On the ethylene-norbornene copolymerization mechanism

Macromolecular Symposia

Volumn 213, Issue , 2004, Pages 109-122

  Tritto, Incoronata ^a   Boggioni, Laura ^a   Sacchi, Maria Carmela ^a   Locatelli, Paolo ^a   Ferro, Dino R ^a  

^a CNR   (Italy)

Author keywords

13C NMR analysis; Copolymer microstructure; Ethylene norbornene copolymers; Living polymerization; Metallocene catalysts; Statistical models

Indexed keywords

CATALYSIS; CATALYSTS; COPOLYMERIZATION; COPOLYMERS; FREQUENCIES; MARKOV PROCESSES; MATHEMATICAL MODELS; MICROSTRUCTURE; NUCLEAR MAGNETIC RESONANCE; REACTION KINETICS;

CHAIN PROPAGATION; CHAIN TRANSFER; NORBORENE; STATISTICAL MODELS;

ETHYLENE;

ALUMINUM DERIVATIVE; COPOLYMER; ETHYLENE; METAL DERIVATIVE; METHYLALUMINOXANE; NORBORNENE DERIVATIVE; UNCLASSIFIED DRUG; ZIRCONOCENE;

CARBON NUCLEAR MAGNETIC RESONANCE; CATALYST; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CONCENTRATION (PARAMETERS); CONFERENCE PAPER; GEOMETRY; POLYMERIZATION; PROBABILITY; RACEMIC MIXTURE; REACTION ANALYSIS; STATISTICAL MODEL; SYNTHESIS;

EID: 4644327119     PISSN: 10221360     EISSN: None     Source Type: Journal    
DOI: 10.1002/masy.200450912     Document Type: Conference Paper

References (28)

1. W. Kaminsky, A. Bark. M. Arndt, Makromol. Chem., Macromol. Symp. 1991, 47, 83.
2. M. Arndt, W. Kaminsky, Macromol. Symp. 1995, 95, 167.
3. W. Kaminsky, I. Beulich, M. Arndt-Rosenau, Macromol. Symp. 2001, 173, 211.
4. H. Cherdron, M.J. Brekner, F. Osan, Angew. Makromol. Chemie 1994, 223, 121.
5. M. J. Brekner, F. Osan, J. Rohrmann, M. Antberg, (Hoechst AG) U.S. Patent 5 324 801, 1994.
6. (a) Ruchatz, D., Fink, G. Macromolecules 1998, 31, 4669-73;
7. (b) Ruchatz, D.; Fink, G. ibid., 4674-80;
8. (c) Ruchatz, D.; Fink, G. ibid., 4681-83;
9. (d) Ruchatz, D.; Fink, G. ibid., 4684-86.
10. I. Tritto, L. Boggioni, M. C. Sacchi, P. Locatelli, D.R. Ferro, A. Provasoli, Macromol. Rapid Commun. 1999, 20, 279.
11. I. Tritto, L. Boggioni, M.C. Sacchi, P. Locatelli, D.R. Ferro, and A. Provasoli, in Metallorganic Catalysts for Synthesis and Polymerization W. Kaminsky Ed. Springer 1999, 493.
12. J. Forsyth, J.M. Pereña, R. Benavente, E. Perez, I. Tritto, L. Boggioni, H.-H Brintzinger, Macromol. Chem. Phys. 2001, 202, 614.
13. N. Ni Bhriain PhD thesis (2003)
14. J.C Jansen, R. Mendichi, P. Locatelli, I. Tritto, Macromol. Rapid Commun., 2001, 22, 1394.
15. G. Natta, I. Pasquon, Adv. Catal. 1959, 11, 1-66.
16. V. Busico, R. Cipullo, V. Esposito, Macromol. Rapid. Commun., 1999, 20, 116
17. J.C. Jansen, R. Mendichi, M.C. Sacchi, I. Tritto, Macromol. Chem. Phys. 2003, 204, 522.
18. Z. Liu, E. Somsook, C. R. Landis, J. Am. Chem. Soc. 2001, 123, 2915.
19. K. Thorshaug, R. Mendichi, I. Tritto, S. Trinkle, C. Friedrich, R. Mülhaupt, Macromolecules 2002, 35, 2903
20. A. Provasoli, D. R. Ferro, I. Tritto, L: Boggioni, Macromolecules 1999, 32, 6697.
21. I. Tritto, C. Marestin, L. Boggioni, L. Zetta, A. Provasoli, D.R. Ferro, Macromolecules 2000, 55, 8931
22. I. Tritto, C. Marestin, L. Boggioni, M.C. Sacchi, H.-H. Brintzinger, D. R. Ferro, Macromolecules 2001, 34, 5770.
23. M. Ragazzi, P. Carbone, D.R. Ferro, Int. J. Quantum Chem. 2002, 88, 663.
24. A. Razavi, V. Bellia, Y. De Brauwer, K. Hortmann, M. Lambrecht, O. Miserque, L. Peters, S. Van Belle, in Metallorganic Catalysis for Synthesis and Polymerization W. Kaminsky Ed. Springer 1999, 236.
25. I. Tritto, L. Boggioni, J.C. Jansen, K. Thorshaug, M.C. Sacchi, D.R. Ferro, Macromolecules, 2002, 55, 616
26. M. Arndt, I. Beulich, Macromol. Chem. Phys., 1998, 199, 1221
27. N. Herfert, P. Montag, G. Fink, Makromol. Chem., 2001, 94, 3167.
28. R.A. Wendt, R. Mynott, G. Fink, Macromol. Chem. Phys. 2002, 205, 2531.