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Volumn 37, Issue 23, 1981, Pages 3951-3956

Diastereoselective and enantioselective synthesis of 1,2-disubstituted cycloalkanecarboxaldehydes

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Indexed keywords

EID: 46349109895 PISSN: 00404020 EISSN: None Source Type: Journal
DOI: 10.1016/S0040-4020(01)93269-7 Document Type: Article

Times cited : (55)

References (28)

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16
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17
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- The chemical shift values of C-Me groups of trans-10 (R'=Me) are substantially higher than those of cis-10 (R'=Me) due to the effect of steric purturbation. Cf., G.A. Webb, Academic Press, New York, It is also shown empirically that the difference of the chemical shift values between quarternary and tertiary carbons of 10 (Δδ=δ, quarternary C)-δ(tertiary C)) is more positive for trans-isomers. Details will be reported elsewhere.
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20
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21
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