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Volumn 126, Issue 38, 2004, Pages 11812-11813

Remarkable room-temperature insertion of carbon monoxide into an aluminum-carbon bond of tri-tert-butylaluminum

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; ALKYL GROUP; ALUMINUM DERIVATIVE; CARBON; CARBON MONOXIDE; TRI TERT BUTYLALUMINUM; UNCLASSIFIED DRUG;

EID: 4644261519     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja046411n     Document Type: Article
Times cited : (32)

References (47)
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    • Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Elsevier: New York, Chapter 6
    • (a) Eisch, J. J. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Elsevier: New York, 1995; Vol. 11, Chapter 6.
    • (1995) Comprehensive Organometallic Chemistry II , vol.11
    • Eisch, J.J.1
  • 3
    • 4644358107 scopus 로고
    • Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Elsevier: New York, Chapter 10
    • (b) Eisch, J. J. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Elsevier: New York, 1995; Vol. 1, Chapter 10.
    • (1955) Comprehensive Organometallic Chemistry II , vol.1
    • Eisch, J.J.1
  • 4
    • 0001569220 scopus 로고
    • Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon Press: Oxford, Chapter 6
    • (c) Eisch, J. J. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon Press: Oxford, 1982; Vol. 6, Chapter 6.
    • (1982) Comprehensive Organometallic Chemistry , vol.6
    • Eisch, J.J.1
  • 5
    • 0038591950 scopus 로고    scopus 로고
    • Scheirs, J., Kaminsky, W., Eds.; John Wiley and Sons: Chichester
    • (a) Barron, A. R. In Metallocene-Based Polyolefins; Scheirs, J., Kaminsky, W., Eds.; John Wiley and Sons: Chichester, 2000; Vol. 1, 33-67.
    • (2000) Metallocene-Based Polyolefins , vol.1 , pp. 33-67
    • Barron, A.R.1
  • 9
    • 4644272603 scopus 로고
    • Vandenberg, E. J., Salamone, J. C., Eds.; ACS Symposium Series 496; American Chemical Society: Washington, DC; Chapter 1
    • (b) Vandenberg, E. J. In Catalysis in Polymer Synthesis; Vandenberg, E. J., Salamone, J. C., Eds.; ACS Symposium Series 496; American Chemical Society: Washington, DC, 1992; Chapter 1.
    • (1992) Catalysis in Polymer Synthesis
    • Vandenberg, E.J.1
  • 36
    • 4644373145 scopus 로고    scopus 로고
    • note
    • Short reaction times (e.g., 5 min) yield a mixture of 1 and a second product, 2. The second product can be removed by recrystallization of crude 1 from THF or avoided altogether by using longer reaction times. The formation and chemistry of 2 is still under investigation.
  • 37
    • 4644358963 scopus 로고    scopus 로고
    • note
    • Acyl coordination to the aluminum atoms in 1 is sufficiently robust that crystallization from THF does not give THF-solvated monomers.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.