A polyoxometalate containing the {Ni2N3} fragment: Ferromagnetic coupling in a NiII μ-1,1 azido complex with a large bridging angle

Angewandte Chemie - International Edition

Volumn 43, Issue 17, 2004, Pages 2274-2277

  Mialane, Pierre ^a   Dolbecq, Anne ^a   Rivière, Eric ^b   Marrot, Jérôme ^a   Sécheresse, Francis ^a  

^a UNIVERSITÉ DE VERSAILLES SAINT QUENTIN EN YVELINES   (France)

^b UFR des Sciences Exactes et Naturelles   (France)

Author keywords

Azides; Magnetism; Nickel; Polyoxometalates

Indexed keywords

ANGLE MEASUREMENT; FERROMAGNETIC MATERIALS; NITROGEN;

AZIDO LIGANDS; FERROMAGNETICALLY COUPLED; POLYOXOMETALATE;

NICKEL;

AZIDE; FERROMAGNETIC MATERIAL; LIGAND; METAL; NICKEL;

ARTICLE; CHEMICAL STRUCTURE; ISOMER; MAGNETISM; MOLECULE;

EID: 4644243806     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200353433     Document Type: Article

References (36)

1. For reviews on polyoxometalates, see the special issue, Chem. Rev. 1998, 98, 1-387 (Guest Ed.: C. Hill).
2. J. M. Clemente-Juan, E. Coronado, Coord. Chem. Rev. 1999, 193-195, 361.
3. For examples of magnetic POM/TM Keggin complexes see: a) H. Y. Woo, H. So, M. T. Pope, J. Am. Chem. Soc. 1996, 118, 621;
4. b) K. Wassermann, R. Palm, H.-J. Lunk, J. Fuchs, N. Steinfeldt, R. Stösser, Inorg. Chem. 1995, 34, 5029;
5. c) J. M. Clemente-Juan, E. Coronado, J. R. Galán-Mascarós, C. J. Gómez-Garcia, Inorg. Chem. 1999, 38, 55;
6. d) U. Kortz, I. Mbomekalle, B. Keita, L. Nadjo, P. Berthet, Inorg. Chem. 2002, 41, 6412;
7. e) P. Mialane, A. Dolbecq, J. Marrot, E. Rivière, F. Sécheresse, Angew. Chem. 2003, 115, 3647; Angew. Chem. Int. Ed. 2003, 42, 3523;
8. e) P. Mialane, A. Dolbecq, J. Marrot, E. Rivière, F. Sécheresse, Angew. Chem. 2003, 115, 3647; Angew. Chem. Int. Ed. 2003, 42, 3523;
9. for POM/TM Dawson complexes: f) X. Zhang, T. M. Anderson, Q. Chen, R. G. Finke, Inorg. Chem. 2001, 40, 418;
10. g) C. J. Gómez-Garcia, J. J. Borrás-Almenar, E. Coronado, L. Ouahab, Inorg. Chem. 1994, 33, 4016.
11. a) U. Kortz. J. Cluster Sci. 2003, 205;
12. b) P. Mialane, A. Dolbecq, E. Rivière, J. Marrot, F. Sécheresse, Eur. J. Inorg. Chem. 2004, 33.
13. II azido-bridge complexes, see J. Ribas, A. Escuer, M. Monfort, R. Vicente, R. Cortés, L. Lezama, T. Rojo, Coord. Chem. Rev. 1999, 193-195, 1027.
14. a) C. J. Gómez-Garcia, E. Coronado, P. Gómez-Romero, N. Casañ-Pastor, Inorg. Chem. 1993, 32, 89;
15. b) R. C. Howell, F. G. Perez, S. Jain, W. De W. Horrocks, Jr., A. L. Rheingold, L. C. Francesconi, Angew. Chem. 2001, 113, 4155; Angew. Chem. Int. Ed. 2001, 40, 4031.
16. b) R. C. Howell, F. G. Perez, S. Jain, W. De W. Horrocks, Jr., A. L. Rheingold, L. C. Francesconi, Angew. Chem. 2001, 113, 4155; Angew. Chem. Int. Ed. 2001, 40, 4031.
17. 2 = 0.1214. Data reduction was performed with the SAINT software. The absorption correction was based on multiple and symmetry-equivalent reflections in the data set using the SADABS program based on the method of Blessing. The structures were solved by direct methods and refined by full-matrix least-squares using the SHELX-TL package. Further details on the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (+49)7247-808-666; e-mail: crysdata@fiz-karlsruhe.de), on quoting the depository number CSD-413547.
18. M. Mikuriya, S. Kida, I. Murase, Bull. Chem. Soc. Jpn. 1987, 60, 1355.
19. 2].
20. -4).
21. P. Chaudhuri, T. Weyhermüller, E. Bill, K. Wieghardt, Inorg. Chim. Acta 1996, 252, 195.
22. M.-F. Charlot, O. Kahn, M. Chaillet, C. Larrieu, J. Am. Chem. Soc. 1986, 108, 2574.
23. M. A. Aebersold, B. Gillon, O. Plantevin, L. Pardi, O. Kahn, P. Bergerat, I. von Seggern, F. Tuczek, L. Öhrström, A. Grand, E. Lelièvre-Berna, J. Am. Chem. Soc. 1998, 120, 5238.
24. S. S. Tandon, L. K. Thompson, M. E. Manuel, J. N. Bridson, Inorg. Chem. 1995, 34, 2356.
25. L. K. Thompson, S. S. Tandon, F. Lloret, J. Cano, M. Julve, Inorg. Chem. 1997, 36, 3301.
26. A. Escuer, R. Vicente, F. A. Mautner, M. A. S. Goher, Inorg. Chem. 1997, 36, 1233.
27. V. McKee, M. Zvagulis, C. A. Reed, Inorg. Chem. 1985, 24, 2914.
28. E. Ruiz, J. Cano, S. Alvarez, P. Alemany, J. Am. Chem. Soc. 1998, 120, 11122.
29. R. Contant, Can. J. Chem. 1987, 65, 568.
30. P. D. Beer, M. G. B. Drew, P. B. Leeson, K. Lyssenko, M. I. Ogden, J. Chem. Soc. Chem. Commun. 1995, 929.
31. a) M. A. Halcrow, J. C. Huffman, G. Christou, Angew. Chem. 1995, 107, 971; Angew. Chem. Int. Ed. Engl. 1995, 34, 889;
32. a) M. A. Halcrow, J. C. Huffman, G. Christou, Angew. Chem. 1995, 107, 971; Angew. Chem. Int. Ed. Engl. 1995, 34, 889;
33. b) M. A. Halcrow, J.-S. Sun, J. C. Huffman, G. Cristou, Inorg. Chem. 1995, 34, 4167.
34. M. G. Barandika, R. Cortes, L. Lezama, M. K. Urtiaga, M. I. Arriortua, T. Rojo, J. Chem. Soc. Dalton Trans: 1999, 2971.
35. A. Escuer, R. Vicente, J. Ribas, X. Solans, Inorg. Chem. 1995, 34, 1793.
36. R. Cortes, J. I. Ruiz de Larramendi, L. Lezama, T. Rojo, K. Urtiga, M. I. Arriortua, J. Chem. Soc. Dalton Trans. 1992, 2723.