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Volumn 2008, Issue 11, 2008, Pages 227-237

Catalytic properties of the Pd/C - Triethylamine system

Author keywords

Conjugate reduction; Heterogeneous catalysis; Isomerization; Palladium; Self alkylation; Triethylamine

Indexed keywords


EID: 46249122373     PISSN: 1551-7012     EISSN: 15517012     Source Type: Journal    
DOI: 10.3998/ark.5550190.0009.b22     Document Type: Article
Times cited : (17)

References (52)
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    • See for example: a
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    • See Section 2.2.3 of Muzart, J. Tetrahedron 2005, 61, 9423.
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    • See Section II.D.4 of ref. 10.
    • (b) See Section II.D.4 of ref. 10.
  • 27
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    • For palladium- promoted dehydrogenation of ketones, see: a
    • For palladium- promoted dehydrogenation of ketones, see: (a) Theissen, R. J. J. Org. Chem. 1971, 36, 752.
    • (1971) J. Org. Chem , vol.36 , pp. 752
    • Theissen, R.J.1
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    • For a mechanistic discussion, see
    • For a mechanistic discussion, see: Muzart, J. Tetrahedron 2003, 59, 5789.
    • (2003) Tetrahedron , vol.59 , pp. 5789
    • Muzart, J.1
  • 34
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    • Haskel, A.; Keinan, E. in: E. Negishi, Ed. Handbook of Organopalladium Chemistry in Organic Synthesis, John Wiley & Sons: New York, 2002; 2, Chap VII 2.3, pp 2767-2782.
    • Haskel, A.; Keinan, E. in: E. Negishi, Ed. Handbook of Organopalladium Chemistry in Organic Synthesis, John Wiley & Sons: New York, 2002; Vol. 2, Chap VII 2.3, pp 2767-2782.
  • 40
    • 85069241810 scopus 로고    scopus 로고
    • A pincer-liganted iridium complex catalyses the dehydrogenation of tertiary amines in the presence of a sacrificial hydrogen acceptor: Zhang, X.; Fried, A.; Knapp, S.; Goldman, A. S. Chem. Commun. 2003, 2060. The Pd/C-NEt3 system applied to an E:Z = 1:2.3 mixture of cyclododecene resulted only in the thermodynamically favored isomerization of the mixture to an E:Z = 1.9:1 mixture of cyclododecene (quantitative recovery). The Pd/C-NEt3 system also left O-benzylated menthol unchanged under the reaction conditions.
    • A pincer-liganted iridium complex catalyses the dehydrogenation of tertiary amines in the presence of a sacrificial hydrogen acceptor: Zhang, X.; Fried, A.; Knapp, S.; Goldman, A. S. Chem. Commun. 2003, 2060. The Pd/C-NEt3 system applied to an E:Z = 1:2.3 mixture of cyclododecene resulted only in the thermodynamically favored isomerization of the mixture to an E:Z = 1.9:1 mixture of cyclododecene (quantitative recovery). The Pd/C-NEt3 system also left O-benzylated menthol unchanged under the reaction conditions.
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    • US Patent 4 845 295, 20669
    • Chao, K.-H. US Patent 4 845 295, 1989; Chem. Abstr. 1990, 20669.
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  • 43
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    • Tietze, L. F, Brasche, G, Gericke, K. M. Wiley-VCH, Weinheim
    • Domino Reactions in Organic Synthesis Tietze, L. F.; Brasche, G.; Gericke, K. M. Wiley-VCH, Weinheim, 2006.
    • (2006) Domino Reactions in Organic Synthesis


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.