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Such ambiphilic (reductant/oxidant) behavior of the stable heavy group 14 element-centered radicals makes them unique organometallic reagents for the preparation of both anionic and cationic derivatives
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Such ambiphilic (reductant/oxidant) behavior of the stable heavy group 14 element-centered radicals makes them unique organometallic reagents for the preparation of both anionic and cationic derivatives.
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18
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47949119938
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The UV-PES spectra were recorded on a home-built, three-part spectrometer equipped with a spherical analyzer (Omicron, main body device (Meca2000, and He-I radiation source (Focus, For additional details, see the Supporting Information. It should be mentioned that all three radicals 1, 2, and 3 are thermally stable at the gas-phase conditions, since their mass spectra were successfully measured see ref 3
-
The UV-PES spectra were recorded on a home-built, three-part spectrometer equipped with a spherical analyzer (Omicron), main body device (Meca2000), and He-I radiation source (Focus). For additional details, see the Supporting Information. It should be mentioned that all three radicals 1, 2, and 3 are thermally stable at the gas-phase conditions, since their mass spectra were successfully measured (see ref 3).
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All computational details are given in the Supporting Information
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All computational details are given in the Supporting Information.
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