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Volumn 43, Issue 37, 2004, Pages 4944-4947

Diazene complexes of copper: Synthesis, spectroscopic analysis, and electronic structure

Author keywords

Copper; Density functional calculations; N ligands; Raman spectroscopy; Structure elucidation

Indexed keywords

ABSORPTION SPECTROSCOPY; CRYSTALLOGRAPHY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROBABILITY DENSITY FUNCTION; RAMAN SPECTROSCOPY; SPECTROSCOPIC ANALYSIS; SYNTHESIS (CHEMICAL);

EID: 4744351992     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200460415     Document Type: Article
Times cited : (28)

References (35)
  • 17
    • 33748637005 scopus 로고
    • a) T-Y. Cheng, A. Ponce, A. L. Rheingold, G. L. Hillhouse, Angew. Chem. 1994, 106, 703; Angew. Chem. Int. Ed. Engl. 1994, 33, 657;
    • (1994) Angew. Chem. Int. Ed. Engl. , vol.33 , pp. 657
  • 27
    • 4744342582 scopus 로고    scopus 로고
    • note
    • 2].[11]
  • 28
    • 4744374936 scopus 로고    scopus 로고
    • note
    • The new diazene complexes 1 and 2 exhibit satisfactory spectroscopic and analytical data (see Supporting Information).
  • 29
    • 4744372204 scopus 로고    scopus 로고
    • note
    • When a solution of 1 or 2 was warmed to above -40°C under an argon atmosphere the color of the solution slowly changed to green. The nature of the decomposition products was unclear. For this reason, the characterization of these complexes in solution (NMR and electronic absorption spectroscopy) was performed on the reaction mixtures.
  • 31
    • 4744372203 scopus 로고    scopus 로고
    • note
    • I centers in 1 and 2 is evident from the fact that no counterions are found in either of the crystal structures.
  • 32
    • 4744357491 scopus 로고    scopus 로고
    • note
    • 1H NMR spectroscopic data and X-ray crystallographic analysis indicated that triethylamine reacted only as a neutralizing agent.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.