An unusual domino retro-ene-Conia reaction: Regio- and stereoselective one-carbon ring expansion of fenchol derivatives

Helvetica Chimica Acta

Volumn 87, Issue 8, 2004, Pages 1990-2021

  Rüedi, Georg ^a   Laikov, Dimitri N ^a   Hansen, Hans Jürgen ^a  

^a UNIVERSITY OF ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ISOMERIZATION; KETONES; PYROLYSIS; SUBSTRATES; THERMAL EFFECTS;

DEETHANATION REACTION; FENCHOL DERIVATIVES;

ALCOHOLS;

1 [1 METHYL 3 (1 METHYLETHENYL)CYCLOPENT 1 YL] 2 METHYLPROPAN 1 ONE; 1,3,3 TRIMETHYL 2 (1 METHYLETHENYL)BICYCLO[2.2.2]HEPTAN 2 OL; 1,3,3 TRIMETHYL 2 (1 METHYLPROP 1 EN 1 YL)BICYCLO[2.2.2]HEPTAN 2 OL; 1,3,3 TRIMETHYL 2 [(TRIMETHYLSILYL)ETHYNYL]BICYCLO[2.2.1]HEPTAN 2 OL; 1,3,3 TRIMETHYL 2 NORCAMPHANONE; 1,3,3 TRIMETHYL 2 PHENYLBICYCLO[2.2.2]HEPTAN 2 OL; 1,3,4 TRIMETHYLBICYCLO[3.2.1]OCT 3 EN 2 ONE; 2 ETHENYL 1,3,3 TRIMETHYLBICYCLO[2.2.1]HEPTAN 2 OL; 2 ETHYNYL 1,3,3 TRIMETHYLBICYCLO[2.2.2]HEPTAN 2 OL; [METHYL 3 (1 METHYLETHYL)CYCLOPENT 1 YL](PHENYL)METHANONE; ALCOHOL DERIVATIVE; ALKYNE DERIVATIVE; ALLYL COMPOUND; CARBON 13; CYCLOPENTANE DERIVATIVE; DEUTERIUM; FENCHOL DERIVATIVE; KETONE; METHYL GROUP; OCTANE; PENTANOL; PHENYL GROUP; PROPYLENE; RADICAL; UNCLASSIFIED DRUG;

ARTICLE; BAEYER VILLIGER REACTION; CARBON RING EXPANSION; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONFORMATION; CONIA REARRANGEMENT; DEETHANATION; DEHYDROGENATION; DOMINO RETRO ENE CONIA REACTION; DYNAMIC GAS PHASE THERMOISOMERIZATION; HIGH TEMPERATURE; ISOMERIZATION; ISOTOPE LABELING; MATHEMATICAL COMPUTING; NUCLEAR OVERHAUSER EFFECT; OPTICAL ROTATION; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; PYROLYSIS; REACTION ANALYSIS; RETRO ENE REACTION; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS; TAUTOMERIC SHIFT; THERMAL EXPOSURE; THERMODYNAMICS;

EID: 4644343629     PISSN: 0018019X     EISSN: None     Source Type: Journal    
DOI: 10.1002/hlca.200490180     Document Type: Article

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