What can we learn about the mechanisms of thermal decompositions of solids from kinetic measurements?

Journal of Thermal Analysis and Calorimetry

Volumn 92, Issue 3, 2008, Pages 967-983

  Galwey, A K ^a,b  

^a RHODES UNIVERSITY   (South Africa)

^b NONE   (United Kingdom)

Author keywords

Crystolysis reactions; Kinetics of reactions of solids; Mechanisms of solid reactions; Solid decompositions; Thermal decompositions of solids

Indexed keywords

ADDITION REACTIONS; ASSOCIATION REACTIONS; CHEMISTRY; DECOMPOSITION; EPITAXIAL GROWTH; FREE RADICAL POLYMERIZATION; IMAGE CODING; KINETICS; MECHANISMS; PYROLYSIS; RATE CONSTANTS; SOLID STATE REACTIONS; SOLIDS; THERMOGRAVIMETRIC ANALYSIS;

(E ,2E) THEORY; (PL) PROPERTIES; BUSINESS MEDIA; CRYSTOLYSIS; GENERAL (CO); HOMOGENEOUS REACTIONS; KINETIC (POLYM.); KINETIC ANALYSES; KINETIC DATA; KINETIC MEASUREMENTS; NUCLEATION AND GROWTH; RATE CONTROL (RC); RATE DATA; RATE MEASUREMENTS; REACTION CHEMISTRY; REACTION MECHANISMS; REACTION MODELLING; SCIENTIFIC DISCIPLINES; SELF-COOLING; SOLID STATE REACTIONS (SSR); SPRINGER (CO); VARIATIONS OF;

REACTION KINETICS;

EID: 46449118285     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-007-8413-0     Document Type: Article

References (89)

1. A. K. Galwey and M. E. Brown, Thermal Decomposition of Ionic Solids, Elsevier, Amsterdam 1999.
2. K. J. Laidler, J. Chem. Ed., 61 (1984) 494.
3. V. V. Boldyrev, Thermochim. Acta, 100 (1986) 315.
4. V. V. Boldyrev, J. Thermal Anal., 40 (1993) 1041.
5. V. V. Boldyrev, M. Bulens and B. Delmon, The Control of the Reactivity of Solids, Elsevier, Amsterdam 1979.
6. A. K. Galwey, Thermochim. Acta, 397 (2003) 249.
7. A. K. Galwey, Thermochim. Acta, 399 (2003) 1.
8. A. K. Galwey, Thermochim. Acta, 407 (2003) 93.
9. A. K. Galwey, Thermochim. Acta, 413 (2004) 139.
10. A. K. Galwey and M. E. Brown, Proc. R. Soc. London, A450 (1995) 501.
11. A. K. Galwey and M. Mortimer, Int. J. Chem. Kinet., 38 (2006) 464.
12. J. M. Thomas and G. D. Renshaw, J. Chem. Soc. A, (1967) 2058.
13. J. M. Thomas and G. D. Renshaw, Chem. Comm., (1968) 1247.
14. P. G. Fox and J. Soria-Ruiz, Proc. R. Soc. London, A314 (1970) 429.
15. V. V. Boldyrev, Thermochim. Acta, 388 (2002) 63.
16. V. V. Boldyrev, Thermochim. Acta, 443 (2006) 1.
17. A. K. Galwey and M. E. Brown, Thermochim. Acta, 386 (2002) 91.
18. V. V. Boldyrev, Yu. A. Gaponov, N. Z. Lyakhov, A. A. Politov, B. P. Tolochko, T. P. Shakhthneider and M. A. Sheromov, Nucl. Meth. Inst. Phys. Res., A261 (1987) 192.
19. W. E. Garner, Chemistry of the Solid State, Butterworth, London. 1955, Ch. 8.
20. A. K. Galwey, R. Spinicci and G. G. T. Guarini, Proc. R. Soc. London, A378 (1981) 477.
21. A. K. Galwey and P. W. M. Jacobs, Proc. R. Soc. London, A254 (1960) 455.
22. A. K. Galwey, Thermochim. Acta, 294 (1997) 205.
23. M. E. Brown, A. K. Galwey, M. A. Mohamed and H. Tanaka, Thermochim. Acta, 235 (1994) 255.
24. E. G. Prout and F. C. Tompkins, Trans. Faraday Soc., 40 (1944) 488.
25. F. H. Herbstein, M. Kapon and A. Weissman, J. Thermal Anal., 41 (1991) 303.
26. V. V. Boldyrev, Z. G. Vinokurova, L. N. Senchenko and B. G. Erenburg, Zh. Neorg. Khim., 15 (1970) 9.
27. A. K. Galwey, G. M. Laverty, N. A. Baranov and V. B. Okhotnikov, Phil. Trans. R. Soc. London, A347 (1994) 139.
28. A. K. Galwey, G. M. Laverty, N. A. Baranov and V. B. Okhotnikov, Phil. Trans. R. Soc. London, A347 (1994) 157.
29. A. K. Galwey and M. A. Mohamed, J. Chem. Soc., Faraday Trans. I, 81 (1985) 2503.
30. A. K. Galwey, P. J. Herley and M. A. Mohamed, J. Chem. Soc., Faraday Trans. I, 84 (1988) 729.
31. M. E. Brown and R. E. Brown, Thermochim. Acta, 357-358 (2000) 133.
32. D. Beruto and A. W. Searcy, J. Chem. Soc., Faraday Trans. I, 70 (1974) 2145.
33. T. Darroudi and A. W. Searcy, J. Phys. Chem., 85 (1981) 3971.
34. F. J. Wilburn, J. H. Sharp, D. M. Tinsley and R. M. McIntosh, J. Thermal Anal., 37 (1991) 2003.
35. F. J. Wilburn, J. H. Sharp, D. M. Tinsley and R. M. McIntosh, J. Thermal Anal., 37 (1991) 2021.
36. J. Zsakó and H. E. Arz, J. Thermal Anal., 6 (1974) 651.
37. P. K. Gallagher and D. W. Johnson, Thermochim. Acta, 14 (1976) 255.
38. A. K. Galwey, Thermochim. Acta, 413 (2004) 139.
39. T. B. Flanagan, J. W. Simons and P. M. Fichte, Chem. Comm., (1971) 370.
40. G. Bertrand, M. Lallemant and G. Watelle-Marion, J. Inorg. Nucl. Chem., 36 (1974) 1303.
41. G. Bertrand, M. Lallemant and G. Watelle-Marion, J. Inorg. Nucl. Chem., 40 (1978) 819.
42. B. V. L'vov, A. V. Novichikhin and A. O. Dyakov, Thermochim. Acta, 315 (1998) 169.
43. B. V. L'vov, Thermochim. Acta, 386 (2002) 1.
44. A. A. Christy, E. Nodland, A. K. Burnham, O. M. Kvalheim and B. Dahl, Appl. Spectr., 48 (1994) 561.
45. A. Glasner and M. Steinberg, J. Inorg. Nucl. Chem., 16 (1961) 279.
46. A. Glasner and M. Steinberg, J. Inorg. Nucl. Chem., 22 (1961) 39.
47. A. Glasner and M. Steinberg, J. Inorg. Nucl. Chem., 22 (1961) 156.
48. A. Glasner, E. Levy and M. Steinberg, J. Inorg. Nucl. Chem., 25 (1963) 1119.
49. A. Glasner, E. Levy and M. Steinberg, J. Inorg. Nucl. Chem., 25 (1963) 1415.
50. A. Glasner, E. Levy and M. Steinberg, J. Inorg. Nucl. Chem., 26 (1964) 1143.
51. A. K. Galwey and M. E. Brown, J. Chem. Soc., Faraday Trans. I, 78 (1982) 411.
52. D. Broadbent, D. Dollimore and J. Dollimore, J. Chem. Soc., A (1966) 1491.
53. C. E. H. Bawn, Chemistry of the Solid State, W. E. Garner, Ed., Butterworth, London 1955, Ch. 10.
54. S. D. Bhattamisra, G. M. Laverty, N. A. Baranov, V. B. Okhotnikov and A. K. Galwey, Phil. Trans. R. Soc. London, A341 (1992) 479.
55. N. J. Carr and A. K. Galwey, Proc. R. Soc. London, A404 (1986) 101.
56. A. K. Galwey and M. A. Mohamed, Thermochim. Acta, 239 (1994) 211.
57. A. K. Galwey, L. Pöppl and S. Rajam, J. Chem. Soc., Faraday Trans. I, 79 (1983) 2143.
58. A. K. Galwey and G. M. Laverty, Proc. R. Soc. London, A440 (1993) 77.
59. F. J. Gotor, J. M. Criado, J. Malek and N. Koga, J. Phys. Chem., A104 (2000) 10777.
60. A. K. Galwey, J. Thermal Anal. Cal., 86 (2006) 267.
61. A. K. Galwey, D. G. Bettany and M. Mortimer, Int. J. Chem. Kinet., 38 (2006) 689.
62. A. K. Galwey, J. Therm. Anal. Cal., 87 (2007) 601.
63. A. K. Galwey, J. Therm. Anal. Cal., 79 (2005) 219.
64. A. K. Galwey, J. Therm. Anal. Cal., 82 (2005) 23.
65. A. K. Galwey, J. Therm. Anal. Cal., 82 (2005) 423.
66. A. K. Galwey, J. Therm. Anal. Cal., 86 (2006) 561.
67. J. Rouquerol, Thermochim. Acta, 300 (1997) 247.
68. A. Ortega, S. Akhouayri, F. Rouquerol and J. Rouquerol, Thermochim. Acta, 163 (1990) 25.
69. A. Ortega, S. Akhouayri, F. Rouquerol and J. Rouquerol, Thermochim. Acta, 235 (1994) 197.
70. S. Vyazovkin, Int. Rev. Phys. Chem., 19 (2000) 45.
71. S. Vyazovkin and C. A. Wight, Chem. Mater., 11 (1999) 3386.
72. P. J. Skrdla and R. T. Robertson, J. Phys. Chem., B109 (2005) 10611.
73. P. J. Skrdla, J. Phys. Chem., B110 (2005) 11494.
74. P. J. Skrdla, Chem. Phys. Lett., 419 (2006) 130.
75. J. H. Taplin, J. Phys. Chem., 68 (1978) 3325.
76. A. K. Galwey and M. E. Brown, J. Therm. Anal. Cal., 60 (2000) 863.
77. A. K. Galwey and M. E. Brown, J. Therm. Anal. Cal., 90 (2007) 9.
78. B. V. L'vov, Thermochim. Acta, 373 (2001) 97.
79. B. V. L'vov, Spectrochim. Acta, B39 (1984) 149.
80. B. V. L'vov, Spectrochim. Acta, B52 (1997) 1.
81. B. V. L'vov, Spectrochim. Acta, B52 (1997) 1239.
82. B. V. L'vov, Spectrochim. Acta, B53 (1998) 809.
83. B. V. L'vov, Thermochim. Acta, 291 (1997) 179.
84. B. V. L'vov and A. V. Novichikhin, Thermochim. Acta, 290 (1997) 239.
85. B. V. L'vov, J. Therm. Anal. Cal., 84 (2006) 581.
86. B. V. L'vov, Thermal Decomposition of Solid and Liquid Substances, Polytech. University, St. Petersberg 2006.
87. B. V. L'vov, Thermal Decomposition of Solids and Melts, Springer, 2007.
88. W. E. Garner, Ed., Chemistry of the Solid State, Butterworth, London 1955.
89. S. Vyazovkin and T. Ozawa, Thermochim. Acta, 388 (2002) 1.