Synthesis and characterization of μ-oxodiiron(III) complexes of porphycenes with electron-withdrawing substituents

Chemistry Letters

Volumn 33, Issue 7, 2004, Pages 906-907

  Baba, Tatsushi ^a   Shimakoshi, Hisashi ^a   Aritome, Isao ^a   Hisaeda, Yoshio ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BROMIDE; IRON COMPLEX; PORPHYRIN;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CRYSTAL STRUCTURE; ELECTROCHEMISTRY; ELECTRON; ELECTRON TRANSPORT; GEOMETRY; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; SUBSTITUTION REACTION; SYNTHESIS; X RAY ANALYSIS;

EID: 4644340169     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2004.906     Document Type: Article

References (13)

1. E. Vogel, M. Köcher, H. Schmickler, and J. Lex, Angew. Chem., Int. Ed. Engl., 25, 257 (1986).
2. T. Hayashi, K. Okazaki, N. Urakawa, H. Shimakoshi, J. L. Sessler, E. Vogel, and Y. Hisaeda, Organometallics, 20, 3074 (2001).
3. M. W. Grinstaff, M. G. Hill, J. A. Labinger, and H. B. Gray, Science, 264, 1311 (1994).
4. M. Lausmann, I. Zimmer, J. Lex, H. Lueken, K. Wieghardt, and E. Vogel, Angew. Chem., Int. Ed. Engl., 33, 736 (1994).
5. S. Will, A. Rahbar, H. Schmickler, J. Lex, and E. Vogel, Angew. Chem., Int. Ed. Engl., 29, 1390 (1990).
6. +, 715.7.
7. 2O: C, 49.32; H, 4.30; N, 7.01%. Two structural isomers, which are racemi- and meso-forms, were detected by HPLC analysis, but these two isomers could not be isolated.
8. 2O: C, 45.09; H, 4.08; N, 6.23%.
9. P. Bhyrappa and V. Krishnan, Inorg. Chem., 30, 239 (1991).
10. 2 = 0.0858 for 13376 observed reflections data [I > 2σ(I)]. GOF = 0.944. Data were collected on a Bruker SMART APEX CCD area-detector diffractometer with monochromated Mo Kα radiation. The details of the crystal data have been deposited with Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-235960.
11. 2O, respectively.
12. 13
13. C. Bernard, Y. Le Mest, and J. P. Gisselbrecht, Inorg. Chem., 37, 181 (1998).