Electrochemical lithium insertion in graphite containing dispersed tin-antimony alloys

Energy Conversion and Management

Volumn 49, Issue 9, 2008, Pages 2447-2454

  Billaud, Denis ^a   Nabais, Catarina ^a   Mercier, Cédric ^a   Schneider, Raphaël ^b   Willmann, Patrick ^c  

^a INSTITUT JEAN LAMOUR   (France)

^b Laboratoire de Chimie Physique et Microbiologie pour l'Environnement   (France)

^c CNES   (France)

Author keywords

Anode; Lithium metal storage; Lithium ion batteries; SnSb alloy

Indexed keywords

ALKALI METALS; ANTIMONY; GRAPHITE; LITHIUM; TIN; TITANIUM COMPOUNDS;

ELECTROCHEMICAL LITHIUM INSERTION; PHASE REDUCTION;

CARBON;

EID: 47549098268     PISSN: 01968904     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.enconman.2008.03.026     Document Type: Article

References (24)

1. Huggins R.A. Lithium alloy negative electrodes. J Power Sources 81-82 (1999) 13-19
2. Tirado J.L. Inorganic materials for the negative electrode of lithium-ion batteries: state-of-the-art and future prospects. Mater Sci Eng: R: Rep 40 (2003) 103-136
3. Needham S.A., Wang G.X., and Liu H.K. Electrochemical performance of SnSb and Sn/SnSb nanosize powders as anode materials in Li-ion cells. J Alloys Compd 400 (2005) 234-238
4. Yang J., Takeda Y., Imanishi N., and Yamamoto O. Ultrafine Sn and SnSb0.14 powders for lithium storage matrices in lithium-ion batteries. J Electrochem Soc 146 (1999) 4009-4013
5. Yang J., Winter M., and Besenhard J.O. Small particle size multiphase Li-alloy anodes for lithium-ion-batteries. Solid State Ionics 90 (1996) 281-287
6. x-based composite electrodes in solid polymer electrolytes. J Power Sources 90 (2000) 64-69
7. Yang J., Takeda Y., Imanishi N., Xie J.Y., and Yamamoto O. Intermetallic SnSbx compounds for lithium insertion hosts. Solid State Ionics 133 (2000) 189-194
8. Mukaibo H., Osaka T., Reale P., Panero S., Scrosati B., and Wachtler M. Optimized Sn/SnSb lithium storage materials. J Power Sources 132 (2004) 225-228
9. Trifonova A., Wachtler M., Winter M., and Besenhard J.O. Sn-Sb and Sn-Bi alloys as anode materials for lithium-ion batteries. Ionics 8 (2002) 321-328
10. Li H., Shi L., Wang Q., Chen L., and Huang X. Nano-alloy anode for lithium-ion batteries. Solid State Ionics 148 (2002) 247-258
11. 0.5 as Li-ion battery anodes. Carbon 41 (2003) 959-966
12. Besenhard J.O., Wachtler M., Winter M., Andreaus R., Rom I., and Sitte W. Kinetics of Li insertion into polycrystalline and nanocrystalline 'SnSb' alloys investigated by transient and steady state techniques. J Power Sources 81-82 (1999) 268-272
13. Wachtler M., Winter M., and Besenhard J.O. Anodic materials for rechargeable Li-batteries. J Power Sources 105 (2002) 151-160
14. Trifonova A., Wachtler M., Wagner M.R., Schroettner H., Mitterbauer C., Hofer F., et al. Influence of the reductive preparation conditions on the morphology and on the electrochemical performance of Sn/SnSb. Solid State Ionics 168 (2004) 51-59
15. 2Sb alloy encapsulated carbon microsphere anode materials for Li-ion batteries by carbothermal reduction of the oxides. Electrochim Acta 52 (2006) 1221-1225
16. Guo H., Zhao H., Jia X., Qiu W., and Cui F. Synthesis and electrochemical characteristics of Sn-Sb-Ni alloy composite anode for Li-ion rechargeable batteries. Mater Res Bull 42 (2007) 836-843
17. xSb anode material for secondary lithium-ion battery. J Alloys Compd 395 (2006) 192-200
18. Inaba M., Uno T., and Tasaka A. Irreversible capacity of electrodeposited Sn thin film anode. J Power Sources 46 (2005) 473-477
19. Dailly A., Schneider R., Billaud D., Fort Y., and Willmann P. New graphite-antimony composites as anodic materials for lithium-ion batteries: preparation, characterisation and electrochemical performance. Electrochim Acta 47 (2002) 4207-4212
20. 2 reduction in organic medium. Electrochim Acta 51 (2006) 3385-3390
21. Billaud D., Balan L., Schneider R., and Willmann P. The influence of the synthesis conditions of graphite/tin nanoparticle materials on their electrode electrochemical performance in Li-ion battery anodes. Carbon 44 (2006) 2508-2515
22. 4/AG) as the anode in a lithium ion battery. Tsinghua Sci Technol 10 (2005) 554-560
23. Liu Y., Xie J.Y., and Yang J. Morphology-stable alloy/C composites for lithium insertion. J Power Sources 119-121 (2003) 572-575
24. Billaud D, Jumas JC, Willmann P, Balan L, Dailly A, Olivier-Fourcade J, et al. Pinning effect for Sb nanoparticles grafted on various supports. In: Proceedings of the international meeting on lithium batteries 2006, Biarritz, France, 18-23 June 2006, Abstract No. 273.