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Ionic liquids were synthesized according to the procedures reported in the literature and their purity was confirmed by 1H NMR and TGA-DTA analysis.19 General Procedure for the Preparation of Sulfones: To a solution of Cu(OAc)2 (0.013 g, 10 mol, in ionic liquid (1 mL) and arylboronic acid (1 mmol, sodium sulfinate salt (1 mmol) was added and stirred at r.t. for 12 h. After completion of the reaction, as monitored by TLC, the crude product was extracted with Et2O (3 × 10 mL, The combined Et2O extracts were concentrated in vacuo and the resulting product was purified by column chromatography on silica gel with EtOAc-n-hexane (2:8) as eluent to afford the desired product. The products were characterized by comparison of their NMR and mass spectra with those reported in the literature.12c,14 The ionic liquid containing Cu(OAc)2 was dried under vacuum and preserved for the next run
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