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Volumn 47, Issue 11, 2008, Pages 4808-4816

Redox active cage for the electrochemical sensing of anions

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Indexed keywords


EID: 46749139962     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic800099j     Document Type: Article
Times cited : (40)

References (41)
  • 2
    • 0004091542 scopus 로고    scopus 로고
    • Bianchi, A, Bowman-James, K, García-Espaňa, E, Eds, Wiley-VCH: New York
    • (a) Supramolecular chemistry of anions; Bianchi, A., Bowman-James, K., García-Espaňa, E., Eds.; Wiley-VCH: New York, 1997;
    • (1997) Supramolecular chemistry of anions
  • 10
  • 29
    • 0001752768 scopus 로고    scopus 로고
    • The Cambridge Structural Database; a quarter of a million crystal structures and rising, Allen, F. H. Acta Crystallogr. 2002, B58, 380-388.
    • The Cambridge Structural Database; a quarter of a million crystal structures and rising, Allen, F. H. Acta Crystallogr. 2002, B58, 380-388.
  • 33
    • 46749154284 scopus 로고    scopus 로고
    • The supporting electrolyte (0.05 M [BU4N]PF6) exerts a dramatic effect on the stability of the [CoII(1, 5+⋯Cl]4+ inclusion complex. In fact, in the absence of electrolyte, significant spectral modifications were observed on titration with chloride; on non-linear least-squares treatment of spectrophotometric titration data, a log KII, 3.9 ± 0.1 was obtained. This value coincides with that previously determined in the case of the analogous [FeII(1)]5+⋯Cl]4+ inclusion complex in MeCN/H2O 4:1 v/v, log KII, 3.9 ± 0.1.5 Background effect on K values has probably to be ascribed to the competition for the receptor of the anion of the electrolyte PF6, in this case, which is present in a 1000-fold excess and more. Moreover, the competition by water for the cavity of the Co
    • 4·2MeCN salt, whose crystals had been grown in wet MeCN.
  • 37
    • 0021385770 scopus 로고    scopus 로고
    • Gustowski, D. A.; Echegoyen, L.; Goli, D. M.; Kaifer, A; Schultz, R. A; Gokel, G. W. J. Am. Chem. Soc. 1984, 106, 1633-1635.
    • (b) Gustowski, D. A.; Echegoyen, L.; Goli, D. M.; Kaifer, A; Schultz, R. A; Gokel, G. W. J. Am. Chem. Soc. 1984, 106, 1633-1635.
  • 40
    • 46749114434 scopus 로고    scopus 로고
    • Encyclopedia of Supramolecular Chemistry; Atwood, J. L., Steed, J., Eds.; Dekker: New York, 2004.
    • Encyclopedia of Supramolecular Chemistry; Atwood, J. L., Steed, J., Eds.; Dekker: New York, 2004.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.