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84906407374
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One notable exception is BICs formed by double hydrophilic block copolymers containing polyion and nonionic water-soluble chains.1,2 Such BICs self-assemble into micelles with a polyion complex core and nonionic polymer shell, which can be stable in aqueous dispersion even at stoichiometric composition upon complete neutralization of charges
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1,2 Such BICs self-assemble into micelles with a polyion complex core and nonionic polymer shell, which can be stable in aqueous dispersion even at stoichiometric composition upon complete neutralization of charges.
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84906392440
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Such analysis is valid because all complexes showed linear dependence of, on the complex composition within the range 0≤Z≤0.3 data not shown
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Such analysis is valid because all complexes showed linear dependence of / on the complex composition within the range 0≤Z≤0.3 (data not shown).
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33
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84906364136
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Notably, the fluorescence quenching in the {PEVP/PS-b-PMANa + PS-WMA*Na system cannot not be explained by exchange of PS-b-PMA*Na chains between free micelles and BIC particles, since according to ref 34, such exchange is prohibited for PS-WMAA micelles in aqueous media. In other words, changes in fluoresce intensity in these systems are caused only by reaction II.
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Notably, the fluorescence quenching in the {PEVP/PS-b-PMANa) + PS-WMA*Na system cannot not be explained by exchange of PS-b-PMA*Na chains between free micelles and BIC particles, since according to ref 34, such exchange is prohibited for PS-WMAA micelles in aqueous media. In other words, changes in fluoresce intensity in these systems are caused only by reaction II.
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34
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0027624982
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35
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84906378431
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The average concentration of ionic groups [ionic groups]shell was calculated as XionicNw/[4/3N AπRh3 10-24- MPSN wXPS/1000ρ, where Xionic is the polymerization degree of the ionic block, Xps is the polymerization degree of the PS-block, NA is Avogadro's number, MPS, 104 g/mol is the molar mass of the PS unit,ρ= 1.04 g/cm3 is the density of polystyrene in a bulk, and Rh, is expressed in nanometers
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h, is expressed in nanometers.
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36
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0030143470
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Mays, J.W.4
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