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Volumn 43, Issue 20, 2004, Pages 6383-6396

Synthesis, characterization, and photochemical and computational investigations of Ru(II) heterocyclic complexes containing 2,6- dimethylphenylisocyanide (CNx) ligand

Author keywords

[No Author keywords available]

Indexed keywords

2,2' BIPYRIDINE DERIVATIVE; 2,6 DIMETHYLPHENYLISOCYANIDE; ALCOHOL; CYANIDE; HETEROCYCLIC COMPOUND; LIGAND; METAL; PYRIDINE DERIVATIVE; RUTHENIUM; RUTHENIUM COMPLEX; UNCLASSIFIED DRUG;

EID: 4644228884     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic049099r     Document Type: Article
Times cited : (35)

References (70)
  • 34
    • 4644270796 scopus 로고    scopus 로고
    • note
    • The structure was solved and refined in the triclinic space group P1. As suggested by the unit cell dimensions, alternative lattice symmetry (monoclinic) can be assigned. After careful examination and attempts to assign a monoclinic space group, it was decided that the triclinic cell was correct. Examination of the h0l and -h0l (h0l and h0l̄) reflections (after absorption correction) indicated that no symmetrical relationship was present. It is suggested that the sample undergoes a second-order phase transition at or before 110 K (monoclinic → triclinic), which is consistent with the known behavior of molecular solids.
  • 54
    • 4644361258 scopus 로고    scopus 로고
    • note
    • Geometry optimization in solvents was not achieved. Partial optimizations (change in distances of less than 0.001 Å and change in angles of less than 0.01°) followed by TD CPCM calculation produced excited-state energies that were not in better agreement with the experimental excited-state energies than the excited-state energies based on the gas-phase-optimized geometry.
  • 60
    • 4644270889 scopus 로고
    • Ph.D. Thesis, University of North Carolina, Chapel Hill, North Carolina
    • (a) Caspar, J. V. Ph.D. Thesis, University of North Carolina, Chapel Hill, North Carolina, 1982.
    • (1982)
    • Caspar, J.V.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.