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Note that we excite both R2 and R3 at 375 nm, i.e, the larger ring is excited in the middle of the first absorption band, the smaller ring in the absorption tail. At room temperature, the spectral width of single polyphenylene chromophores has been shown to be comparable to the disorder see Müller, J. G, Lemmer, U, Raschke, G, Anni, M, Scherf, U, Lupton, J. M, Feldmann, J. Phys. Rev. Lett. 2003, 91, 267403, We therefore expect to be able to excite all chromophores of one polarization within the molecule with equal probability
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