Theory of competitive counterion adsorption on flexible polyelectrolytes: Divalent salts

Journal of Chemical Physics

Volumn 128, Issue 24, 2008, Pages

  Kundagrami, Arindam ^a   Muthukumar, M ^a  

^a UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; ALKALI METALS; CHEMICALS; CONDENSATION; ELECTROLYTES; GRAPHIC METHODS; POLYELECTROLYTES; SALTS; SODIUM; SOLUTIONS;

(E ,2E) THEORY; (MIN ,MAX ,+) FUNCTIONS; ADSORPTION MODELING; AMERICAN INSTITUTE OF PHYSICS (AIP); AQUEOUS SOLUTIONS; BJERRUM LENGTH; COLLAPSE (DRYING); COMPETITIVE ADSORPTION; COUNTERION ADSORPTION; COUNTERION DISTRIBUTION; DIVALENT COUNTERIONS; EFFECTIVE CHARGES; ELECTROSTATIC SCREENING; FIRST ORDERS; FLEXIBLE POLYELECTROLYTES; HIGH COULOMB; MONOVALENT COUNTERIONS; PHYSICAL CONDITIONS; PHYSICAL VARIABLES; SALT CONCENTRATIONS; SELF-CONSISTENT CALCULATIONS; SODIUM POLYSTYRENE SULFONATE (NASS); STRENGTH (IGC: D5/D6);

POLYMERS;

DIVALENT CATION; INORGANIC SALT; POLYMER;

ADSORPTION; ARTICLE; CHEMICAL MODEL; CHEMISTRY; CONFORMATION; ELECTRICITY; OSMOLARITY; TEMPERATURE; THEORETICAL MODEL;

ADSORPTION; CATIONS, DIVALENT; ELECTROSTATICS; MODELS, CHEMICAL; MODELS, THEORETICAL; MOLECULAR CONFORMATION; OSMOLAR CONCENTRATION; POLYMERS; SALTS; TEMPERATURE;

EID: 46149090383     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.2940199     Document Type: Article

References (47)

1. M. Muthukumar, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.1701839 120, 9343 (2004).
2. G. S. Manning, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.1672157 51, 924 (1969).
3. P. Gonzalez-Mozuelos and M. Olvera de la Cruz, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.470248 103, 3145 (1995).
4. M. Olvera de la Cruz, L. Belloni, M. Delsanti, J. P. Dalbiez, O. Spalla, and M. Drifford, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.470459 103, 5781 (1995).
5. P. S. Kuhn, Y. Levin, and M. C. Barbosa, Macromolecules MAMOBX 0024-9297 10.1021/ma980069f 31, 8347 (1998).
6. F. J. Solis and M. Olvera de la Cruz, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.480763 112, 2030 (2000).
7. F. J. Solis, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.1514575 117, 9009 (2002).
8. C. C. Conwell and N. V. Hud, J. Cluster Sci. JCSCEB 1040-7278 14, 115 (2003).
9. C. C. Conwell, I. D. Vilfan, and N. V. Hud, Proc. Natl. Acad. Sci. U.S.A. PNASA6 0027-8424 10.1073/pnas.1533135100 100, 9296 (2003).
10. K. Huber, J. Phys. Chem. JPCHAX 0022-3654 10.1021/j100140a046 97, 9825 (1993).
11. Y. Ikeda, M. Beer, M. Schmidt, and K. Huber, Macromolecules MAMOBX 0024-9297 10.1021/ma970540p 31, 728 (1998).
12. R. Schweins and K. Huber, Eur. Phys. J. E EPJSFH 1292-8941 10.1007/s101890170093 5, 117 (2001).
13. M. Delsanti, J. P. Dalbiez, O. Spalla, L. Belloni, and M. Drifford, ACS Symp. Ser. ACSMC8 0097-6156 548, 381 (1994).
14. R. Chang and A. Yethiraj, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.1575731 118, 11315 (2003).
15. T. T. Nguyen, I. Rouzina, and B. I. Shklovskii, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.480819 112, 2562 (2000).
16. T. T. Nguyen, A. Y. Grosberg, and B. I. Shklovskii, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.481890 113, 1110 (2000).
17. T. T. Nguyen, A. Y. Grosberg, and B. I. Shklovskii, Phys. Rev. Lett. PRLTAO 0031-9007 10.1103/PhysRevLett.85.1568 85, 1568 (2000).
18. Also see, H. Schiessel and P. Pincus, Macromolecules MAMOBX 0024-9297 10.1021/ma980823x 31, 7953 (1998).
19. H. Schiessel, Macromolecules MAMOBX 0024-9297 10.1021/ma990051k 32, 5673 (1999).
20. P.-Y. Hsiao and E. Luijten, Phys. Rev. Lett. PRLTAO 0031-9007 10.1103/PhysRevLett.97.148301 97, 148301 (2006).
21. M. Beer, M. Schmidt, and M. Muthukumar, Macromolecules MAMOBX 0024-9297 10.1021/ma9709821 30, 8375 (1997).
22. V. M. Prabhu, M. Muthukumar, G. D. Wignall, and Y. B. Melnichenko, Polymer POLMAG 0032-3861 10.1016/S0032-3861(01)00382-2 42, 8935 (2001).
23. For a nice review, see V. M. Prabhu, Curr. Opin. Colloid Interface Sci. COCSFL 1359-0294 10.1016/j.cocis.2005.04.002 10, 2 (2005).
24. M. J. Stevens and K. Kremer, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.470698 103, 1669 (1995).
25. M. J. Stevens and K. Kremer, Phys. Rev. Lett. PRLTAO 0031-9007 10.1103/PhysRevLett.71.2228 71, 2228 (1993).
26. S. Liu and M. Muthukumar, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.1476930 116, 9975 (2002).
27. R. G. Winkler, M. Gold, and P. Reineker, Phys. Rev. Lett. PRLTAO 0031-9007 10.1103/PhysRevLett.80.3731 80, 3731 (1998).
28. S. Liu, K. Ghosh, and M. Muthukumar, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.1580109 119, 1813 (2003).
29. Y. Murayama, Y. Sakamaki, and M. Sano, Phys. Rev. Lett. PRLTAO 0031-9007 10.1103/PhysRevLett.90.018102 90, 018102 (2003).
30. K. Besteman, K. Van Eijk, and S. G. Lemay, Nat. Phys. ZZZZZZ 1745-2473 3, 641 (2007).
31. X. Qiu, K. Andresen, L. W. Kwok, J. S. Lamb, H. Y. Park, and L. Pollack, Phys. Rev. Lett. PRLTAO 0031-9007 10.1103/PhysRevLett.99.038104 99, 038104 (2007).
32. J. Wittmer, A. Johner, and J. F. Joanny, J. Phys. II JPAHER 1155-4312 10.1051/jp2:1995154 5, 635 (1995).
33. E. L. Mehler and G. Eichele, Biochemistry BICHAW 0006-2960 10.1021/bi00312a015 23, 3887 (1984).
34. G. Lamm and G. R. Pack, J. Phys. Chem. B JPCBFK 1089-5647 10.1021/jp9623453 101, 959 (1997).
35. I. Rouzina and V. A. Bloomfield, Biophys. J. BIOJAU 0006-3495 74, 3152 (1998).
36. V. M. Prabhu, E. J. Amis, D. P. Bossev, and N. Rosov, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.1386924 115, 4367 (2004).
37. M. Muthukumar, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.452763 86, 7230 (1987).
38. I. Rouzina and V. A. Bloomfield, J. Phys. Chem. JPCHAX 0022-3654 10.1021/jp960458g 100, 9977 (1996).
39. B.-Y. Ha and A. J. Liu, Phys. Rev. Lett. PRLTAO 0031-9007 10.1103/PhysRevLett.79.1289 79, 1289 (1997).
40. R. Golestanian, M. Kardar, and T. Liverpool, Phys. Rev. Lett. PRLTAO 0031-9007 10.1103/PhysRevLett.82.4456 82, 4456 (1999).
41. A. Yu. Grosberg, T. T. Nguyen, and B. I. Shklovskii, Rev. Mod. Phys. RMPHAT 0034-6861 10.1103/RevModPhys.74.329 74, 329 (2002).
42. N. Gronbech-Jensen, R. J. Mashl, R. F. Bruinsma, and W. M. Gelbart, Phys. Rev. Lett. PRLTAO 0031-9007 10.1103/PhysRevLett.78.2477 78, 2477 (1997).
43. Y. Zhang, J. F. Douglas, B. D. Ermi, and E. J. Amis, J. Chem. Phys. JCPSA6 0021-9606 10.1063/1.1386924 115, 4367 (2001).
44. G. Goerigk, R. Schweins, K. Huber, and M. Ballauff, Europhys. Lett. EULEEJ 0295-5075 10.1209/epl/i2003-10215-y 66, 331 (2004).
45. R. Schweins, G. Goerigk, and K. Huber, Eur. Phys. J. E EPJSFH 1292-8941 10.1140/epje/i2006-10047-7 21, 99 (2006).
46. K. A. Narh and A. Keller, J. Polym. Sci., Part B: Polym. Phys. JPBPEM 0887-6266 10.1002/polb.1993.090310213 31, 231 (1993).
47. M. Muthukumar, in Molecular Basis of Polymer Networks, Springer Proceedings in Physics, Vol. 42, edited by, A. Baumgärtner, and, C. E. Picot, (Springer, New York, 1989), p. 28.