Flammability properties of intumescent PLA starch and lignin

Polymers for Advanced Technologies

Volumn 19, Issue 6, 2008, Pages 628-635

  Reti C ^a   Casetta, Mathilde ^a   Duquesne, Sophie ^a   Bourbigot, S ^a   Delobel, R ^a  

^a Ecole Nationale Superieure de Chimie de Lille   (France)

Author keywords

Ammonium polyphosphate; Intumescent flame retardation; Lignin; Polylactic acid; Starch

Indexed keywords

AMMONIUM COMPOUNDS; CALORIMETERS; CALORIMETRY; CARBON FIBER REINFORCED PLASTICS; FLAME RETARDANTS; FLAME SPRAYING; FLAMMABILITY; LIGNIN; NONMETALS; OXYGEN; PUMPING PLANTS;

''GREEN'' COMPOSITES; AMMONIUM POLYPHOSPHATE (APP); BIORESOURCES; CONE CALORIMETERS; CONE CALORIMETRY (CC); FLAME RETARDANT PROPERTIES; FLAMMABILITY PROPERTIES; HEAT RELEASES; INTUMESCENT STRUCTURES; LIMITING OXYGEN INDEX (LOI); MIXTURE DESIGNS; PENTAERYTHRITOL (PER); POLY-LACTIC ACID (PLA);

STARCH;

FLAME RETARDANTS; FLAME SPRAYING; FLAMMABILITY; LIGNINS; NONMETALS; POLYETHYLENE; REINFORCED PLASTIC; STARCH;

CALORIMETRY; FLAME RESISTANCE; POLYLACTIC ACID; STARCH;

EID: 47149089341     PISSN: 10427147     EISSN: 10991581     Source Type: Journal    
DOI: 10.1002/pat.1130     Document Type: Article

References (22)

1. Solarski S, Ferreira M, Devaux E. Characterization of the thermal properties of PLA fibers by modulated differential scanning calorimetry. Polymer 2005; 46: 11187-11192.
2. Tokiwa Y, Calabia BP. Biodegradability and biodegradation of poly (lactide). Appl. Microbiol. Biotechnol. 2006; 72: 244-251.
3. Nishida H, Fan Y, Mori T, Oyagi N, Shirai Y, Endo T. Feedstock recycling of flame-resisting poly(lactic acid)/aluminum hydroxide composite to L,L-lactide. Ind. Eng. Chem. Res. 2005; 44: 1433-1437.
4. Kimura K, Horikoshi Y. Bio-based polymers. Fujitsu Sci. Tech. J. 2005; 41(2): 173-180.
5. Vandersall HL. Intumescent coating systems, their development and chemistry. J. Fire Flammab. 1971; 2: 97G.
6. Montaudo G, Scamporrino E, Vitali D. Intumescent flame retardants for polymers, the polypropylene-ammonium polyphosphate-polyurea system. J. Polym. Sci. Polym. Chem. 1983; 21(12): 3361-3371.
7. Camino G. Actes du ler Colloque Francophone sur l'ignifugation des Polymères, Martel J (ed). Saint-Denis, France, 1985; 36.
8. Duquesne S, Magnet S, Jama C, Delobel R. Intumescent paints: fire protective coatings for metallic substrates. Surf. Coat. Technol. 2004; 180/181: 302-307.
9. Riva A, Camino G, Fomperie L, Amiqouet P. Fire retardant mechanism in intumescent ethylene vinyl acetate compositions. Polym. Degrad. Stab. 2003; 82: 341-346.
10. Lewin M. In Physical and Chemical Mechanisms of Flame Retarding of Polymers. Fire Retardancy of Polymer, Le Bras M, Camino G, Bourbigot S, Delobel R (eds). The Royal Society of Chemistry: Cambridge, 1997.
11. Bourbigot S, Le Bras M, Delobel R, Decressain R, Amoureux JP. Synergistic effect of zeolite in an intumescent process: study of the carbonaceous structures using solid-state NMR. J. Chem. Soc. Faraday Trans. 1996; 92: 149-158.
12. Bourbigot S, Le Bras M, Delobel R, Bréant P, Trémillon JM. Fire retardant polymers. 5th European Conference, Salford, September, 1995.
13. Le Bras M, Bourbigot S, Le Tallec Y, Laureyns J. Synergy in intumescence-application to β-cyclodextrine carbonisation agent in intumescent additives for fire retardant polyethylene formulation. Polym. Degrad. Stab. 1997; 56: 11-21.
14. Standard Test Method for Measuring the Minimum Oxygen Concentration to Support Candle-like Combustion of Plastics, ASTM D2863/77, ASTM: Philadelphia, 1977.
15. Tests for Flammability of Plastic Materials for Part Devices and Appliances, ANSI/ASTM D635/77, Underwriters Laboratories: Northbrook, 1977.
16. Babrauskas V. Comparative rates of heat release from five different types of test apparatuses. J. Fire Sci. 1986; 4: 148-192.
17. Goupy J. Plans d'expériences: les mélanges Dunod: Paris, 2000.
18. Bourbigot S, Le Bras M, Gengembre L, Delobel R. XPS study of an intumescent coating, application to the ammonium polyphosphate/ pentaerythritol fire-retardant system. Appl. Surf. Sci. 1994; 81: 299-307.
19. Price D, Liu Y, Hull TR, Milnes GJ, Kandola BK, Horrocks AR. Burning behaviour of foam/cotton fabric combinations in the cone calorimeter. Polym. Degrad. Stab. 2002; 77: 213-220.
20. Lv P, Wang Z, Hu K, Fan W. Flammability and thermal degradation of flame retarded PP composites containing melamine phosphate and pentaerythritol derivatives. Polym. Degrad. Stab. 2005; 90: 523-534.
21. Zhang J, Jiang DD, Wilkie CA. Polyethylene and polypropylene nanocomposites based upon an oligomerically modified clay. Thermochim. Acta 2005; 430: 107-113.
22. Bourbigot S, Le Bras M, Delobel R. Fire retardant of an intumescent flame retardant PP using cone calorimeter. J. Fire Sci. 1995; 13(1): 3-22.