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Volumn 112, Issue 11, 2008, Pages 4372-4377

Photo- and electrochemical properties of linked ferrocene and viologen donor-acceptor-type molecules and their application to electrochromic devices

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROOPTICAL DEVICES; IRON COMPOUNDS; OPTICAL PROPERTIES; SEMICONDUCTING CADMIUM TELLURIDE;

DONOR ACCEPTOR (D A); ELECTROCHROMIC; FERROCENE (FC); OPTICAL (PET) (OPET); VIOLOGEN;

ELECTROCHEMICAL PROPERTIES;

EID: 47149111428 PISSN: 19327447 EISSN: 19327455 Source Type: Journal
DOI: 10.1021/jp711103h Document Type: Article

Times cited : (37)

References (16)

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16
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- The validity of the analysis of the EC coloring/bleaching process using the simple graphical method was confirmed by solving the following diffusion equation, ∂[Fc-V+]/∂t, D ∂2[Fc- V+]/∂x2, K[Fc-V, Fc, V2, where K is the recombination rate constant of Fc-V+ and Fc, V2, Experimental data of ΔOD showed that the change with the time of the EC cell was best fitted by this equation when D, 3.8 x 10-7 cm2 s -1 and K, 65 M-1 s-1. Using these values, the concentration profiles of Fc- y+ Fc+-V 2, and Fc-V2+ in region (iii) were simulated, whereby we assumed that the diffusion constant of Fc-V+ is identical to that of Fc, V2, The concentration profiles obtained were almost ident
- -1 justifies the conclusion mentioned above.

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