Tailoring longitudinal surface plasmon wavelengths, scattering and absorption cross sections of gold nanorods

ACS Nano

Volumn 2, Issue 4, 2008, Pages 677-686

  Ni, Weihai ^a   Kou, Xiaoshan ^a   Yang, Zhi ^a   Wang, Jianfang ^a  

^a CHINESE UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

Absorption; Dark field imaging; Extinction; Gold nanorods; Scattering; Surface plasmon resonance

Indexed keywords

ABSORPTION; ASPECT RATIO; CALCULATIONS; DIMENSIONAL STABILITY; FINITE DIFFERENCE TIME DOMAIN METHOD; GOLD; GOLD ALLOYS; NANORODS; NONLINEAR OPTICS; PLASMONS; SCATTERING;

ABSORPTION CROSS SECTIONS; AMERICAN CHEMICAL SOCIETY (ACS); DARK FIELD IMAGING (DFI); EXPERIMENTAL RESULTS; EXTINCTION COEFFICIENT (K); EXTINCTION RATIO (ER); FDTD CALCULATIONS; FINITE DIFFERENCE TIME DOMAIN (FDTD-3D); GANS THEORY; GOLD NANORODS (GNR); NANO RODS; SCATTERING AND ABSORPTION; SCATTERING INTENSITIES; SPECTRAL RANGES; SURFACE PLASMON (SP); SYSTEMATIC CHANGES;

NANOSTRUCTURES;

GOLD; NANOTUBE;

ARTICLE; CHEMICAL MODEL; CHEMISTRY; COMPUTER AIDED DESIGN; COMPUTER SIMULATION; CONFORMATION; CRYSTALLIZATION; LIGHT; MACROMOLECULE; MATERIALS TESTING; METHODOLOGY; NANOTECHNOLOGY; PARTICLE SIZE; RADIATION SCATTERING; REFRACTOMETRY; SURFACE PLASMON RESONANCE; SURFACE PROPERTY; ULTRASTRUCTURE;

COMPUTER SIMULATION; COMPUTER-AIDED DESIGN; CRYSTALLIZATION; GOLD; LIGHT; MACROMOLECULAR SUBSTANCES; MATERIALS TESTING; MODELS, CHEMICAL; MOLECULAR CONFORMATION; NANOTECHNOLOGY; NANOTUBES; PARTICLE SIZE; REFRACTOMETRY; SCATTERING, RADIATION; SURFACE PLASMON RESONANCE; SURFACE PROPERTIES;

EID: 46849119003     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn7003603     Document Type: Article

References (45)

1. Lee, K.-S.; El-Sayed, M. A. Dependence of the Enhanced Optical Scattering Efficiency Relative to That of Absorption for Gold Metal Nanorods on Aspect Ratio, Size, End-Cap Shape, and Medium Refractive Index. J. Phys. Chem. B 2005, 109, 20331-20338.
2. Jain, P. K.; Lee, K. S.; El-Sayed, I. H.; El-Sayed, M. A. Calculated Absorption and Scattering Properties of Gold Nanoparticles of Different Size, Shape, and Composition: Applications in Biological Imaging and Biomedicine. J. Phys. Chem. B 2006, 170, 7238-7248.
3. Chen, W. R.; Adams, R. L.; Carubelli, R.; Nordquist, R. E. Laser-Photosensitizer Assisted Immunotherapy: A Novel Modality for Cancer Treatment. Cancer Lett. 1997, 115, 25-30.
4. Gorelikov, I.; Field, L. M.; Kumacheva, E. Hybrid Microgels Photoresponsive in the Near-infrared Spectral Range. J. Am. Chem. Soc. 2004, 126, 15938-15939.
5. Karg, M.; Pastoriza-Santos, I.; Pérez-Juste, J.; Hellweg, T.; Liz-Marzán, L. M. Nanorod-Coated PNIPAM Microgels: Thermoresponsive Optical Properties. Small 2007, 3, 1222-1229.
6. Pérez-Juste, J.; Rodríguez-González, B.; Mulvaney, P.; Liz-Marzán, L. M. Optical Control and Patterning of Gold-Nanorod-Poly(vinyl alcohol) Nanocomposite Films. Adv. Funct. Mater. 2005, 15, 1065-1071.
7. Murphy, C. J.; Orendorff, C. J. Alignment of Gold Nanorods in Polymer Composites and on Polymer Surfaces. Adv. Mater. 2005, 17, 2173-2177.
8. Chon, J. W. M.; Bullen, C.; Zijlstra, P.; Gu, M. Spectral Encoding on Gold Nanorods Doped in a Silica Sol-Gel Matrix and Its Application to High-Density Optical Data Storage. Adv. Funct. Mater. 2007, 17, 875-880.
9. Berry, V.; Gole, A.; Kundu, S.; Murphy, C. J.; Saraf, R. F. Deposition of CTAB-Terminated Nanorods on Bacteria to Form Highly Conducting Hybrid Systems. J. Am. Chem. Soc. 2005, 127, 17600-17601.
10. Katz, E.; Willner, I. Integrated Nanoparticle-Biomolecule Hybrid Systems: Synthesis, Properties, and Applications. Angew. Chem., Int. Ed. 2004, 43, 6042-6108.
11. Sudeep, P. K.; Joseph, S. T. S.; Thomas, K. G. Selective Detection of Cysteine and Glutathione Using Gold Nanorods. J. Am. Chem. Soc. 2005, 127, 6516-6517.
12. Wang, H. F.; Huff, T. B.; Zweifel, D. A.; He, W.; Low, P. S.; Wei, A.; Cheng, J.-X. In Vitro and In Vivo Two-Photon Luminescence Imaging of Single Gold Nanorods. Proc. Natl. Acad. Sci. U.S.A. 2005, 102, 15752-15756.
13. Durr, N. J.; Larson, T.; Smith, D. K.; Korgel, B. A.; Sokolov, K.; Ben-Yakar, A. Two-Photon Luminescence Imaging of Cancer Cells Using Molecularly Targeted Gold Nanorods. Nano Lett. 2007, 7, 941-945.
14. Huang, X. H.; El-Sayed, I. H.; Qian, W.; El-Sayed, M. A. Cancer Cells Assemble and Align Gold Nanorods Conjugated to Antibodies to Produce Highly Enhanced, Sharp, and Polarized Surface Raman Spectra: A Potential Cancer Diagnostic Marker. Nano Lett. 2007, 7, 1591-1597.
15. Huang, X. H.; El-Sayed, I. H.; Qian, W.; El-Sayed, M. A. Cancer Cell Imaging and Photothermal Therapy in the Near-infrared Region by Using Gold Nanorods. J. Am. Chem. Soc. 2006, 128, 2115-2120.
16. Chen, C.-C.; Lin, Y.-P.; Wang, C.-W.; Tzeng, H.-C.; Wu, C.-H.; Chen, Y.-C.; Chen, C.-P.; Chen, L.-C.; Wu, Y.-C. DNA-Gold Nanorod Conjugates for Remote Control of Localized Gene Expression by Near Infrared Irradiation. J. Am. Chem. Soc. 2006, 128, 3709-3715.
17. Weissleder, R. A Clearer Vision for In Vivo Imaging. Nat. Biotechnol. 2001, 19, 316-317.
18. Hirsch, L. R.; Stafford, R. J.; Bankson, J. A.; Sershen, S. R.; Rivera, B.; Price, R. E.; Hazle, J. D.; Halas, N. J.; West, J. L. Nanoshell-Mediated Near-infrared Thermal Therapy of Tumors under Magnetic Resonance Guidance. Proc. Natl. Acad. Sci. U.S.A. 2003, 100, 13549-13554.
19. Loo, C.; Lowery, A.; Halas, N.; West, J.; Drezek, R. Immunotargeted Nanoshells for Integrated Cancer Imaging and Therapy. Nano Lett. 2005, 5, 709-711.
20. Chen, J. Y.; Saeki, F.; Wiley, B. J.; Cang, H.; Cobb, M. J.; Li, Z.-Y.; Au, L.; Zhang, H.; Kimmey, M. B.; Li, X. D.; Xia, Y. N. Gold Nanocages: Bioconjugation and Their Potential Use as Optical Imaging Contrast Agents. Nano Lett. 2005, 5, 473-477.
21. Jana, N. R.; Gearheart, L.; Murphy, C. J. Wet Chemical Synthesis of High Aspect Ratio Cylindrical Gold Nanorods. J. Phys. Chem. B 2001, 105, 4065-4067.
22. Kim, F.; Song, J. H.; Yang, P. D. Photochemical Synthesis of Gold Nanorods. J. Am. Chem. Soc. 2002, 124, 14316-14317.
23. Busbee, B. D.; Obare, S. O.; Murphy, C. J. An Improved Synthesis of High-Aspect-Ratio Gold Nanorods. Adv. Mater. 2003, 15, 414-416.
24. Pérez-Juste, J.; Liz-Marzán, L. M.; Carnie, S.; Chan, D. Y. C.; Mulvaney, P. Electric-Field-Directed Growth of Gold Nanorods in Aqueous Surfactant Solutions. Adv. Funct. Mater. 2004, 14, 571-579.
25. Nikoobakht, B.; El-Sayed, M. A. Preparation and Growth Mechanism of Gold Nanorods (NRs) Using Seed-Mediated Growth Method. Chem. Mater. 2003, 15, 1957-1962.
26. Sau, T. K.; Murphy, C. J. Seeded High Yield Synthesis of Short Au Nanorods in Aqueous Solution. Langmuir 2004, 20, 6414-6420.
27. Kou, X. S.; Zhang, S. Z.; Tsung, C.-K.; Yeung, M. H.; Shi, Q. H.; Stucky, G. D.; Sun, L. D.; Wang, J. F.; Yan, C. H. Growth of Gold Nanorods and Bipyramids Using CTEAB Surfactant. J. Phys. Chem. B 2006, 110, 16377-16383.
28. Kou, X. S.; Zhang, S. Z.; Tsung, C.-K.; Yang, Z.; Yeung, M. H.; Stucky, G. D.; Sun, L. D.; Wang, J. F.; Yan, C. H. One-Step Synthesis of Large-Aspect-Ratio Single-Crystalline Gold Nanorods by Using CTPAB and CTBAB Surfactants. Chem. - Eur. J. 2007, 13, 2929-2936.
29. Tsung, C.-K.; Kou, X. S.; Shi, Q. H.; Zhang, J. P.; Yeung, M. H.; Wang, J. F.; Stucky, G. D. Selective Shortening of Single-Crystalline Gold Nanorods by Mild Oxidation. J. Am. Chem. Soc. 2006, 128, 5352-5353.
30. Kou, X. S.; Zhang, S. Z.; Yang, Z.; Tsung, C.-K.; Stucky, G. D.; Sun, L. D.; Wang, J. F.; Yan, C. H. Glutathione- and Cysteine-Induced Transverse Overgrowth on Gold Nanorods. J. Am. Chem. Soc. 2007, 129, 6402-6404.
31. Zweifel, D. A.; Wei, A. Sulfide-Arrested Growth of Gold Nanorods. Chem. Mater. 2005, 17, 4256-4261.
32. Zhang, S. Z.; Kou, X. S.; Yang, Z.; Shi, Q. H.; Stucky, G. D.; Sun, L D.; Wang, J. F.; Yan, C. H. Nanonecklaces Assembled from Gold Rods, Spheres, and Bipyramids. Chem. Commun. 2007, 1816-1818.
33. Liao, H. W.; Hafner, J. H. Gold Nanorod Bioconjugates. Chem. Mater. 2005, 77, 4636-4641.
34. Orendorff, C. J.; Murphy, C. J. Quantitation of Metal Content in the Silver-Assisted Growth of Gold Nanorods. J. Phys. Chem. B 2006, 110, 3990-3994.
35. Gans, R. Form of Ultramicroscopic Particles of Silver. Ann. Phys. (Leipzig) 1915, 47, 270-284.
36. Johnson, P. B.; Christy, R. W. Optical Constants of the Noble Metals. Phys. Rev. B 1972, 6, 4370-4379.
37. Link, S.; Mohamed, M. B.; El-Sayed, M. A. Simulation of the Optical Absorption Spectra of Gold Nanorods as a Function of Their Aspect Ratio and the Effect of the Medium Dielectric Constant. J. Phys. Chem. B 1999, 103, 3073-3077.
38. Gulati, A.; Liao, H. W.; Hafner, J. H. Monitoring Gold Nanorod Synthesis by Localized Surface Plasmon Resonance. J. Phys. Chem. B 2006, 110, 22323-22327.
39. Sönnichsen, C.; Franzl, T.; Wilk, T.; von Plessen, G.; Feldmann, J. Drastic Reduction of Plasmon Damping in Gold Nanorods. Phys. Rev. Lett. 2002, 88, 077402.
40. Sönnichsen, C.; Alivisatos, A. P. Gold Nanorods as Novel Nonbleaching Plasmon-Based Orientation Sensors for Polarized Single-Particle Microscopy. Nano Lett. 2005, 5, 301-304.
41. Mock, J. J.; Smith, D. R.; Schultz, S. Local Refractive Index Dependence of Plasmon Resonance Spectra from Individual Nanoparticles. Nano Lett. 2003, 3, 485-491.
42. McFarland, A. D.; Van Duyne, R. P. Single Silver Nanoparticles as Real-Time Optical Sensors with Zeptomole Sensitivity. Nano Lett. 2003, 3, 1057-1062.
43. Mie, G. A Contribution to the Optics of Turbid Media Special Colloidal Metal Solutions. Ann. Phys. (Leipzig) 1908, 25, 377-445.
44. Oubre, C.; Nordlander, P. Optical Properties of Metallodielectric Nanostructures Calculated Using the Finite Difference Time Domain Method. J. Phys. Chem. B 2004, 108, 17740-17747.
45. Oldenburg, A. L.; Hansen, M. N.; Zweifel, D. A.; Wei, A.; Boppart, S. A. Plasmon-Resonant Gold Nanorods as Low Backscattering Albedo Contrast Agents for Optical Coherence Tomography. Opt. Express 2006, 14, 6724-6738.