On-line monitoring of all-acrylic emulsion polymerization reactors by Raman spectroscopy

Macromolecular Symposia

Volumn 206, Issue , 2004, Pages 135-148

  Elizalde, Oihana ^a   Leiza, Jose Ramon ^a   Asua, José M ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

Acrylic monomers; Emulsion polymerization; High solids; On line monitoring; Partial Least Squares Regression; Raman spectroscopy

Indexed keywords

ACRYLIC MONOMERS; COPOLYMERIZATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; MATHEMATICAL MODELS; MOLECULAR STRUCTURE; ONLINE SYSTEMS; PROCESS CONTROL; REGRESSION ANALYSIS; SENSORS;

ON-LINE MONITORING; PARTIAL LEAST SQUARES REGRESSION (PLSR); POLYMERIZATION REACTORS; SEMI-BATCH REACTIONS;

EMULSION POLYMERIZATION;

ACRYLIC ACID;

ANALYTIC METHOD; CALIBRATION; CHEMICAL STRUCTURE; CONFERENCE PAPER; CONTROL SYSTEM; EMULSION; INFRARED SPECTROSCOPY; ONLINE MONITORING; POLYMERIZATION; RAMAN SPECTROMETRY; REACTION ANALYSIS; REACTOR; REGRESSION ANALYSIS; SAMPLING; SENSOR;

EID: 4644266240     PISSN: 10221360     EISSN: None     Source Type: Conference Proceeding    
DOI: 10.1002/masy.200450211     Document Type: Conference Paper

References (23)

1. J.R. Leiza, J.M. Asua, in Polymeric Dispersions: Principles and Applications, J.M. Asua, Ed., Kluwer Academic Publishers, Dordrecht, 1997.
2. J. Dimitratos, G. Elicabe,C. Georgakis, AIChE J., 1994, 40, 1993.
3. D.H.C. Chien, A. Penlidis, J. Macromol. Chem. Phys., 1990, C30(1), 1.
4. O. Kammona, E.G. Chatzi, C. Kiparissides, Rev. Macromol. Che. Phys., 1999, 57, 39.
5. A. Urretabizkaia, E.D. Sudol, M.S. El-Aasser, J.M. Asua, J. Polym. Sci., Polym. Chem., 1993, 31, 2907.
6. L.M. Gugliotta, J.R. Leiza, M. Arotcarena, P.D. Armitage, J.M. Asua, Ind. Eng. Chem. Res., 1995, 34, 3899.
7. I. Sáenz de Buruaga, J.R. Leiza, J.M. Asua, Polym. React. Eng., 2000, 8(1), 39.
8. M. Vicente, S. Ben Amor, L.M. Gugliotta, J.R. Leiza, J.M. Asua, Ind. Eng. Chem. Res., 2001, 40, 218.
9. C. Wang, T.J. Vickers, C.K. Mann, Applied Spectroscopy, 1993, 47(7), 928.
10. C.K. Chong, C. Shan, Y. Fong, Vibrational Spectroscopy, 1993, 47(7), 928.
11. N. Everall, B. King, Macromol. Symp., 1999, 141, 103.
12. A. Al-Khanbashi, M. Dhamdhere, M. Hansen, Appl. Spec. Rev., 1998, 33(1&2), 115.
13. M. Agnely, B. Amhram, D. Charmot, S. Ben Amor, J.R. Leiza, J.M. Asua, C. Macron, J.P. Huvenne, J. Sawatski, Symp. on Polymerization in Dispersed Media, Lyon, France April 11-15, 1999.
14. C. Bauer, B. Amhram, M. Agnely, D. Charmot, J. Sawatzki, N. Dupuy, J.P. Huvenne, Appl. Spectrosc., 2000, 54(4), 528.
15. M. Van den Brink, J.F. Hansen, P. De Peinder, A. M. Van Herk, A.L. German, J. Appl. Polym. Sci., 2001, 79, 426.
16. W.D. Hergeth, Chem. Eng. Technol., 1998, 21(8), 647.
17. E. Gulari, K. McKeigue, K. Ng, Macromolecules, 1984, 17, 1822.
18. H. Martens, T. Næs, "Multivariate Calibration", John Willey & Sons Inc., New York, 1989.
19. K.H. Esbensen, "Multivariate data analysis - in practice", CAMO ASA, Norway, 2000.
20. G. Ellis, M. Claybourn, E. Richards, Spectrochimica Acta, 1990, 46 A, 227.
21. H.G.M. Edwards, A.F. Johnson, I.R. Lewis, J. Raman Spectroscopy, 1993, 24, 475.
22. M. Claybourn, J.K. Agbenyega, P.J. Hendra, G. Ellis, Adv. Chem. Ser. (Structure and property relations in polymers), 1993, 236, 443.
23. F. Adar, R. Geiger, J. Noonan, Appl. Spectrosc. Rev., 1997, 32(1&2), 45.