Formal synthesis of (-)-frontalin through diastereoselective hydrocyanation of a β-keto sulfoxide

Synthesis

Volumn , Issue 13, 2008, Pages 2105-2109

  Ortiz, Benjamín ^a   Sánchez Obregón, Rubén ^a   Toscano, Rubén A ^a   Yuste, Francisco ^a  

^a UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

Author keywords

keto sulfoxides; Asymmetric synthesis; Chiral cyanohydrins; Diastereoselective hydrocyanation; Frontalin

Indexed keywords

CASE HARDENING; CYANIDES;

ASYMMETRIC SYNTHESIS; DIASTEREOSELECTIVE; DIASTEREOSELECTIVE SYNTHESIS; FORMAL SYNTHESIS; PINE BEETLES; SYNTHETIC SEQUENCES;

DIMETHYL SULFOXIDE;

4 (2,2,4 TRIMETHYL 1,3 DIOXOLAN 4 YL)BUTAN 1 OL; ALUMINUM DERIVATIVE; BETA KETO SULFOXIDE; BUTANOL; DIETHYLALUMINUM CYANIDE; FRONTALIN; GLUTARIC ACID DERIVATIVE; GLUTARIC ANHYDRIDE; SULFOXIDE;

ARTICLE; CYANATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 47349122149     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2008-1067120     Document Type: Article

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