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Volumn 37, Issue 19, 2004, Pages 7069-7071

Synthesis of poly(1,3-adamantane)s by cationic ring-opening polymerization of 1,3-dehydroadamantanes

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; MOLECULAR WEIGHT; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC SOLVENTS; POLYMERIZATION; SYNTHESIS (CHEMICAL); THERMOGRAVIMETRIC ANALYSIS;

EID: 4744339338     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma048925c     Document Type: Article
Times cited : (38)

References (30)
  • 13
    • 4744368735 scopus 로고    scopus 로고
    • note
    • The framework of poly(1,3-adamantane)s can be involved in the diamond lattice, as previously shown in ref 14.
  • 14
    • 4744372648 scopus 로고
    • Reinhardt, H. F. Polym. Lett. 1964, 2, 567. Through another synthetic route, insoluble poly(1,3-adamantane) was similarly obtained by the Wurtz-type coupling reaction of 3,3′-dibromo-1,1′-biadamantane with sodium in xylene.
    • (1964) Polym. Lett. , vol.2 , pp. 567
    • Reinhardt, H.F.1
  • 15
    • 0035803030 scopus 로고    scopus 로고
    • Ishizone, T.; Tajima, H.; Matsuoka, S.; Nakahama, S. Tetrahedron Lett. 2001, 42, 8645. Introduction of a butyl substituent was very effective to achieve the sufficient solubility of a series of oligo(1,3-adamantane)s.
    • (2001) Tetrahedron Lett. , vol.42 , pp. 8645
    • Ishizone, T.1    Tajima, H.2    Matsuoka, S.3    Nakahama, S.4
  • 16
    • 4744363462 scopus 로고    scopus 로고
    • note
    • 6, 75 MHz): 14.4 (Ca), 24.2 (Cb), 27.8 (Cc), 36.1 (01, 03), 37.8 (Cd), 42.6 (C6), 45.3 (C8, C10), 48.1 (C-2), 49.8 (C4, C9), 53.5 (C7), 64.4 (C5).
  • 17
    • 4744355689 scopus 로고    scopus 로고
    • note
    • 1-Acetoxyadamantanes, 1,3-adducts of acetic acid, and unreacted 1 or 2 were observed in the reaction mixture after quenching the polymerization with acetic acid.
  • 18
    • 4744338215 scopus 로고    scopus 로고
    • note
    • Even tetramer of adamantane is hardly soluble in any organic solvent. See ref 15.
  • 19
    • 4744361018 scopus 로고    scopus 로고
    • note
    • n: C, 89.49; H.; 10.51; found: C, 84.08; H, 9.98.
  • 20
    • 4744338219 scopus 로고    scopus 로고
    • note
    • n values became partially insoluble in THF but completely soluble in 1,2-dichlorobenzene at 80 °C.
  • 21
    • 4744340501 scopus 로고    scopus 로고
    • note
    • n: C, 88.35; H.; 11.65; found: C, 87.17; H, 11.47.
  • 23
    • 4744367400 scopus 로고    scopus 로고
    • note
    • Unpublished result. The molecular weight of poly(2) was independently estimated by the comparison with a series of oligo(5-butyl-l,3-adamantane)s synthesized by the Wurtz-type coupling reaction of 3-butyl-1-bromoadamantane or 5,5′-dibutyl-3-dibromo-1,1′-biadamantane.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.