • 31
    • 47949115615 scopus 로고    scopus 로고
    • Scheer, M.; Bilodeau, R. C.; Brodie, C. A.; Haugen, H. K. Phys. Rev. A 1998, 58, 2844. (b) CRC Handbook of Chemistry and Physics; Lide, D. R., Ed.; CRC Press: Boca Raton, 2006-2007; Chapter 10, pp 203 and 156.
    • (a) Scheer, M.; Bilodeau, R. C.; Brodie, C. A.; Haugen, H. K. Phys. Rev. A 1998, 58, 2844. (b) CRC Handbook of Chemistry and Physics; Lide, D. R., Ed.; CRC Press: Boca Raton, 2006-2007; Chapter 10, pp 203 and 156.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.