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Volumn 126, Issue 38, 2004, Pages 11762-11763

Alkylated polyethyleneimine/polyoxometalate synzymes as catalysts for the oxidation of hydrophobic substrates in water with hydrogen peroxide

Author keywords

[No Author keywords available]

Indexed keywords

ENZYME; HYDROGEN PEROXIDE; METAL DERIVATIVE; ORGANIC SOLVENT; POLYETHYLENE DERIVATIVE; POLYETHYLENEAMINE; POLYOXOMETALATE; UNCLASSIFIED DRUG; WATER;

EID: 4644264475     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja046349u     Document Type: Article
Times cited : (135)

References (45)
  • 8
    • 0842283643 scopus 로고    scopus 로고
    • Volkov, A. G., Ed.; Marcel Dekker: New York
    • (a) Reinsborough, V. C. In Interfacial Catalysis; Volkov, A. G., Ed.; Marcel Dekker: New York, 2003; pp 377-390.
    • (2003) Interfacial Catalysis , pp. 377-390
    • Reinsborough, V.C.1
  • 17
    • 4644361990 scopus 로고    scopus 로고
    • Volkov, A. G., Ed.; Marcel Dekker: New York
    • (c) Urrutigoity, M.; Kalck, P. In Interfacial Catalysis; Volkov, A. G., Ed.; Marcel Dekker: New York, 2003; pp 113-130.
    • (2003) Interfacial Catalysis , pp. 113-130
    • Urrutigoity, M.1    Kalck, P.2
  • 35
    • 4644366480 scopus 로고    scopus 로고
    • note
    • 3I (5.5 mL, 0.088 mol) was added dropwise and then refluxed for 17 h. Volatiles were removed by vacuum evaporation, and low molecular weight components were removed by dialysis (12 h): 50% EtOH in 50 mM HCl (x3), 20% EtOH in 50 mM HCl (x3), 10% EtOH in 50 mM HCl (x3), 50 mM HCl (x3), water (x3). The Alk-PEI obtained, 10.2 g, was dried by lyophilization.
  • 36
    • 4644271293 scopus 로고    scopus 로고
    • note
    • 1H HMBC and XPS experiments show several types of tertiary and quaternary amine species, respectively. This is probably due to primary formation of such moieties by alkylation with iododecane and iodomethane and some additional formation of such moieties during the purification process (dialysis in the presence of HCl).
  • 39
    • 0004164846 scopus 로고
    • Williams, A., Page, M., Eds.; Royal Society of Chemistry: London
    • This has also been discussed in the past. cf. Klotz, I. In Enzyme Mechanisms; Williams, A., Page, M., Eds.; Royal Society of Chemistry: London; 1987, pp 14-34.
    • (1987) Enzyme Mechanisms , pp. 14-34
    • Klotz, I.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.