메뉴 건너뛰기




Volumn 32, Issue 9, 2008, Pages 2155-2167

Free-radical polymerization at higher temperatures: Systems impacts of secondary reactions

Author keywords

Chromatographic properties; Complex nonlinear dynamics; High temperature free radical polymerization; Microstructure properties; Reaction kinetics; Spectroscopic properties

Indexed keywords

ADDITION REACTIONS; CHEMICAL REACTIONS; CUSTOMER SATISFACTION; DYNAMICAL SYSTEMS; DYNAMICS; FLUIDS; FUNCTIONAL GROUPS; INDUSTRIAL ENGINEERING; MARKETING; MATHEMATICAL MODELS; MEASUREMENTS; MECHANICS; MOLECULAR WEIGHT; MOLECULES; MONOMERS; NUMERICAL METHODS; POLYMERIZATION; POLYMERS; PROBLEM SOLVING; QUALITY ASSURANCE; QUALITY CONTROL; QUALITY FUNCTION DEPLOYMENT; REACTION KINETICS; RESINS; SOLUTIONS; SOLVENTS; TEMPERATURE; TOTAL QUALITY MANAGEMENT;

EID: 45949088643     PISSN: 00981354     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.compchemeng.2007.10.023     Document Type: Article
Times cited : (12)

References (48)
  • 2
    • 0032485685 scopus 로고    scopus 로고
    • Chain transfer to polymer in free-radical solution polymerization of n-butyl acrylate studied by NMR spectroscopy
    • Ahmad N.M., Heatley F., and Lovell P.A. Chain transfer to polymer in free-radical solution polymerization of n-butyl acrylate studied by NMR spectroscopy. Macromolecules 31 (1998) 2822-2827
    • (1998) Macromolecules , vol.31 , pp. 2822-2827
    • Ahmad, N.M.1    Heatley, F.2    Lovell, P.A.3
  • 3
    • 9144244954 scopus 로고    scopus 로고
    • Critically evaluated rate coefficients for free-radical polymerization, 5. Propagation rate coefficient for butyl acrylate
    • Asua J.M., Beuermann S., Buback M., Castignolles P., Charleux B., Gilbert R.G., et al. Critically evaluated rate coefficients for free-radical polymerization, 5. Propagation rate coefficient for butyl acrylate. Macromolecular Chemistry and Physics 205 (2004) 2151-2160
    • (2004) Macromolecular Chemistry and Physics , vol.205 , pp. 2151-2160
    • Asua, J.M.1    Beuermann, S.2    Buback, M.3    Castignolles, P.4    Charleux, B.5    Gilbert, R.G.6
  • 5
    • 0036498339 scopus 로고    scopus 로고
    • Rate coefficients of free-radical polymerization deduced from pulsed laser experiments
    • Beuermann S., and Buback M. Rate coefficients of free-radical polymerization deduced from pulsed laser experiments. Progress in Polymer Science 27 (2002) 191-254
    • (2002) Progress in Polymer Science , vol.27 , pp. 191-254
    • Beuermann, S.1    Buback, M.2
  • 6
    • 0041908968 scopus 로고
    • Spontaneous polymerization of methyl methacrylate, 3. Reaction behavior of the unsaturated dimer upon polymerization
    • Brand E., Stickler M., and Meyerhoff G. Spontaneous polymerization of methyl methacrylate, 3. Reaction behavior of the unsaturated dimer upon polymerization. Makromolekulare Chemie 181 (1980) 913-921
    • (1980) Makromolekulare Chemie , vol.181 , pp. 913-921
    • Brand, E.1    Stickler, M.2    Meyerhoff, G.3
  • 7
    • 1642634957 scopus 로고    scopus 로고
    • Chain-length dependence of termination rate coefficients in acrylate and methacrylate homopolymerizations investigated via the sp-plp technique
    • Buback M., Egorov M., and Feldermann A. Chain-length dependence of termination rate coefficients in acrylate and methacrylate homopolymerizations investigated via the sp-plp technique. Macromolecules 37 (2004) 1768-1776
    • (2004) Macromolecules , vol.37 , pp. 1768-1776
    • Buback, M.1    Egorov, M.2    Feldermann, A.3
  • 8
    • 4344636240 scopus 로고    scopus 로고
    • Simulating acrylate polymerization reactions: Toward improved mechanistic understanding and reliable parameter estimates
    • Busch M., and Muller M. Simulating acrylate polymerization reactions: Toward improved mechanistic understanding and reliable parameter estimates. Macromolecular Symposia 206 (2004) 399-418
    • (2004) Macromolecular Symposia , vol.206 , pp. 399-418
    • Busch, M.1    Muller, M.2
  • 9
    • 3142528715 scopus 로고    scopus 로고
    • Kinetics of butylacrylate polymerization in a starved feed reactor
    • Cao G., Zhu Z., Zhang M., and Yuan W. Kinetics of butylacrylate polymerization in a starved feed reactor. Journal of Applied Polymer Science 93 (2004) 1519-1525
    • (2004) Journal of Applied Polymer Science , vol.93 , pp. 1519-1525
    • Cao, G.1    Zhu, Z.2    Zhang, M.3    Yuan, W.4
  • 10
    • 0037186231 scopus 로고    scopus 로고
    • Modeling of high-pressure ethylene polymerization. I. Kinetic parameters of oxygen initiation
    • Cerinski B., and Jelencic J. Modeling of high-pressure ethylene polymerization. I. Kinetic parameters of oxygen initiation. Journal of Applied Polymer Science 83 (2002) 2043-2051
    • (2002) Journal of Applied Polymer Science , vol.83 , pp. 2043-2051
    • Cerinski, B.1    Jelencic, J.2
  • 11
    • 0032135925 scopus 로고    scopus 로고
    • Chiefari J., Chong Y. K., Ercole F., Kristina J., Le T.P., Mayadunne R. T. A., et al. (1998). Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process. Macromolecules, 31, 5559.
    • Chiefari J., Chong Y. K., Ercole F., Kristina J., Le T.P., Mayadunne R. T. A., et al. (1998). Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process. Macromolecules, 31, 5559.
  • 15
    • 0027592121 scopus 로고
    • Narrow molecular weight resins by a free-radical polymerization process
    • Georges M.K., Veregin R.P.N., Kazmaier P.M., and Hamer G.K. Narrow molecular weight resins by a free-radical polymerization process. Macromolecules 26 (1993) 2987
    • (1993) Macromolecules , vol.26 , pp. 2987
    • Georges, M.K.1    Veregin, R.P.N.2    Kazmaier, P.M.3    Hamer, G.K.4
  • 16
    • 0036310186 scopus 로고    scopus 로고
    • Studies of higher temperature polymerization of n-butyl methacrylate and n-butyl acrylate
    • Grady M.C., Simonsick W.J., and Hutchinson R.A. Studies of higher temperature polymerization of n-butyl methacrylate and n-butyl acrylate. Macromolecular Symposia 182 (2002) 149-168
    • (2002) Macromolecular Symposia , vol.182 , pp. 149-168
    • Grady, M.C.1    Simonsick, W.J.2    Hutchinson, R.A.3
  • 17
    • 0033722630 scopus 로고    scopus 로고
    • High-temperature solution polymerization of butyl acrylate/methyl methacrylate: Reactivity ratio estimation
    • Hakim M., Verhoeven V., McManus N.T., Dube M.A., and Penlidis A. High-temperature solution polymerization of butyl acrylate/methyl methacrylate: Reactivity ratio estimation. Journal of Applied Polymer Science 77 (2000) 602
    • (2000) Journal of Applied Polymer Science , vol.77 , pp. 602
    • Hakim, M.1    Verhoeven, V.2    McManus, N.T.3    Dube, M.A.4    Penlidis, A.5
  • 18
    • 0011710076 scopus 로고
    • A study of the purification of methyl mecthacrylate suggests that the 'thermal' polymerisation of this monomer is initiated by adventitious peroxides
    • Lehrle R.S., and Shortland A. A study of the purification of methyl mecthacrylate suggests that the 'thermal' polymerisation of this monomer is initiated by adventitious peroxides. European Polymer Journal 24 (1988) 425-429
    • (1988) European Polymer Journal , vol.24 , pp. 425-429
    • Lehrle, R.S.1    Shortland, A.2
  • 19
    • 0000456963 scopus 로고
    • The spontaneous polymerization of methyl methacrylate. 7. External heavy atom effect on the initiation
    • Lingnau J., and Meyerhoff G. The spontaneous polymerization of methyl methacrylate. 7. External heavy atom effect on the initiation. Makromolekulare Chemie 185 (1984) 587-600
    • (1984) Makromolekulare Chemie , vol.185 , pp. 587-600
    • Lingnau, J.1    Meyerhoff, G.2
  • 20
    • 0008321344 scopus 로고
    • Spontaneous polymerization of methyl methacrylate. 8. Polymerization kinetics of acrylates containing chlorine atoms
    • Lingnau J., and Meyerhoff G. Spontaneous polymerization of methyl methacrylate. 8. Polymerization kinetics of acrylates containing chlorine atoms. Macromolecules 17 (1984) 941-945
    • (1984) Macromolecules , vol.17 , pp. 941-945
    • Lingnau, J.1    Meyerhoff, G.2
  • 21
    • 0001291609 scopus 로고
    • The spontaneous polymerization of methyl methacrylate. IV. Formation of cyclic dimers and linear trimers
    • Lingnau J., Stickler M., and Meyerhoff G. The spontaneous polymerization of methyl methacrylate. IV. Formation of cyclic dimers and linear trimers. European Polymer Journal 16 (1980) 785-791
    • (1980) European Polymer Journal , vol.16 , pp. 785-791
    • Lingnau, J.1    Stickler, M.2    Meyerhoff, G.3
  • 22
    • 0020845252 scopus 로고
    • The spontaneous polymerization of methyl methacrylate. 6. Polymerization in solution: Participation of transfer agents in the initiation reaction
    • Lingnau J., Stickler M., and Meyerhoff G. The spontaneous polymerization of methyl methacrylate. 6. Polymerization in solution: Participation of transfer agents in the initiation reaction. Polymer 24 (1983) 1473-1478
    • (1983) Polymer , vol.24 , pp. 1473-1478
    • Lingnau, J.1    Stickler, M.2    Meyerhoff, G.3
  • 23
    • 0032118597 scopus 로고    scopus 로고
    • Measurement of transfer constant for butyl acrylate free radical polymerization
    • Maeder S., and Gilbert R.G. Measurement of transfer constant for butyl acrylate free radical polymerization. Macromolecules 31 (1998) 4410-4418
    • (1998) Macromolecules , vol.31 , pp. 4410-4418
    • Maeder, S.1    Gilbert, R.G.2
  • 24
    • 0030783960 scopus 로고    scopus 로고
    • Short-chain branching structures in ethylene copolymers prepared by high-pressure free-radical polymerization: An NMR analysis
    • McCord E.F., Shaw W.H., and Hutchinson Jr. R.A. Short-chain branching structures in ethylene copolymers prepared by high-pressure free-radical polymerization: An NMR analysis. Macromolecules 30 (1997) 246-256
    • (1997) Macromolecules , vol.30 , pp. 246-256
    • McCord, E.F.1    Shaw, W.H.2    Hutchinson Jr., R.A.3
  • 25
    • 0037033762 scopus 로고    scopus 로고
    • Copolymerization of alpha-methyl styrene with butyl acrylate in bulk
    • McManus N.T., Penlidis A., and Dube M.A. Copolymerization of alpha-methyl styrene with butyl acrylate in bulk. Polymer 43 (2002) 1607-1614
    • (2002) Polymer , vol.43 , pp. 1607-1614
    • McManus, N.T.1    Penlidis, A.2    Dube, M.A.3
  • 26
    • 0000519503 scopus 로고
    • Some structural and chemical aspects of aging and degradation of vinyl and diene polymers
    • Mesrobian R.B., and Tobolsky A.V. Some structural and chemical aspects of aging and degradation of vinyl and diene polymers. Polymer Science 2 (1947) 463
    • (1947) Polymer Science , vol.2 , pp. 463
    • Mesrobian, R.B.1    Tobolsky, A.V.2
  • 27
    • 0042193585 scopus 로고    scopus 로고
    • Determination of propagation rate coefficient of acrylates by pulsed-laser polymerization in the presence of intramolecular chain transfer to polymer
    • Nikitin A.N., Castignolles P., Charleux B., and Vairon J.P. Determination of propagation rate coefficient of acrylates by pulsed-laser polymerization in the presence of intramolecular chain transfer to polymer. Macromolecular Rapid Communications 24 (2003) 778-782
    • (2003) Macromolecular Rapid Communications , vol.24 , pp. 778-782
    • Nikitin, A.N.1    Castignolles, P.2    Charleux, B.3    Vairon, J.P.4
  • 30
    • 4344692645 scopus 로고    scopus 로고
    • Secondary reactions in the high-temperature free radical polymerization of butyl acrylate
    • Peck A.N.F., and Hutchinson R.A. Secondary reactions in the high-temperature free radical polymerization of butyl acrylate. Macromolecules 37 (2004) 5944-5951
    • (2004) Macromolecules , vol.37 , pp. 5944-5951
    • Peck, A.N.F.1    Hutchinson, R.A.2
  • 31
    • 32044438387 scopus 로고    scopus 로고
    • Branching and scission reactions in high temperature acrylate polymerisations
    • Peck A.N.F., Hutchinson R.A., and Grady M.C. Branching and scission reactions in high temperature acrylate polymerisations. Polymer Preprints 43 (2002) 154-155
    • (2002) Polymer Preprints , vol.43 , pp. 154-155
    • Peck, A.N.F.1    Hutchinson, R.A.2    Grady, M.C.3
  • 32
    • 0004279576 scopus 로고
    • Federation of Societies for Coatings Technology, Philadelphia, PA p. 24
    • Prane J.W. Introduction la polymers and resins (1986), Federation of Societies for Coatings Technology, Philadelphia, PA p. 24
    • (1986) Introduction la polymers and resins
    • Prane, J.W.1
  • 33
    • 0014554260 scopus 로고
    • Studies on the polymerization of ethyl acrylate. II. Chain transfer studies
    • Raghuram P.V.T., and Nandi U.S. Studies on the polymerization of ethyl acrylate. II. Chain transfer studies. Journal of Polymer Science Part A-1 7 (1969) 2379-2385
    • (1969) Journal of Polymer Science Part A-1 , vol.7 , pp. 2379-2385
    • Raghuram, P.V.T.1    Nandi, U.S.2
  • 34
    • 45949108308 scopus 로고    scopus 로고
    • Rantow, F. S. (2006). Secondary reactions in high-temperature free-radical polymerization of alkyl acrylates. Ph.D. Thesis, Philadelphia, PA, USA: Drexel University.
    • Rantow, F. S. (2006). Secondary reactions in high-temperature free-radical polymerization of alkyl acrylates. Ph.D. Thesis, Philadelphia, PA, USA: Drexel University.
  • 35
    • 32044462959 scopus 로고    scopus 로고
    • Spontaneous polymerization and chain microstructure evolution in high-temperature solution polymerization of n-butyl acrylate
    • Rantow F.S., Soroush M., Grady M.C., and Kalfas G.A. Spontaneous polymerization and chain microstructure evolution in high-temperature solution polymerization of n-butyl acrylate. Polymer 47 (2006) 1423-1435
    • (2006) Polymer , vol.47 , pp. 1423-1435
    • Rantow, F.S.1    Soroush, M.2    Grady, M.C.3    Kalfas, G.A.4
  • 36
    • 0009800761 scopus 로고
    • Paints and coatings
    • (October)
    • Reisch M.S. Paints and coatings. Chemical Engineering News 71 (1993) 34-37 (October)
    • (1993) Chemical Engineering News , vol.71 , pp. 34-37
    • Reisch, M.S.1
  • 37
    • 0021230897 scopus 로고
    • The dynamic behavior of continuous polymerization reactors-III
    • Schmidt A.D., Clinch A.B., and Ray W.H. The dynamic behavior of continuous polymerization reactors-III. Chemical Engineering Science 39 (1981) 419-432
    • (1981) Chemical Engineering Science , vol.39 , pp. 419-432
    • Schmidt, A.D.1    Clinch, A.B.2    Ray, W.H.3
  • 38
    • 45949098258 scopus 로고    scopus 로고
    • Schultz, K.R. Proceedings of Advance Coat. Technology Conference, Chicago, IL, 1992.
    • Schultz, K.R. Proceedings of Advance Coat. Technology Conference, Chicago, IL, 1992.
  • 39
    • 0001715510 scopus 로고
    • Thermal polymerization of methyl methacrylate, 1. Polymerization in bulk
    • Stickler M., and Meyerhoff G. Thermal polymerization of methyl methacrylate, 1. Polymerization in bulk. Makromolekulare Chemie 179 (1978) 2729-2745
    • (1978) Makromolekulare Chemie , vol.179 , pp. 2729-2745
    • Stickler, M.1    Meyerhoff, G.2
  • 40
    • 0019584782 scopus 로고
    • The spontaneous thermal polymerization of methyl methacrylate. 5. Experimental study and computer simulation of the high conversion reaction at 130 c
    • Stickler M., and Meyerhoff G. The spontaneous thermal polymerization of methyl methacrylate. 5. Experimental study and computer simulation of the high conversion reaction at 130 c. Polymer 22 (1981) 928-933
    • (1981) Polymer , vol.22 , pp. 928-933
    • Stickler, M.1    Meyerhoff, G.2
  • 41
    • 45949094076 scopus 로고    scopus 로고
    • Superintendent of Documents, Title 1. (1990). US Government Printing Office, Washington, DC, p. 1.
    • Superintendent of Documents, Title 1. (1990). US Government Printing Office, Washington, DC, p. 1.
  • 42
    • 45949089721 scopus 로고    scopus 로고
    • Superintendent of Documents. (1990). Clean Air Act Amendments of 1990. Title 111, US Government Printing Office, Washington, DC, p. 236.
    • Superintendent of Documents. (1990). Clean Air Act Amendments of 1990. Title 111, US Government Printing Office, Washington, DC, p. 236.
  • 43
    • 0033119083 scopus 로고    scopus 로고
    • Multirate nonlinear state estimation with application to a polymerization reactor
    • Tatiraju T., Soroush M., and Ogunnaike B.A. Multirate nonlinear state estimation with application to a polymerization reactor. AIChE Journal 45 (1999) 769-780
    • (1999) AIChE Journal , vol.45 , pp. 769-780
    • Tatiraju, T.1    Soroush, M.2    Ogunnaike, B.A.3
  • 44
    • 0021165215 scopus 로고
    • Free radical polymerization engineering. I. A new method for modeling free radical homogeneous polymerization reactions
    • Villermaux J., and Blavier L. Free radical polymerization engineering. I. A new method for modeling free radical homogeneous polymerization reactions. Chemical Engineering Science 39 (1984) 87-99
    • (1984) Chemical Engineering Science , vol.39 , pp. 87-99
    • Villermaux, J.1    Blavier, L.2
  • 45
    • 45949090513 scopus 로고    scopus 로고
    • VOC's Directive, EU Committee of the American Chamber of Commerce in Belgium, ASBL/VZw, Brussels, July 1996.
    • VOC's Directive, EU Committee of the American Chamber of Commerce in Belgium, ASBL/VZw, Brussels, July 1996.
  • 46
    • 0029638116 scopus 로고
    • Controlled "living" radical polymerization. halogen atom transfer radical polymerization promoted by a Cu(I)/Cu(II) redox process
    • Wang S.J., and Matyjaszewski K. Controlled "living" radical polymerization. halogen atom transfer radical polymerization promoted by a Cu(I)/Cu(II) redox process. Macromolecules 28 (1995) 7901
    • (1995) Macromolecules , vol.28 , pp. 7901
    • Wang, S.J.1    Matyjaszewski, K.2
  • 47
    • 0345761634 scopus 로고    scopus 로고
    • Wayland, B. B., Mukerjee, S., Poszmik, G., Woska, D. C., Basickes, L., Gridnev, A. A., et al. (1998). Control of radical polymerizations by metalloradicals, ACS Symposium Series, 685, 305-315 (Controlled Radical Polymerization).
    • Wayland, B. B., Mukerjee, S., Poszmik, G., Woska, D. C., Basickes, L., Gridnev, A. A., et al. (1998). Control of radical polymerizations by metalloradicals, ACS Symposium Series, 685, 305-315 (Controlled Radical Polymerization).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.