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Volumn 88, Issue 6, 2008, Pages 927-948

Generalized surface thermodynamics with application to nucleation

Author keywords

Nucleation; Surface thermodynamics

Indexed keywords

ADSORPTION; CHEMICAL POTENTIAL; CHEMICALS; CRYSTALLIZATION; DYNAMICS; EPITAXIAL GROWTH; HELIUM; NUCLEATION; PHOTOACOUSTIC EFFECT; SOLIDIFICATION; SOLIDS; SURFACE CHEMISTRY; SURFACE TENSION; THERMODYNAMICS;

EID: 46149107084     PISSN: 14786435     EISSN: 14786443     Source Type: Journal    
DOI: 10.1080/14786430802014654     Document Type: Article
Times cited : (24)

References (43)
  • 1
    • 0002166247 scopus 로고
    • Dover, New York, original work published in 1876
    • J.W. Gibbs, The Scientific Papers of J.W. Gibbs, Vol. 1, Dover, New York, 1961, original work published in 1876, 1878 p.55.
    • (1878) The Scientific Papers of J.W. Gibbs , vol.1 , pp. 55
    • Gibbs, J.W.1
  • 2
    • 46149089117 scopus 로고    scopus 로고
    • Ref, 1, p.56
    • Ref. [1], p.56.
  • 3
    • 46149090748 scopus 로고    scopus 로고
    • When Gibbs considered variations in the amount of a component, he expressed them as variations in the mass rather than in the number of moles
    • When Gibbs considered variations in the amount of a component, he expressed them as variations in the mass rather than in the number of moles.
  • 4
    • 46149109414 scopus 로고    scopus 로고
    • Ref, 1, p.222
    • Ref. [1], p.222.
  • 5
    • 46149085333 scopus 로고    scopus 로고
    • Ref, 1, p.193
    • Ref. [1], p.193.
  • 11
    • 0004180277 scopus 로고
    • Cambridge University Press, Cambridge
    • C.J. Adkins, Equilibrium Thermodynamics, Cambridge University Press, Cambridge, 1983, p.106.
    • (1983) Equilibrium Thermodynamics , pp. 106
    • Adkins, C.J.1
  • 13
    • 46149114084 scopus 로고
    • Dover, New York, original work published in 1873, p
    • J.W. Gibbs, The Scientific Papers of J.W. Gibbs, Vol. 1, Dover, New York, 1961, original work published in 1873, p.40.
    • (1961) The Scientific Papers of J.W. Gibbs , vol.1 , pp. 40
    • Gibbs, J.W.1
  • 14
    • 46149123153 scopus 로고    scopus 로고
    • Ref, 1, p.109
    • Ref. [1], p.109.
  • 15
    • 46149108050 scopus 로고    scopus 로고
    • Ref, 1, p.221
    • Ref. [1], p.221.
  • 17
    • 46149084363 scopus 로고    scopus 로고
    • Ref, 1, p.219
    • Ref. [1], p.219.
  • 18
    • 46149107220 scopus 로고    scopus 로고
    • Ref, 1, p.225
    • Ref. [1], p.225.
  • 19
    • 46149092690 scopus 로고    scopus 로고
    • H. Ehrenreich and F. Spaepen, eds, Elsevier, Amsterdam
    • P.W. Voorhees and W.C. Johnson, in Solid State Physics, Vol. 59, H. Ehrenreich and F. Spaepen, eds., Elsevier, Amsterdam, 2004, p.2.
    • (2004) Solid State Physics , vol.59 , pp. 2
    • Voorhees, P.W.1    Johnson, W.C.2
  • 24
    • 0004261478 scopus 로고
    • W.C. Johnson and J.M. Blakely, eds, American Society for Metals, Metals Park, OH
    • J.W. Cahn, in Interfacial Segregation, W.C. Johnson and J.M. Blakely, eds., American Society for Metals, Metals Park, OH, 1979.
    • (1979) Interfacial Segregation
    • Cahn, J.W.1
  • 30
    • 46149120497 scopus 로고    scopus 로고
    • Ref, 1, p.229
    • Ref. [1], p.229.
  • 31
    • 46149112936 scopus 로고    scopus 로고
    • Ref, 1, p.314
    • Ref. [1], p.314.
  • 32
    • 46149094328 scopus 로고    scopus 로고
    • Ref, 1, p.317
    • Ref. [1], p.317.
  • 33
    • 46149098593 scopus 로고    scopus 로고
    • M. Hillert, quoted in ref. [6].
    • M. Hillert, quoted in ref. [6].
  • 34
    • 46149125200 scopus 로고    scopus 로고
    • j=0 if j is not an actual component of α.
    • j=0 if j is not an actual component of α.
  • 35
    • 46149126570 scopus 로고    scopus 로고
    • If the surface crystal plane of the solid before dissolution has a relatively small atom fraction of components that are not actual components of the α, then atoms of these components will remain on the newly created surface, and a small mole fraction of atoms that were originally in the crystal plane adjacent to the surface plane that can be Gibbs-reversibly varied will be dissolved in order to make the total number of dissolved atoms equal to the number of lattice sites in the original surface crystal layer
    • If the surface crystal plane of the solid before dissolution has a relatively small atom fraction of components that are not actual components of the α, then atoms of these components will remain on the newly created surface, and a small mole fraction of atoms that were originally in the crystal plane adjacent to the surface plane that can be Gibbs-reversibly varied will be dissolved in order to make the total number of dissolved atoms equal to the number of lattice sites in the original surface crystal layer.
  • 38
    • 46149111617 scopus 로고    scopus 로고
    • For a general anisotropic surface, defining the two-dimensional infinitesimal surface strain dεij in the standard way, the surface stress tensor fij can be defined by setting the reversible work to introduce a surface strain dεij as Afij dεij, dZs, so that fij, 1/A (∂Zs/∂ε ij)εkl≠ij The surface stress can be related to the open system surface availability σ by noting that for fixed nsi, dZs, dBs, d(σA) and that dA, Aδijdε ij, where δij is the Kronecker delta, so that fij =1/A (∂(σ A, ∂εij)εkl≠ij,nsi, σ
    • i.
  • 39
    • 46149113635 scopus 로고    scopus 로고
    • Ref, 1, p. 254
    • Ref. [1], p. 254.
  • 42
    • 46149117429 scopus 로고    scopus 로고
    • Ref, 1, p.88
    • Ref. [1], p.88.
  • 43
    • 46149127497 scopus 로고    scopus 로고
    • Ref, 12, p.215
    • Ref. [12], p.215.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.