-
2
-
-
0010325502
-
-
For preliminary reports of this reaction, see
-
For preliminary reports of this reaction, see: J.W. Herndon P.P. Patel J. Org. Chem. 61 1996 4500-4501
-
(1996)
J. Org. Chem.
, vol.61
, pp. 4500-4501
-
-
Herndon, J.W.1
Patel, P.P.2
-
4
-
-
0038524273
-
-
For a recent review of this reaction, see
-
For a recent review of this reaction, see K.H. Dötz P. Tomuschat Chem. Soc. Rev. 28 1999 187-198
-
(1999)
Chem. Soc. Rev.
, vol.28
, pp. 187-198
-
-
Dötz, K.H.1
Tomuschat, P.2
-
5
-
-
0037367187
-
-
For a recent review of this reaction, see
-
For a recent review of this reaction, see J.W. Herndon Curr. Org. Chem. 7 2003 329-352
-
(2003)
Curr. Org. Chem.
, vol.7
, pp. 329-352
-
-
Herndon, J.W.1
-
6
-
-
0000865381
-
-
We are unaware of an example of a 1,7-silicon shift process, however the 1,5-silicon shift is known
-
We are unaware of an example of a 1,7-silicon shift process, however the 1,5-silicon shift is known. M. Stradiotto P. Hazendonk A.D. Bain M.A. Brook M.J. McGlinchey Organometallics 19 2000 590-601
-
(2000)
Organometallics
, vol.19
, pp. 590-601
-
-
Stradiotto, M.1
Hazendonk, P.2
Bain, A.D.3
Brook, M.A.4
McGlinchey, M.J.5
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7
-
-
4644308559
-
-
These results were obtained using the program Gaussian 98W. using the B3LYP method and the 6-31G** basis set Mt Gaussian Inc. Pittsburgh PA 1998
-
These results were obtained using the program Gaussian 98W. using the B3LYP method and the 6-31G** basis set Mt M.J. Frisch G.W. Trucks H.B. Schlegel G.E. Scuseria M.A. Robb. J.R. Cheesman V.G. Zakrzewski J.A. Montgomery R.E. Stratmann J.C. Burant S. Dapprich J.M. Milliam A.D. Daniels K.N. Kudin M.C. Strain O. Farkas J. Tomasi V. Barone M. Cossi R. Cammi B. Menucci C. Pomelli C. Adamo S. Clifford J. Ochterski G.A. Petersson P.Y. Ayala Q. Cui K. Morokuma D.K. Malick A.D. Rabuck K. Raghavachari J.B. Foresman J. Cioslowki J.V. Ortiz B.B. Stefano A. Liu A. Liashenko P. Piskorz I. Komaromi R. Gomperts R.L. Martin D.J. Fox T. Keith M.A. Al-Laham C.Y. Peng A. Nanayakkara M. Gonzalez M. Callacombe P.M.W. Gill B.G. Johnson W. Chen M.W. Wong J.L. Andres M. Head-Gordon E.S. Replogle J.A. Pople Gaussian Inc. Pittsburgh PA 1998
-
-
-
Frisch, M.J.1
Trucks, G.W.2
Schlegel, H.B.3
Scuseria, G.E.4
Robb, M.A.5
Cheesman, J.R.6
Zakrzewski, V.G.7
Montgomery, J.A.8
Stratmann, R.E.9
Burant, J.C.10
Dapprich, S.11
Milliam, J.M.12
Daniels, A.D.13
Kudin, K.N.14
Strain, M.C.15
Farkas, O.16
Tomasi, J.17
Barone, V.18
Cossi, M.19
Cammi, R.20
Menucci, B.21
Pomelli, C.22
Adamo, C.23
Clifford, S.24
Ochterski, J.25
Petersson, G.A.26
Ayala, P.Y.27
Cui, Q.28
Morokuma, K.29
Malick, D.K.30
Rabuck, A.D.31
Raghavachari, K.32
Foresman, J.B.33
Cioslowki, J.34
Ortiz, J.V.35
Stefano, B.B.36
Liu, A.37
Liashenko, A.38
Piskorz, P.39
Komaromi, I.40
Gomperts, R.41
Martin, R.L.42
Fox, D.J.43
Keith, T.44
Al-Laham, M.A.45
Peng, C.Y.46
Nanayakkara, A.47
Gonzalez, M.48
Callacombe, M.49
Gill, P.M.W.50
Johnson, B.G.51
Chen, W.52
Wong, M.W.53
Andres, J.L.54
Head-Gordon, M.55
Replogle, E.S.56
Pople, J.A.57
more..
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9
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4644337830
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The first letter refers to the stereochemistry of the end ether. The second letter refers to the stereochemistry of the alkenylsilane
-
The first letter refers to the stereochemistry of the end ether. The second letter refers to the stereochemistry of the alkenylsilane.
-
-
-
-
15
-
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0031013620
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-
Similarly successful carbene-alkyne couplings have been reported for pentenyloxycarbene complexes
-
Similarly successful carbene-alkyne couplings have been reported for pentenyloxycarbene complexes. J.W. Herndon P.P. Patel Tetrahedron Lett. 38 1997 59-62
-
(1997)
Tetrahedron Lett.
, vol.38
, pp. 59-62
-
-
Herndon, J.W.1
Patel, P.P.2
-
17
-
-
0037028158
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-
A similar failure in geometry optimization of this complex was previously documented. Successful optimization was only effected starting from a non-cis arrangement of methyl groups
-
A similar failure in geometry optimization of this complex was previously documented. Successful optimization was only effected starting from a non-cis arrangement of methyl groups X. Wang E. Weitz J. Phys. Chem. A 106 2002 11782-11790
-
(2002)
J. Phys. Chem. A
, vol.106
, pp. 11782-11790
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Wang, X.1
Weitz, E.2
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19
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33845556708
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-
For a discussion of deviation of alkene-metal complexes from totally symmetrical coordination see
-
For a discussion of deviation of alkene-metal complexes from totally symmetrical coordination see O. Eisenstein R. Hoffmann J. Am. Chem. Soc. 103 1981 4308-4320
-
(1981)
J. Am. Chem. Soc.
, vol.103
, pp. 4308-4320
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-
Eisenstein, O.1
Hoffmann, R.2
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21
-
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0002324898
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-
This explanation is very similar to that used to explain retention of stereochemistry in reaction of alkenylsilanes with electrophiles
-
This explanation is very similar to that used to explain retention of stereochemistry in reaction of alkenylsilanes with electrophiles I. Fleming J. Dunogues R. Smithers Org. React. 37 1989 57-575
-
(1989)
Org. React.
, vol.37
, pp. 57-575
-
-
Fleming, I.1
Dunogues, J.2
Smithers, R.3
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30
-
-
4644221205
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-
The silica gel was slurried ina 99:1 hexane:triethylamine solution prior to packing the chromatography column
-
The silica gel was slurried ina 99:1 hexane:triethylamine solution prior to packing the chromatography column.
-
-
-
-
32
-
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4644333251
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-
Note that conversion of a trimethylsilyl group to a hydrogen changes the E-Z designation of the non-enol ether double bond due to changes in Cahn-Ingold priority number
-
Note that conversion of a trimethylsilyl group to a hydrogen changes the E-Z designation of the non-enol ether double bond due to changes in Cahn-Ingold priority number.
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