Mononuclear, five-coordinate lanthanide amido and aryloxide complexes bearing tetradentate (N2O2) Schiff bases

Inorganic Chemistry

Volumn 43, Issue 20, 2004, Pages 6203-6214

  Schuetz, Steven A ^a   Silvernail, Carter M ^a   Incarvito, Christopher D ^b,c   Rheingold, Arnold L ^b,c   Clark, Joanna L ^a   Day, Victor W ^a   Belot, John A ^a  

^a UNIVERSITY OF NEBRASKA LINCOLN   (United States)

^b UNIVERSITY OF DELAWARE   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

2,6 BIS(TERT BUTYL) 4 METHYLPHENOL; [BIS 5,5' (1,3 PROPANEDIYLDIIMINO) 2,2 DIMETHYL 4 HEXEN 3 ONATO]ERBIUM[2,6 BIS(TERT BUTYL) 4 METHYLPHENOXIDE]; [BIS 5,5' (1,3 PROPANEDIYLDIIMINO) 2,2 DIMETHYL 4 HEXEN 3 ONATO]LANTHANIDE[BIS(TRIMETHYLSILYL)AMIDE]; [BIS 5,5' (1,3 PROPANEDIYLDIIMINO) 2,2 DIMETHYL 4 HEXEN 3 ONATO]SAMARIUM[2,6 BIS(TERT BUTYL) 4 METHYLPHENOXIDE]; ALCOHOL; AMIDE; CHELATE; CRESOL; EPSILON CAPROLACTONE; LACTIDE; LACTONE; LANTHANIDE; NITROUS OXIDE; OXIDE; SCHIFF BASE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; DEGRADATION; POLYMERIZATION; PURIFICATION; X RAY DIFFRACTION;

ALLYL COMPOUNDS; AMIDES; LANTHANOID SERIES ELEMENTS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; SCHIFF BASES; X-RAY DIFFRACTION;

EID: 4744366734     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic040006f     Document Type: Article

References (55)

1. (a) Dehnicke, K.; Greiner, A. Angew. Chem., Int. Ed. 2003, 42, 1340.
2. (b) Piers, W. E.; Emslie, J. J. H. Coord. Chem. Rev. 2002, 233-234, 131.
3. (c) Aspinall, H. C. Chem. Rev. 2002, 102, 1807.
4. (d) Roesky, P. W. Chem. Soc. Rev. 2000, 29, 335.
5. (e) Evans, W. J. New J. Chem. 1995, 19, 525.
6. (a) Giesbrecht, G. R.; Whitener, G. D.; Arnold, J. J. Chem. Soc., Dalton Trans. 2001, 923.
7. (b) Noss, H.; Oberthür, M.; Fischer, C.; Kretschmer, W. P.; Kempe, R. Eur. J. Inorg. Chem. 1999, 2283.
8. Estler, F.; Herdtweck, E.; Anwander, R. J. Chem. Soc., Dalton Trans. 2002, 3088.
9. Foley, T. J.; Abboud, K. A.; Boncella, J. M. Inorg. Chem. 2002, 41, 1704.
10. Neculai, A. M.; Roesky, H. W.; Neculai, D.; Magull, J. Organometallics 2001, 20, 5501.
11. (a) Schuetz, S. A.; Day, V. W.; Rheingold, A. L.; Belot, J. A. J. Chem. Soc., Dalton Trans. 2003, 22, 4303.
12. (b) Yu, L.-B.; Yao, Y.-M.; Shen, Q.; Zhang, J.; Wu, L.-X.; Ye, L. Chim. J. Chem. 2003, 21, 442.
13. (c) Schuetz, S. A.; Day, V. W.; Clark, J. L.; Belot, J. A. Inorg. Chem. Commun. 2002, 5, 706.
14. (d) Evans, W. J.; Fujimoto, C. H.; Ziller, J. W. Polyhedron 2002, 21, 1683.
15. (e) Schuetz, S. A.; Day, V. W.; Sommer, R. D.; Rheingold, A. L.; Belot, J. A. Inorg. Chem. 2001, 40, 5292.
16. (f) Evans, W. J.; Fujimoto, C. H.; Ziller, J. W. J. Chem. Soc., Chem. Commun. 1999, 311.
17. (g) Liu, Q.; Ding, M.; Lin, Y.; Xing, Y. Polyhedron 1998, 13-14, 2327.
18. (h) Liu, Q.; Ding, M. J. Organomet. Chem. 1998, 555, 179.
19. (i) Liu, Q.; Ding, M.; Lin, Y.; Xing, Y. Polyhedron, 1998, 17, 555.
20. (j) Dube, T.; Gambarotta, S.; Yap, G. Organometallics 1998, 17, 3967.
21. (k) Liu, Q.; Ding, M.; Lin, Y.; Xing, Y. J. Organomet. Chem. 1997, 548, 139.
22. Yamada, S. Coord. Chem. Rev. 1999, 190-192, 537.
23. (a) Cai, Y. P.; Ma, H. Z.; Kang, B. S.; Su, C. Y.; Zhang, W.; Sun, J.; Xiong, Y. L. J. Organomet. Chem. 2001, 628, 99.
24. (b) Blech, P.; Floriani, C.; Chiesivilla, A.; Guastini, C. J. Chem. Soc., Dalton Trans. 1990, 3557.
25. (a) Lin, M.-H.; RajanBabu, T. V. Org. Lett. 2002, 4, 1607.
26. (b) Runte, O.; Priermeier, T.; Anwander, R. J. Chem. Soc., Chem. Commun. 1996, 1385.
27. (a) McCarthy, P. J.; Martell, A. E. Inorg. Chem. 1967, 6, 781.
28. (b) McCarthy, P. J.; Hovey, R. J.; Ueno, K.; Martell, A. E. J. Am. Chem. Soc. 1955, 77, 5820.
29. 2O- and EtOH-free compound.
30. Adams, J. T.; Hauser, C. R. J. Am. Chem. Soc. 1944, 66, 1220.
31. (a) Anwander, R. Top. Curr. Chem. 1996, 179, 33.
32. (b) Anwander, R.; Runte, O.; Eppinger, J.; Gerstberger, G.; Herdtweck, E.; Spiegier, M. J. Chem. Soc., Dalton Trans. 1998, 847.
33. (a) Hessen, B. Presented at the 225th National Meeting of the American Chemical Society, New Orleans, LA, March 2003; paper INOR-919.
34. (b) Gagne, M. R.; Stern, C. L.; Marks, T. J. J. Am. Chem. Soc. 1992, 114, 275.
35. Daniele, S.; Hubert-Pfalzgraf, L. G.; Vaissermann, J. Polyhedron 2003, 22, 127.
36. Caulton, K. G.; Hubert-Pfalzgraf, L. G. Chem. Rev. 1990, 90, 969.
37. For the τ calculation and its significance in five-coordinate square-planar complexes, see: Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rijn, J.; Verschoor, G. C. J. Chem. Soc., Dalton Trans. 1984, 1349.
38. Throughout this manuscript, a standard formalism of crystallography- derived estimated standard deviations is used to provide a more concise, yet comprehensive, synopsis of metrical parameters. Hence, the first number in parentheses following an average value of a bond length is the rms estimated standard deviation of an individual datum. The second and third numbers are the average and maximum deviations from the average value, respectively. The fourth number represents the number of individual measurements included in the average values.
39. 2 plane, which is not the case in our systems; see Nathan, L. C.; Koehne, J. E.; Gilmore, J. M.; Hannibal, K. A.; Dewhirst, W. E.; Mai, T. D. Polyhedron 2003, 22, 887.
40. 3+⋯H-C interactions; see Gordon, J. C.; Giesbrecht, G. R.; Brady, J. T.; Clark, D. L.; Keogh, D. W.; Scott, B. L.; Watkin, J. G. Organometallics 2002, 21, 127.
41. 6 bridge of an achiral aluminum Salen, thereby facilitating the site-controlled mechanism of isotactic polylactide formation.
42. Atwood, D. A.; Harvey, M. J. Chem. Rev. 2001, 101, 37.
43. (b) Atwood, D. A.; Hill, M. S.; Jegier, J. A.; Rutherford, D. Organometallics 1997, 16, 2659.
44. Hitchcock, P. B.; Lappert, M. F.; Singh, A. J. Chem. Soc., Chem. Commun. 1983, 1499.
45. Clark, D. L.; Gordon, J. C.; Huffman, J. C.; Vincent-Hollis, R. L.; Watkin, J. G.; Zwick, B. D. Inorg. Chem. 1994, 55, 5903.
46. Katagiri, K.; Kameoka, M.; Nishiura, M.; Imamoto, T. Chem. Lett. 2002, 426.
47. Russo, M. R.; Kaltsoyannis, N.; Sella, A. Chem. Commun. 2002, 2458.
48. Mikuriya, M.; Minowa, K.; Lim, J.-W. Bull. Chem. Soc. Jpn. 2001, 74, 331.
49. Costes, J.-P.; Dahan, F.; Nicodème, F. Inorg. Chem. 2001, 40, 5285.
50. Aspinall, H. C.; Black, J.; Dodd, I.; Harding, M. M.; Winkley, S. J. J. Chem. Soc., Dalton Trans. 1993, 709.
51. Kepert, D. L. Prog. Inorg. Chem. 1979, 25, 41.
52. (a) Ovitt, T. M.; Coates, G. W. J. Am. Chem. Soc. 2002, 124, 1316.
53. (b) Aubrecht, K. B.; Hillmyer, M. A.; Tolman, W. B. Macromolecules 2002, 35, 644.
54. (c) O'Keefe, B. J.; Monnier, S. M.; Hillmyer, M. A.; Tolman, W. B. J. Am. Chem. Soc. 2001, 123, 339.
55. (d) Ovitt, T. M.; Coates, G. W. J. Polym. Sci., Part A: Polym. Chem. 2000, 38, 4686.